Abstract
We demonstrate highly efficient multi-colored semitransparent perovskite solar cells that can create high angular tolerant controllable transmissive colors up to 60°, based on phase-compensated microcavities. The efficiency of the semitransparent colors was improved by impedance matching, which was enabled by placing a dielectric functional layer on top of traditional optical microcavities, with negligible influence on color pureness. The vast majority of the visible part of solar radiation is efficiently utilized for solar energy harvesting, achieving 10.47%, 10.66%, and 11.18% of efficiency for red, green, and blue (RGB) colored solar cells, respectively, while a very small proportion of the visible solar spectrum is used for structural coloration that can be readily tuned by altering the cavity medium thickness. The approach described herein can be suitable for a variety of applications such as display systems with ultra-low power consumption, highly efficient colorful solar panels, low-power wearable electronics, and energy-efficient optoelectronics.
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Jeon, N. J.; Noh, J. H.; Yang, W. S.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Compositional engineering of perovskite materials for high-performance solar cells. Nature 2015, 517, 476–480.
Stranks, S. D.; Snaith, H. J. Metal-halide perovskites for photovoltaic and light-emitting devices. Nat. Nanotechnol. 2015, 10, 391–402.
Cho, H.; Jeong, S.-H.; Park, M.-H.; Kim, Y.-H.; Wolf, C.; Lee, C.-L.; Heo, J. H.; Sadhanala, A.; Myoung, N.; Yoo, S. et al. Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes. Science 2015, 350, 1222–1225.
Park, Y.; Lee, S.; Park, H. J.; Baac, H. W.; Yoo, G.; Heo, J. Hybrid metal-halide perovskite-MoS2 phototransistor. J. Nanosci. Nanotechnol. 2016, 16, 11722–11726.
Xing, G. C.; Mathews, N.; Sun, S. Y.; Lim, S. S.; Lam, Y. M.; Grätzel, M.; Mhaisalkar, S.; Sum, T. C. Long-range balanced electron- and hole-transport lengths in organic-inorganic CH3NH3PbI3. Science 2013, 342, 344–347.
Jeon, S. H.; Thakur, U. K.; Lee, D.; Wenping, Y.; Kim, D.; Lee, S.; Ahn, T. K.; Park, H. J.; Kim, B.-G. N-phenylindolediketopyrrolopyrrole-containing narrow band-gap materials for dopant-free hole transporting layer of perovskite solar cell. Org. Electron. 2016, 37, 134–140.
Brenner, T. M.; Egger, D. A.; Kronik, L.; Hodes, G.; Cahen, D. Hybrid organic–inorganic perovskites: Low-cost semiconductors with intriguing charge-transport properties. Nat. Rev. Mater. 2016, 1, 15007.
Park, N.-G. Perovskite solar cells: An emerging photovoltaic technology. Mater. Today 2015, 18, 65–72.
Park, S. J.; Jeon, S.; Lee, I. K.; Zhang, J.; Jeong, H.; Park, J.-Y.; Bang, J.; Ahn, T. K.; Shin, H. W.; Kim, B.-G. et al. Inverted planar perovskite solar cells with dopant free hole transporting material: Lewis base-assisted passivation and reduced charge recombination. J. Mater. Chem. A 2017, 5, 13220–13227.
Song, J. Z.; Li, J. H.; Li, X. M.; Xu, L. M.; Dong, Y. H.; Zeng, H. B. Quantum dot light-emitting diodes based on inorganic perovskite cesium lead halides (CsPbX3). Adv. Mater. 2015, 27, 7162–7167.
Li, J. H.; Xu, L. M.; Wang, T.; Song, J. Z.; Chen, J. W.; Xue, J.; Dong, Y. H.; Cai, B.; Shan, Q. S.; Han, B. N. et al. 50-fold EQE improvement up to 6.27% of solution-processed all-inorganic perovskite CsPbBr3 QLEDs via surface ligand density control. Adv. Mater. 2017, 29, 1603885.
Xue, J.; Gu, Y.; Shan, Q. S.; Zou, Y. S.; Song, J. Z.; Xu, L. M.; Dong, Y. H.; Li, J. H.; Zeng, H. B. Constructing Mie-scattering porous interface-fused perovskite films to synergistically boost light harvesting and carrier transport. Angew. Chem., Int. Ed. 2017, 56, 5232–5236.
Shin, S. S.; Yeom, E. J.; Yang, W. S.; Hur, S.; Kim, M. G.; Im, J.; Seo, J.; Noh, J. H.; Seok, S. I. Colloidally prepared La-doped BaSnO3 electrodes for efficient, photostable perovskite solar cells. Science 2017, 356, 167–171.
You, P.; Liu, Z. K.; Tai, Q. D.; Liu, S. H.; Yan, F. Efficient semitransparent perovskite solar cells with graphene electrodes. Adv. Mater. 2015, 27, 3632–3638.
Lee, K.-T.; Jang, J.-Y.; Park, S. J.; Ok, S. A.; Park, H. J. Incident-angle-controlled semitransparent colored perovskite solar cells with improved efficiency exploiting a multilayer dielectric mirror. Nanoscale 2017, 9, 13983–13989.
Lu, J.-H.; Yu, Y.-L.; Chuang, S.-R.; Yeh, C.-H.; Chen, C.-P. High-performance, semitransparent, easily tunable vivid colorful perovskite photovoltaics featuring Ag/ITO/Ag microcavity structures. J. Phys. Chem. C 2016, 120, 4233–4239.
Lee, K.-T.; Fukuda, M.; Joglekar, S.; Guo, L. J. Colored, see-through perovskite solar cells employing an optical cavity. J. Mater. Chem. C 2015, 3, 5377–5382.
Lee, K.-T.; Guo, L. J.; Park, H. J. Neutral- and multi-colored semitransparent perovskite solar cells. Molecules 2016, 21, 475.
Eperon, G. E.; Burlakov, V. M.; Goriely, A.; Snaith, H. J. Neutral color semitransparent microstructured perovskite solar cells. ACS Nano 2014, 8, 591–598.
Lee, K.-T.; Lee, J. Y.; Xu, T.; Park, H. J.; Guo, L. J. Colored dual-functional photovoltaic cells. J. Opt. 2016, 18, 064003.
Guo, F.; Azimi, H.; Hou, Y.; Przybilla, T.; Hu, M. Y.; Bronnbauer, C.; Langner, S.; Spiecker, E.; Forberich, K.; Brabec, C. J. High-performance semitransparent perovskite solar cells with solution-processed silver nanowires as top electrodes. Nanoscale 2015, 7, 1642–1649.
Lee, K.-T.; Jang, J.-Y.; Zhang, J.; Yang, S.-M.; Park, S.; Park H. J. Highly efficient colored perovskite solar cells integrated with ultrathin subwavelength plasmonic nanoresonators. Sci. Rep. 2017, 7, 10640.
Noh, J. H.; Im, S. H.; Heo, J. H.; Mandal, T. N.; Seok, S. I. Chemical management for colorful, efficient, and stable inorganic–organic hybrid nanostructured solar cells. Nano Lett. 2013, 13, 1764–1769.
Ramírez Quiroz, C. O.; Bronnbauer, C.; Levchuk, I.; Hou, Y.; Brabec, C. J.; Forberich, K. Coloring semitransparent perovskite solar cells via dielectric mirrors. ACS Nano 2016, 10, 5104–5112.
Deng, Y. H.; Wang, Q.; Yuan, Y. B.; Huang, J. S. Vividly colorful hybrid perovskite solar cells by doctor-blade coating with perovskite photonic nanostructures. Mater. Horiz. 2015, 2, 578–583.
Jiang, Y. Y.; Luo, B. W.; Jiang, F. Y.; Jiang, F. B.; Fuentes-Hernandez, C.; Liu, T. F.; Mao, L.; Xiong, S. X.; Li, Z. F.; Wang, T. et al. Efficient colorful perovskite solar cells using a top polymer electrode simultaneously as spectrally selective antireflection coating. Nano Lett. 2016, 16, 7829–7835.
Lee, K.-T.; Seo, S.; Lee, J. Y.; Guo, L. J. Ultrathin metalsemiconductor-metal resonator for angle invariant visible band transmission filters. Appl. Phys. Lett. 2014, 104, 231112.
Lee, C.-C.; Chen, S.-H.; Jaing, C.-C. Optical monitoring of silver-based transparent heat mirrors. Appl. Opt. 1996, 35, 5698–5703.
Kim, H.; Lee, K.-T.; Zhao, C. M.; Guo, L. J.; Kanicki, J. Top illuminated organic photodetectors with dielectric/metal/dielectric transparent anode. Org. Electron. 2015, 20, 103–111.
Lee, K.-T.; Ji, C. G.; Banerjee, D.; Guo, L. J. Angularand polarization-independent structural colors based on 1D photonic crystals. Laser Photonics Rev. 2015, 9, 354–362.
Shrestha, V. R.; Lee, S.-S.; Kim, E.-S.; Choi, D.-Y. Noniridescent transmissive structural color filter featuring highly efficient transmission and high excitation purity. Sci. Rep. 2014, 4, 4921.
Park, C.-S.; Shrestha, V. R.; Lee, S.-S.; Kim, E.-S.; Choi, D.-Y. Omnidirectional color filters capitalizing on a nanoresonator of Ag-TiO2-Ag integrated with a phase compensating dielectric overlay. Sci. Rep. 2015, 5, 8467.
Park, C.-S.; Shrestha, V. R.; Lee, S.-S.; Choi, D.-Y. Transreflective color filters based on a phase compensated etalon enabling adjustable color saturation. Sci. Rep. 2016, 6, 25496.
Lee, K.-T.; Han, S. Y.; Park, H. J. Omnidirectional flexible transmissive structural colors with high-color-purity and high-efficiency exploiting multicavity resonances. Adv. Opt. Mater. 2017, 5, 1700284.
Acknowledgements
This work was supported by the Ministry of Trade, Industry and Energy (MOTIE, No. 10051565) and Korea Display Research Corporation (KDRC) support program for the development of future devices technology for display industry. This work was partially supported by the GRRC program of Gyeonggi province (GRRC AJOU 2016B03, Photonics-Medical Convergence Technology Research Center). This research was also supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (No. NRF-2017R1D1A1B03034711).
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Lee, KT., Jang, JY., Ha, N.Y. et al. High-performance colorful semitransparent perovskite solar cells with phase-compensated microcavities. Nano Res. 11, 2553–2561 (2018). https://doi.org/10.1007/s12274-017-1880-0
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DOI: https://doi.org/10.1007/s12274-017-1880-0