Nano Research

, Volume 3, Issue 5, pp 326–338 | Cite as

Formation and optical properties of ZnO:ZnFe2O4 superlattice microwires

  • Yun Li
  • Guozhang Dai
  • Chunjiao Zhou
  • Qinglin Zhang
  • Qiang Wan
  • Limin Fu
  • Jianping Zhang
  • Ruibin Liu
  • Chuanbao Cao
  • Anlian Pan
  • Yunhong Zhang
  • Bingsuo Zou
Open Access
Research Article

Abstract

Pure ZnO hexagonal microwires and Fe(III)-doped ZnO microwires (MWs) with a novel rectangular cross section were synthesized in a confined chamber by a convenient one-step thermal evaporation method. An oriented attachment mechanism is consistent with a vapor-solid growth process. Photoluminescence (PL) and Raman spectroscopy of the Fe(III)-doped ZnO MWs and in situ spectral mappings indicate a quasi-periodic distribution of Fe(III) along a one-dimensional (1-D) superlattice ZnO:ZnFe2O4 wire, while PL mapping shows the presence of optical multicavities and related multimodes. The PL spectra at room temperature show weak near-edge doublets (376 nm and 383 nm) and a broad band (450–650 nm) composed of strong discrete lines, due to a 1-D photonic crystal structure. Such a 1-D coupled optical cavity material may find many applications in future photonic and spintronic devices.

Keywords

ZnO superlattice microwire micro-photoluminescence micro-Raman spectroscopy 

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Copyright information

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Yun Li
    • 1
  • Guozhang Dai
    • 1
    • 2
  • Chunjiao Zhou
    • 1
  • Qinglin Zhang
    • 1
  • Qiang Wan
    • 1
  • Limin Fu
    • 3
  • Jianping Zhang
    • 3
  • Ruibin Liu
    • 2
  • Chuanbao Cao
    • 2
  • Anlian Pan
    • 2
  • Yunhong Zhang
    • 2
  • Bingsuo Zou
    • 1
    • 2
  1. 1.State Key Laboratory of Chemo/biosensing and Chemometrics (CBSC)Hunan UniversityChangshaChina
  2. 2.School of Materials Science and Engineering (MSE)Beijing Institute of TechnologyBeijingChina
  3. 3.Chemistry DepartmentRenmin University of ChinaBeijingChina

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