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Free-standing Na2C6O6/MXene composite paper for high-performance organic sodium-ion batteries

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Abstract

Sodium-ion batteries (SIBs) are regarded as the ideal low-cost choice for next-generation large-scale energy storage system. Carbonyl-based organic salt-disodium rhodizonate (Na2C6O6) with high theoretical specific capacity (501 mAh·g−1) is considered as a promising cathode material for SIBs. However, the dissolution of active material in electrolyte and low electronic conductivity lead to rapidly capacity decay and poor rate performance. Herein, a simple method is designed to construct free-standing and flexible Ti3C2Tx Na2C6O6/MXene paper via vacuum-assisted filtration and antisolvent approach. The MXene can form an electronic conductive network, adsorb the active materials, and offer additional active sites for Na storage. The binder-free Na2C6O6/MXene paper delivers excellent electrochemical property with a high rate performance of 231 mAh·g−1 at 1,000 mA·g−1 and a high capacity of 215 mAh·g−1 after 100 cycles. This work provides an attractive strategy for designing high-performance organic electrode materials of SIBs.

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Acknowledgements

This work was supported by the Natural Science Foundation of Shandong Province (No. ZR2020JQ19), Taishan Scholars Program of Shandong Province (Nos. tsqn201812002, ts20190908, and ts201511004), the Young Scholars Program of Shandong University (No. 2016WLJH03), Shenzhen Fundamental Research Program (No. JCYJ20190807093405503), and the National Natural Science Foundation of China (Nos. 51972198 and 61633015).

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  1. Zhengran Wang and Yuchan Zhang contributed equally to this work.

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  1. Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), Research Center for Carbon Nanomaterials, School of Materials Science and Engineering, Shandong University, Jinan, 250061, China

    Zhengran Wang, Yuchan Zhang, Huiyu Jiang, Chuanliang Wei, Yongling An, Liwen Tan & Jinkui Feng

  2. Shenzhen Institute of Shandong University, Shenzhen, 518057, China

    Zhengran Wang, Shenglin Xiong & Jinkui Feng

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  1. Zhengran Wang
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Wang, Z., Zhang, Y., Jiang, H. et al. Free-standing Na2C6O6/MXene composite paper for high-performance organic sodium-ion batteries. Nano Res. 16, 458–465 (2023). https://doi.org/10.1007/s12274-022-4696-5

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