Nano Research

, 2:903 | Cite as

Direct observation of the strong interaction between carbon nanotubes and quartz substrate

  • Lei Ding
  • Weiwei Zhou
  • Thomas P. McNicholas
  • Jinyong Wang
  • Haibin Chu
  • Yan Li
  • Jie Liu
Open Access
Research Article

Abstract

We present a chemical vapor deposition (CVD) method for the growth of uniform single-walled carbon nanotube (SWNT) arrays on a stable temperature (ST)-cut single crystal quartz substrate using a mixture of methanol and ethanol as carbon source. It is found that introducing methanol during the growth can improve the density and the length of the well-aligned SWNTs in the arrays as well as increase the SWNT/quartz interaction. Obvious “up-shifts” of G-band frequencies in the Raman spectra have been found for the aligned SWNTs. A welldesigned control experiment shows that the G-band “up-shifts” originate from the strong interaction between SWNTs and the quartz substrate. It is believed that exploring this interaction will help to elucidate the growth mechanism; ultimately, this will help realize the promise of controlling the chirality of SWNTs.

Keywords

Single-walled carbon nanotube quartz wafer Raman spectroscopy G-band “up-shift” chemical vapor deposition (CVD) 

Supplementary material

12274_2009_9093_MOESM1_ESM.pdf (433 kb)
Supplementary material, approximately 340 KB.

References

  1. [1]
    Kocabas, C.; Dunham, S.; Cao, Q.; Cimino, K.; Ho, X. N.; Kim, H. S.; Dawson, D.; Payne, J.; Stuenkel, M.; Zhang, H.; Banks, T.; Feng, M.; Rotkin, S. V.; Rogers, J. A. Highfrequency performance of submicrometer transistors that use aligned arrays of single-walled carbon nanotubes. Nano Lett. 2009, 9, 1937–1943.CrossRefPubMedADSGoogle Scholar
  2. [2]
    Kocabas, C.; Kim, H. S.; Banks, T.; Rogers, J. A.; Pesetski, A. A.; Baumgardner, J. E.; Krishnaswamy, S. V.; Zhang, H. Radio frequency analog electronics based on carbon nanotube transistors. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 1405–1409.CrossRefPubMedADSGoogle Scholar
  3. [3]
    Cao, Q.; Kim, H. S.; Pimparkar, N.; Kulkarni, J. P.; Wang, C. J.; Shim, M.; Roy, K.; Alam, M. A.; Rogers, J. A. Medium-scale carbon nanotube thin-film integrated circuits on flexible plastic substrates. Nature 2008, 454, 495–500.CrossRefPubMedADSGoogle Scholar
  4. [4]
    Cubukcu, E.; Degirmenci, F.; Kocabas, C.; Zimmler, M. A.; Rogers, J. A.; Capasso, F. Aligned carbon nanotubes as polarization-sensitive, molecular near-field detectors. Proc. Natl. Acad. Sci. U.S.A. 2009, 106, 2495–2499.CrossRefPubMedADSGoogle Scholar
  5. [5]
    Rao, S. G.; Huang, L.; Setyawan, W.; Hong, S. H. Largescale assembly of carbon nanotubes. Nature 2003, 425, 36–37.CrossRefPubMedADSGoogle Scholar
  6. [6]
    LeMieux, M. C.; Roberts, M.; Barman, S.; Jin, Y. W.; Kim, J. M.; Bao, Z. N. Self-sorted, aligned nanotube networks for thin-film transistors. Science 2008, 321, 101–104.CrossRefPubMedADSGoogle Scholar
  7. [7]
    Ural, A.; Li, Y. M.; Dai, H. J. Electric-field-aligned growth of single-walled carbon nanotubes on surfaces. Appl. Phys. Lett. 2002, 81, 3464–3466.CrossRefADSGoogle Scholar
  8. [8]
    Huang, S. M.; Maynor, B.; Cai, X. Y.; Liu, J. Ultralong, well-aligned single-walled carbon nanotube architectures on surfaces. Adv. Mater. 2003, 15, 1651–1655.CrossRefGoogle Scholar
  9. [9]
    Zhou, W. W.; Han, Z. Y.; Wang, J. Y.; Zhang, Y.; Jin, Z.; Sun, X.; Zhang, Y. W.; Yan, C. H.; Li, Y. Copper catalyzing growth of single-walled carbon nanotubes on substrates. Nano Lett. 2006, 6, 2987–2990.CrossRefPubMedADSGoogle Scholar
  10. [10]
    Ismach, A.; Segev, L.; Wachtel, E.; Joselevich, E. Atomic-step-templated formation of single wall carbon nanotube patterns. Angew. Chem. Int. Ed. 2004, 43, 6140–6143.CrossRefGoogle Scholar
  11. [11]
    Han, S.; Liu, X. L.; Zhou, C. W. Template-free directional growth of single-walled carbon nanotubes on a- and r-plane sapphire. J. Am. Chem. Soc. 2005, 127, 5294–5295.CrossRefPubMedGoogle Scholar
  12. [12]
    Kocabas, C.; Kang, S. J.; Ozel, T.; Shim, M.; Rogers, J. A. Improved synthesis of aligned arrays of single-walled carbon nanotubes and their implementation in thin film type transistors. J. Phys. Chem. C 2007, 111, 17879–17886.CrossRefGoogle Scholar
  13. [13]
    Kang, S. J.; Kocabas, C.; Ozel, T.; Shim, M.; Pimparkar, N.; Alam, M. A.; Rotkin, S. V.; Rogers, J. A. High-performance electronics using dense, perfectly aligned arrays of single-walled carbon nanotubes. Nat. Nanotechnol. 2007, 2, 230–236.CrossRefPubMedADSGoogle Scholar
  14. [14]
    Ding, L.; Yuan, D. N.; Liu, J. Growth of high-density parallel arrays of long single-walled carbon nanotubes on quartz substrates. J. Am. Chem. Soc. 2008, 130, 5428–5429.CrossRefPubMedGoogle Scholar
  15. [15]
    Yuan, D. N.; Ding, L.; Chu, H. B.; Feng, Y. Y.; McNicholas, T. P.; Liu, J. Horizontally aligned single-walled carbon nanotube on quartz from a large variety of metal catalysts. Nano Lett. 2008, 8, 2576–2579.CrossRefPubMedADSGoogle Scholar
  16. [16]
    Zhou, W. W.; Rutherglen, C.; Burke, P. J. Wafer scale synthesis of dense aligned arrays of single-walled carbon nanotubes. Nano Res. 2008, 1, 158–165.CrossRefGoogle Scholar
  17. [17]
    Ding, L.; Tselev, A.; Wang, J. Y.; Yuan, D. N.; Chu, H. B.; McNicholas, T. P.; Li, Y.; Liu, J. Selective growth of well-aligned semiconducting single-walled carbon nanotubes. Nano Lett. 2009, 9, 800–805.CrossRefPubMedADSGoogle Scholar
  18. [18]
    Kang, S. J.; Kocabas, C.; Kim, H. -S.; Cao, Q.; Meitl, M. A.; Khang, D.-Y.; Rogers, J. A. Printed multilayer superstructures of aligned single-walled carbon nanotubes for electronic applications. Nano Lett. 2007, 7, 3343–3348.CrossRefPubMedADSGoogle Scholar
  19. [19]
    McNicholas, T. P.; Ding, L.; Yuan, D. N.; Liu, J. Density enhancement of aligned single-walled carbon nanotube thin films on quartz substrates by sulfur-assisted synthesis. Nano Lett. 2009, in press, DOI: 10/1021/ nl901890x.Google Scholar
  20. [20]
    Rutherglen, C.; Burke, P. J. Nano-electromagnetics: Circuit and electromagnetic properties of carbon nanotubes. Small 2009, 5, 884–906.CrossRefPubMedGoogle Scholar
  21. [21]
    Dresselhaus, M. S.; Dresselhaus, G.; Saito, R.; Jorio, A. Raman spectroscopy of carbon nanotubes. Phys. Rep. 2005, 409, 47–99.CrossRefADSGoogle Scholar
  22. [22]
    Rohrl, J.; Hundhausen, M.; Emtsev, K. V.; Seyller, Th.; Graupner, R.; Ley, L. Raman spectra of epitaxial graphene on SiC(0001). Appl. Phys. Lett. 2008, 92, 201918.CrossRefADSGoogle Scholar
  23. [23]
    Ozel, T.; Abdula, D.; Hwang, E.; Shim, M. Nonuniform compressive strain in horizontally aligned single-walled carbon nanotubes grown on single crystal quartz. ACS Nano 2009, 3, 2217–2224.CrossRefPubMedGoogle Scholar

Copyright information

© Tsinghua University Press and Springer Berlin Heidelberg 2009

Authors and Affiliations

  • Lei Ding
    • 1
  • Weiwei Zhou
    • 1
  • Thomas P. McNicholas
    • 1
  • Jinyong Wang
    • 2
  • Haibin Chu
    • 2
  • Yan Li
    • 2
  • Jie Liu
    • 1
  1. 1.Department of ChemistryDuke UniversityDurhamUSA
  2. 2.Beijing National Laboratory for Molecular Sciences, Key Laboratory for the Physics and Chemistry of Nanodevices, National Laboratory of Rare Earth Material Chemistry and Application, College of Chemistry and Molecular EngineeringPeking UniversityBeijingChina

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