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Ternary NiCoP nanosheet arrays: An excellent bifunctional catalyst for alkaline overall water splitting

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Abstract

Exploring bifunctional catalysts for the hydrogen and oxygen evolution reactions (HER and OER) with high efficiency, low cost, and easy integration is extremely crucial for future renewable energy systems. Herein, ternary NiCoP nanosheet arrays (NSAs) were fabricated on 3D Ni foam by a facile hydrothermal method followed by phosphorization. These arrays serve as bifunctional alkaline catalysts, exhibiting excellent electrocatalytic performance and good working stability for both the HER and OER. The overpotentials of the NiCoP NSA electrode required to drive a current density of 50 mA/cm2 for the HER and OER are as low as 133 and 308 mV, respectively, which is ascribed to excellent intrinsic electrocatalytic activity, fast electron transport, and a unique superaerophobic structure. When NiCoP was integrated as both anodic and cathodic material, the electrolyzer required a potential as low as ~1.77 V to drive a current density of 50 mA/cm2 for overall water splitting, which is much smaller than a reported electrolyzer using the same kind of phosphide-based material and is even better than the combination of Pt/C and Ir/C, the best known noble metal-based electrodes. Combining satisfactory working stability and high activity, this NiCoP electrode paves the way for exploring overall water splitting catalysts.

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

    Yingjie Li, Haichuan Zhang, Ming Jiang, Yun Kuang, Xiaoming Sun & Xue Duan

  2. Institute for New Energy Materials & Low-Carbon Technologies, Tianjin University of Technology, Tianjin, 300384, China

    Xiaoming Sun

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  1. Yingjie Li
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  2. Haichuan Zhang
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  3. Ming Jiang
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  4. Yun Kuang
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  5. Xiaoming Sun
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Correspondence to Yun Kuang or Xiaoming Sun.

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Li, Y., Zhang, H., Jiang, M. et al. Ternary NiCoP nanosheet arrays: An excellent bifunctional catalyst for alkaline overall water splitting. Nano Res. 9, 2251–2259 (2016). https://doi.org/10.1007/s12274-016-1112-z

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