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Uniform MnO2 nanostructures supported on hierarchically porous carbon as efficient electrocatalysts for rechargeable Li-O2 batteries

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Abstract

Through in situ redox deposition and growth of MnO2 nanostructures on hierarchically porous carbon (HPC), a MnO2/HPC hybrid has been synthesized and employed as cathode catalyst for non-aqueous Li-O2 batteries. Owing to the mild synthetic conditions, MnO2 was uniformly distributed on the surface of the carbon support, without destroying the hierarchical porous nanostructure. As a result, the as-prepared MnO2/HPC nanocomposite exhibits excellent Li-O2 battery performance, including low charge overpotential, good rate capacity and long cycle stability up to 300 cycles with controlling capacity of 1,000 mAh·g−1. A combination of the multi-scale porous network of the shell-connected carbon support and the highly dispersed MnO2 nanostructure benefits the transportation of ions, oxygen and electrons and contributes to the excellent electrode performance.

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Authors and Affiliations

  1. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin, 300071, China

    Xiaopeng Han, Fangyi Cheng, Chengcheng Chen, Yuxiang Hu & Jun Chen

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  1. Xiaopeng Han
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  2. Fangyi Cheng
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  3. Chengcheng Chen
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  4. Yuxiang Hu
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  5. Jun Chen
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Correspondence to Fangyi Cheng or Jun Chen.

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Han, X., Cheng, F., Chen, C. et al. Uniform MnO2 nanostructures supported on hierarchically porous carbon as efficient electrocatalysts for rechargeable Li-O2 batteries. Nano Res. 8, 156–164 (2015). https://doi.org/10.1007/s12274-014-0604-y

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