Abstract
Since the advent of graphene in 2004, two-dimensional (2D) materials had ignited the development of fascinating functional materials for almost 20 years. Currently, the main members of 2D materials family are graphene, transition metal dichalcogenides (TMDs, MoS2, WS2, and others), MXenes (Ti3C2, Ta4C3, and others), Xenes (B, Si, P, Ge, and Sn), organic materials (COF, covalent organic frameworks), etc. [1]. The unique sheet-like morphology (single- or few-atomic-layer thickness) endow 2D materials with unconventional physicochemical properties for promising applications in catalysis, energy storage/conversion, electronics, biomedicine, sensors, etc. Nevertheless, the exploration and preparation of novel two-dimensional materials with desired characteristics through highly controlled strategy remains one of the major challenges in this field. In a recent work from Nature Chemistry published on 10 February 2022, Liu et al. [2] reported a new member, clusterphene, in the family of two-dimensional materials.
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Chang, C.; Chen, W.; Chen, Y.; Chen, Y. H.; Chen, Y.; Ding, F.; Fan, C. H.; Fan, H. J.; Fan, Z. X.; Gong, C. et al. Recent progress on two-dimensional materials. Acta Phys. -Chim. Sin. 2021, 37, 2108017.
Liu, Q. D.; Zhang, Q. H.; Shi, W. X.; Hu, H. S.; Zhuang, J.; Wang, X. Self-assembly of polyoxometalate clusters into two-dimensional clusterphene structures featuring hexagonal pores. Nat. Chem. 2022, 14, 433–440.
Zhang, S. M.; Shi, W. X.; Rong, S. J.; Li, S. Z.; Zhuang, J.; Wang, X. Chirality evolution from sub-1 nanometer nanowires to the macroscopic helical structure. J. Am. Chem. Soc. 2020, 142, 1375–1381.
Bian, T.; Gardin, A.; Gemen, J.; Houben, L.; Perego, C.; Lee, B.; Elad, N.; Chu, Z. L.; Pavan, G. M.; Klajn, R. Electrostatic co-assembly of nanoparticles with oppositely charged small molecules into static and dynamic superstructures. Nat. Chem. 2021, 13, 940–949.
Avci, C.; Imaz, I.; Carné-Sánchez, A.; Pariente, J. A.; Tasios, N.; Pérez-Carvajal, J.; Alonso, M. I.; Blanco, A.; Dijkstra, M.; López, C. et al. Self-assembly of polyhedral metal-organic framework particles into three-dimensional ordered superstructures. Nat. Chem. 2018, 10, 78–84.
Yang D. R.; Zuo S. W.; Yang H. Z.; Zhou Y.; Wang X. Freestanding millimeter-scale porphyrin-based monoatomic layers with 0. 28 nm thickness for CO2 electrocatalysis. Angew. Chem., Int. Ed. 2020, 59, 18954–18959.
Liu J. L.; Shi W. X.; Ni B.; Yang Y.; Li S. Z.; Zhuang J.; Wang X. Incorporation of clusters within inorganic materials through their addition during nucleation steps. Nat. Chem. 2019, 11, 839–845.
Baek, W.; Bootharaju, M. S.; Walsh, K. M.; Lee, S.; Gamelin, D. R.; Hyeon, T. Highly luminescent and catalytically active suprastructures of magic-sized semiconductor nanoclusters. Nat. Mater. 2021, 20, 650–657.
Henzie, J.; Grünwald, M.; Widmer-Cooper, A.; Geissler, P. L.; Yang, P. D. Self-assembly of uniform polyhedral silver nanocrystals into densest packings and exotic superlattices. Nat. Mater. 2012, 11, 131–137.
Hu, S.; Liu, H. L.; Wang, P. P.; Wang, X. Inorganic nanostructures with sizes down to 1 nm: A macromolecule analogue. J. Am. Chem. Soc. 2013, 135, 11115–11124.
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Zhou, J., Li, L., Gao, X.J. et al. Clusterphene: A new two-dimensional structure from cluster self-assembly. Nano Res. 15, 5790–5791 (2022). https://doi.org/10.1007/s12274-022-4399-y
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DOI: https://doi.org/10.1007/s12274-022-4399-y