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Wavelength-selectivity polarization dependence of optical absorption and photoresponse in SnS nanosheets

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Abstract

The optical and optoelectronic characteristics of SnS nanosheets with strong anisotropic crystal structure are researched. Transmission electron microscopy and polarized Raman spectra are used to determine the crystal orientation of SnS nanosheets. The photodetector based on SnS nanosheets exhibits the carrier mobility of 37.75 cm2/V·S photoresponsivity of 310.5 A/W and external quantum efficiency of 8.56 × 104 % at 450 nm. Optical absorption around the absorption edge presents obvious polarization sensitivity with the highest optical absorption dichroic ratio of 3.06 at 862 nm. Due to anisotropic optical absorption, the polarized photocurrent appears as the periodic change affected by the polarized direction of the incident light at 808 nm. Overall, SnS nanosheets show good potential in the future application of the polarized photodetectors for specific wavelength.

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References

  1. Tyo, J. S.; Goldstein, D. L.; Chenault, D. B.; Shaw, J. A. Review of passive imaging polarimetry for remote sensing applications. Appl. Opt. 2006, 45, 5453–5469.

    Article  Google Scholar 

  2. Li, Q.; Li, Z. F.; Li, N.; Chen, X. S.; Chen, P. P.; Shen, X. C.; Lu, W. High-polarization-discriminating infrared detection using a single quantum well sandwiched in plasmonic micro-cavity. Sci. Rep. 2014, 4, 6332.

    Article  CAS  Google Scholar 

  3. Li, L.; Xiong, D. Y.; Wen, J.; Li, N.; Zhu, Z. Q. A surface plasmonic coupled mid-long-infrared two-color quantum cascade detector. Infrared Phys. Technol. 2016, 79, 45–49.

    Article  CAS  Google Scholar 

  4. Venuthurumilli, P. K.; Ye, P. D.; Xu, X. F. Plasmonic resonance enhanced polarization-sensitive photodetection by black phosphorus in near infrared. ACS Nano 2018, 12, 4861–4867.

    Article  CAS  Google Scholar 

  5. Chen, Y. B.; Chen, C. Y.; Kealhofer, R.; Liu, H. L.; Yuan, Z. Q.; Jiang, L. L.; Suh, J.; Park, J.; Ko, C.; Choe, H. S. et al. Black arsenic: A layered semiconductor with extreme in-plane anisotropy. Adv. Mater. 2018, 30, 1800754.

    Article  Google Scholar 

  6. Chu, F. H.; Chen, M. Y.; Wang, Y.; Xie, Y. Q.; Liu, B. Y.; Yang, Y. H.; An, X. T.; Zhang, Y. Z. A highly polarization sensitive antimonene photodetector with a broadband photoresponse and strong anisotropy. J. Mater. Chem. C 2018, 6, 2509–2514.

    Article  CAS  Google Scholar 

  7. Wang, X. T.; Li, Y. T.; Huang, L.; Jiang, X. W.; Jiang, L.; Dong, H. L.; Wei, Z. M.; Li, J. B.; Hu, W. P. Short-wave near-infrared linear dichroism of two-dimensional germanium selenide. J. Am. Chem. Soc. 2017, 139, 14976–14982.

    Article  CAS  Google Scholar 

  8. Zhou, Z. Q.; Cui, Y.; Tan, P. H.; Liu, X. L.; Wei, Z. M. Optical and electrical properties of two-dimensional anisotropic materials. J. Semicond. 2019, 40, 061001.

    Article  CAS  Google Scholar 

  9. Liu, F. C.; Zheng, S. J.; He, X. X.; Chaturvedi, A.; He, J. F.; Chow, W. L.; Mion, T. R.; Wang, X. L.; Zhou, J. D.; Fu, Q. D. et al. Highly sensitive detection of polarized light using anisotropic 2D ReS2. Adv. Funct. Mater. 2016, 26, 1169–1177.

    Article  CAS  Google Scholar 

  10. Zhou, W.; Chen, J. Z.; Gao, H.; Hu, T.; Ruan, S. C.; Stroppa, A.; Ren, W. Anomalous and polarization-sensitive photoresponse of Td-WTe2 from visible to infrared light. Adv. Mater. 2019, 31, 1804629.

    Article  Google Scholar 

  11. Liu, F. C.; Shimotani, H.; Shang, H.; Kanagasekaran, T.; Zólyomi, V.; Drummond, N.; Fal’ko, V. I.; Tanigaki, K. High-sensitivity photo-detectors based on multilayer GaTe flakes. ACS Nano 2014, 8, 752–760.

    Article  CAS  Google Scholar 

  12. Liu, S. J.; Xiao, W. B.; Zhong, M. Z.; Pan, L. F.; Wang, X. T.; Deng, H. X.; Liu, J.; Li, J. B.; Wei, Z. M. Highly polarization sensitive photodetectors based on quasi-1D titanium trisulfide (TiS3). Nanotechnology 2018, 29, 184002.

    Article  Google Scholar 

  13. Wang, X. T.; Wu, K. D.; Blei, M.; Wang, Y.; Pan, L. F.; Zhao, K.; Shan, C. X.; Lei, M.; Cui, Y.; Chen, B. et al. Highly polarized photoelectrical response in vdW ZrS3 nanoribbons. Adv. Elect. Mater. 2019, 5, 1900419.

    Article  Google Scholar 

  14. Li, L.; Han, W.; Pi, L. J.; Niu, P.; Han, J. B.; Wang, C. L.; Su, B.; Li, H. Q.; Xiong, J.; Bando, Y. et al. Emerging in-plane anisotropic two-dimensional materials. InfoMat 2019, 1, 54–73.

    Article  CAS  Google Scholar 

  15. Li, L. K.; Yu, Y. J.; Ye, G. J.; Ge, Q. Q.; Ou, X. D.; Wu, H.; Feng, D. L.; Chen, X. H.; Zhang, Y. B. Black phosphorus field-effect transistors. Nat. Nanotechnol. 2014, 9, 372–377.

    Article  CAS  Google Scholar 

  16. Hong, T.; Chamlagain, B.; Lin, W. Z.; Chuang, H. J.; Pan, M. H.; Zhou, Z. X.; Xu, Y. Q. Polarized photocurrent response in black phosphorus field-effect transistors. Nanoscale 2014, 6, 8978–8983.

    Article  CAS  Google Scholar 

  17. Yuan, H. T.; Liu, X. G; Afshinmanesh, F.; Li, W.; Xu, G.; Sun, J.; Lian, B.; Curto, A. G.; Ye, G. J.; Hikita, Y. et al. Polarization-sensitive broadband photodetector using a black phosphorus vertical p-n junction. Nat. Nanotechnol. 2015, 10, 707–713.

    Article  CAS  Google Scholar 

  18. Zhou, Z. Q.; Long, M. S.; Pan, L. F.; Wang, X. T.; Zhong, M. Z.; Blei, M.; Wang, J. L.; Fang, J. Z.; Tongay, S.; Hu, W. D. et al. Perpendicular optical reversal of the linear dichroism and polarized photodetection in 2D GeAs. ACS Nano 2018, 12, 12416–12423.

    Article  CAS  Google Scholar 

  19. Tian, Z.; Guo, C. L.; Zhao, M. X.; Li, R. R.; Xue, J. M. Two-dimensional SnS: A phosphorene analogue with strong in-plane electronic anisotropy. ACS Nano 2017, 11, 2219–2226.

    Article  CAS  Google Scholar 

  20. Lin, S. R.; Carvalho, A.; Yan, S. C.; Li, R.; Kim, S.; Rodin, A.; Carvalho, L.; Chan, E. M.; Wang, X.; Castro Neto, A. H. et al. Accessing valley degree of freedom in bulk Tin(II) sulfide at room temperature. Nat. Commun. 2018, 9, 1455.

    Article  Google Scholar 

  21. Zhang, Z. D.; Yang, J. H.; Zhang, K.; Chen, S.; Mei, F. H.; Shen, G. Z. Anisotropic photoresponse of layered 2D SnS-based near infrared photodetectors. J. Mater. Chem. C 2017, 5, 11288–11293.

    Article  CAS  Google Scholar 

  22. Sun, B. Z.; Ma, Z. J.; He, C.; Wu, K. C. Enhanced thermoelectric performance of layered SnS crystals: The synergetic effect of temperature and carrier concentration. RSC Adv. 2015, 5, 56382–56390.

    Article  CAS  Google Scholar 

  23. Zheng, D. S.; Fang, H. H.; Long, M. S.; Wu, F.; Wang, P.; Gong, F.; Wu, X.; Ho, J. C.; Liao, L.; Hu, W. D. High-performance near-infrared photodetectors based on p-type SnX (X = S, Se) nanowires grown via chemical vapor deposition. ACS Nano 2018, 12, 7239–7245.

    Article  CAS  Google Scholar 

  24. Zhou, X.; Gan, L.; Zhang, Q.; Xiong, X.; Li, H. Q.; Zhong, Z. Q.; Han, J. B.; Zhai, T. Y. High performance near-infrared photodetectors based on ultrathin SnS nanobelts grown via physical vapor deposition. J. Mater. Chem. C 2016, 4, 2111–2116.

    Article  CAS  Google Scholar 

  25. Sohila, S.; Rajalakshmi, M.; Ghosh, C.; Arora, A. K.; Muthamizhchelvan, C. Optical and Raman scattering studies on SnS nanoparticles. J. Alloys Compd. 2011, 509, 5843–5847.

    Article  CAS  Google Scholar 

  26. Gao, W.; Li, Y. T.; Guo, J. H.; Ni, M. X.; Liao, M.; Mo, H. J.; Li, J. B. Narrow-gap physical vapour deposition synthesis of ultrathin SnS1−xSex (0 ≤ x ≤ 1) two-dimensional alloys with unique polarized Raman spectra and high (opto)electronic properties. Nanoscale 2018, 10, 8787–8795.

    Article  CAS  Google Scholar 

  27. Xia, J.; Li, X. Z.; Huang, X.; Mao, N. N.; Zhu, D. D.; Wang, L.; Xu, H.; Meng, X. M. Physical vapor deposition synthesis of two-dimensional orthorhombic SnS flakes with strong angle/temperature-dependent Raman responses. Nanoscale 2016, 8, 2063–2070.

    Article  CAS  Google Scholar 

  28. Xu, X. L.; Song, Q. J.; Wang, H. F.; Li, P.; Zhang, K.; Wang, Y. L.; Yuan, K.; Yang, Z. C.; Ye, Y.; Dai, L. In-plane anisotropies of polarized Raman response and electrical conductivity in layered tin selenide. ACS Appl. Mater. Interfaces 2017, 9, 12601–12607.

    Article  CAS  Google Scholar 

  29. Ling, X.; Liang, L. B.; Huang, S. X.; Puretzky, A. A.; Geohegan, D. B.; Sumpter, B. G.; Kong, J.; Meunier, V.; Dresselhaus, M. S. Low-frequency interlayer breathing modes in few-layer black phosphorus. Nano Lett. 2015, 15, 4080–4088.

    Article  CAS  Google Scholar 

  30. Rath, T.; Gury, L.; Sánchez-Molina, I.; Martínez, L.; Haque, S. A. Formation of porous SnS nanoplate networks from solution and their application in hybrid solar cells. Chem. Commun. 2015, 51, 10198–10201.

    Article  CAS  Google Scholar 

  31. Shi, H. Y.; Yan, R. S.; Bertolazzi, S.; Brivio, J.; Gao, B.; Kis, A.; Jena, D.; Xing, H. G.; Huang, L. B. Exciton dynamics in suspended monolayer and few-layer MoS2 2D crystals. ACS Nano 2013, 7, 1072–1080.

    Article  CAS  Google Scholar 

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 62004193 and 81900912), the National Key Research and Development Program of China (Grant No. 2017YFA0207500), the Strategic Priority Research Program of Chinese Academy of Sciences (XDB43000000), and Beijing National Laboratory for Molecular Sciences (BNLMS201908).

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Correspondence to Juehan Yang.

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Cui, Y., Zhou, Z., Wang, X. et al. Wavelength-selectivity polarization dependence of optical absorption and photoresponse in SnS nanosheets. Nano Res. 14, 2224–2230 (2021). https://doi.org/10.1007/s12274-020-3197-7

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  • DOI: https://doi.org/10.1007/s12274-020-3197-7

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