Skip to main content
Log in

Effect of Aged Lubricating Oil on the Regeneration of Diesel Particulate Filters and Ash Physical Characteristics with Non-Thermal Plasma Technology

  • Published:
International Journal of Automotive Technology Aims and scope Submit manuscript

Abstract

The objective of this study was to evaluate the effects of lubricating oil age on the generation of diesel particulate filters (DPF) by non-thermal plasma (NTP) technology and to characterize the physical properties of ash. The regeneration status was evaluated by the concentration of regeneration products and regeneration temperature. The compositional and morphological characteristics of ash were analyzed by energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Compared with DPF@L-fresh, the internal regeneration temperature was reduced in DPF@L-age. The unit removal time of carbon was 39.23 min/g for DPF@L-fresh but was reduced to 34.87 min/g for DPF@L-age, which indicated that the efficiency of NTP regeneration increased. Shorter regeneration time and lower airflow resistance caused by NTP technology aided the formation of a unique chain-type ash with the structure of a hollow column. Several fine particles that had formed by the condensation of volatiles were distributed on the ash surface of the aged lubricant, and the ash clusters were loosely combined. TEM images revealed that ash was mostly composed of a crystal structure, that the ash dimension of aged lubricant decreased, and that the adhesion between ash particulates was weak.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Andrews, G. E., Abdelhalim, S. M. and Li, H. (1999). The influence of lubricating oil age on oil quality and emissions from IDI passenger car diesels. SAE Technical Paper No. 1999-01-1135.

  • Babaie, M., Davari, P., Talebizadeh, P., Zare, F., Rahimzadeh, H., Ristovski, Z. and Brown, R. (2015). Performance evaluation of non-thermal plasma on particulate matter, ozone and CO2 correlation for diesel exhaust emission reduction. Chemical Engineering J., 276, 240–248.

    Article  Google Scholar 

  • Balabin, R. M. and Safieva, R. Z. (2008). Motor oil classification by base stock and viscosity based on near infrared (NIR) spectroscopy data. Fuel 87, 12, 2745–2752.

    Article  Google Scholar 

  • Beatrice, C., Di Iorio, S., Guido, C. and Napolitano, P. (2012). Detailed characterization of particulate emissions of an automotive catalyzed DPF using actual regeneration strategies. Experimental Thermal and Fluid Science, 39, 45–53.

    Article  Google Scholar 

  • Braga, J. W. B., dos Santos Junior, A. A. and Martins, I. S. (2014). Determination of viscosity index in lubricant oils by infrared spectroscopy and PLSR. Fuel, 120, 171–178.

    Article  Google Scholar 

  • Buhre, B. J., Hinkley, J. T., Gupta, R. P., Wall, T. F. and Nelson, P. F. (2005). Submicron ash formation from coal combustion. Fuel 84, 10, 1206–1214.

    Article  Google Scholar 

  • Burnete, N. V., Balint, R. J., Măgherusan, C. A. and Moldovanu, D. (2020). Performance, combustion and emissions study of a di diesel engine running on several types of diesel fuels. The 30th SIAR Int. Cong. Automotive and Transport Engineering: Science and Management of Automotive and Transportation Engineering 153–159.

  • Chaobing, Z., Lizhong, S. and Yu, Z. (2019). Technology roadmap of DPF after-treatment for diesel application to meet the emission regulation above china VI. Agricultural Equipment & Vehicle Engineering.

  • Choi, S. and Seong, H. (2015). Oxidation characteristics of gasoline direct-injection (GDI) engine soot: catalytic effects of ash and modified kinetic correlation. Combustion and Flame 162, 6, 2371–2389.

    Article  Google Scholar 

  • Choi, S. and Seong, H. (2016). Lube oil-dependent ash chemistry on soot oxidation reactivity in a gasoline direct-injection engine. Combustion and Flame, 174, 68–76.

    Article  Google Scholar 

  • Fan, R., Cai, Y., Shi, Y. and Cui, Y. (2018). Effect of the reaction temperature on the removal of diesel particulate matter by ozone injection. Plasma Chemistry and Plasma Proc. 39, 1, 143–163.

    Article  Google Scholar 

  • Fang, J., Meng, Z., Li, J., Pu, Y., Du, Y., Li, J., Jin, Z., Chen, C. and Chase, G. G. (2017). The influence of ash on soot deposition and regeneration processes in diesel particular filter. Applied Thermal Engineering, 124, 633–640.

    Article  Google Scholar 

  • Fang, J., Zhang, Q., Meng, Z., Luo, Y., Ou, J., Du, Y. and Zhang, Z. (2020). Effects of ash composition and ash stack heights on soot deposition and oxidation processes in catalytic diesel particulate filter. J. Energy Institute 93, 5, 1942–1950.

    Article  Google Scholar 

  • Guan, B., Zhan, R., Lin, H. and Huang, Z. (2015). Review of the state-of-the-art of exhaust particulate filter technology in internal combustion engines. J. Environmental Management, 154, 225–258.

    Article  Google Scholar 

  • Hao, Y., Gao, C., Deng, S., Yuan, M., Song, W., Lu, Z. and Qiu, Z. (2019). Chemical characterisation of PM_(2.5) emitted from motor vehicles powered by diesel, gasoline, natural gas and methanol fuel. Science of the Total Environment, 674, 128–139.

    Article  Google Scholar 

  • Haralampous, O. and Koltsakis, G. C. (2002). Intra-layer temperature gradients during regeneration of diesel particulate filters. Chemical Engineering Science 57, 13, 2345–2355.

    Article  Google Scholar 

  • Kamp, C. J., Sappok, A., Wang, Y., Bryk, W., Rubin, A. and Wong, V. (2014). Direct measurements of soot/ash affinity in the diesel particulate filter by atomic force microscopy and implications for ash accumulation and dpf degradation. SAE Int. J. Fuels and Lubricants 7, 1, 307–316.

    Article  Google Scholar 

  • Kral Jr, J., Konecny, B., Kral, J., Madac, K., Fedorko, G. and Molnar, V. (2014). Degradation and chemical change of longlife oils following intensive use in automobile engines. Measurement, 50, 34–42.

    Article  Google Scholar 

  • Kuwahara, T., Nishii, S., Kuroki, T. and Okubo, M. (2013). Complete regeneration characteristics of diesel particulate filter using ozone injection. Applied energy, 111, 652–656.

    Article  Google Scholar 

  • Kuwahara, T., Yoshida, K., Kuroki, T., Hanamoto, K., Sato, K. and Okubo, M. (2020). Pilot-scale combined reduction of accumulated particulate matter and nox using nonthermal plasma for marine diesel engine. IEEE Trans. Industry Applications 56, 2, 1804–1814.

    Article  Google Scholar 

  • Liati, A., Eggenschwiler, P. D., Gubler, E. M., Schreiber, D. and Aguirre, M. (2012). Investigation of diesel ash particulate matter: A scanning electron microscope and transmission electron microscope study. Atmospheric Environment, 49, 391–402.

    Article  Google Scholar 

  • McGeehan, J., Yeh, S., Rutherford, J., Couch, M., Otterholm, B., Hinz, A. and Walker, A. (2009). Analysis of DPF incombustible materials from volvo trucks using DPF-SCR-Urea with API CJ-4 and API CI-4 PLUS Oils. SAE Int. J. Fuels and Lubricants 2, 1, 762–780.

    Article  Google Scholar 

  • Muramatsu, T., Kominami, T., Minamikawa, J., Matsunami, M., Komatsu, J. and Ozawa, J. (2006). DPR with empirical formula to improve active regeneration of a pm filter. SAE Technical Paper No. 2006-01-0878.

  • Okubo, M., Arita, N., Kuroki, T., Yoshida, K. and Yamamoto, T. (2008). Total Diesel Emission Control Technology Using Ozone Injection and Plasma Desorption. Plasma Chemistry and Plasma Proc. 28, 2, 173–187.

    Article  Google Scholar 

  • Okubo, M., Kuroki, T., Kawasaki, S., Yoshida, K. and Yamamoto, T. (2009). Continuous regeneration of ceramic particulate filter in stationary diesel engine by nonthermal-plasma-induced ozone injection. IEEE Trans. Industry Applications 45, 5, 1568–1574.

    Article  Google Scholar 

  • Palma, V., Ciambelli, P., Meloni, E. and Sin, A. (2015). Catalytic DPF microwave assisted active regeneration. Fuel, 140, 50–61.

    Article  Google Scholar 

  • Sappok, A., Munnis, S. and Wong, V. W. (2012). Individual and synergistic effects of lubricant additive components on diesel particulate filter ash accumulation and performance. Proc. ASME Internal Combustion Engine Division Spring Technical Conf. Torino, Piemonte, Italy.

  • Sappok, A., Wang, Y., Wang, R. Q., Kamp, C. and Wong, V. (2014). Theoretical and experimental analysis of ash accumulation and mobility in ceramic exhaust particulate filters and potential for improved ash management. SAE Int. J. Fuels and Lubricants 7, 2, 511–524.

    Article  Google Scholar 

  • Sappok, A. and Wong, V. (2010). Ash effects on diesel particulate filter pressure drop sensitivity to soot and implications for regeneration frequency and dpf control. SAE Int. J. Fuels and Lubricants 3, 1, 380–396.

    Article  Google Scholar 

  • Sappok, A. and Wong, V. W. (2011). Lubricant-derived ash properties and their effects on diesel particulate filter pressure-drop performance. J. Engineering for Gas Turbines and Power 133, 3, 032805.

    Article  Google Scholar 

  • Shi, Y., Cai, Y., Wang, J., Pu, X. and Linbo, G. (2017). Influence of PM size distribution and ingredients on dpf regeneration by non-thermal plasma technology. Plasma Chemistry and Plasma Proc. 37, 2, 451–464.

    Article  Google Scholar 

  • Shi, Y. X., Cai, Y. X., Li, X. H., Chen, Y. Y., Ding, D. W. and Tang, W. (2014). Meachanism and method of DPF regeneration by oxygen radical generated by NTP technology. Int. J. Automotive Technology 15, 6, 871–876.

    Article  Google Scholar 

  • Tan, P. Q., Duan, L. S., Li, E. F., Hu, Z. Y. and Lou, D. M. (2020). Experimental study on the temperature characteristics of a diesel particulate filter during a drop to idle active regeneration process. Applied Thermal Engineering, 178, 115628.

    Article  Google Scholar 

  • Wang, P., Gu, W., Lei, L., Cai, Y. and Li, Z. (2015). Microstructural and components evolution mechanism of particular matter from diesel engines with non-thermal plasma technology. Applied Thermal Engineering, 91, 1–10.

    Article  Google Scholar 

  • Wang, Y., Kamp, C. J., Wang, Y., Toops, T. J., Su, C., Wang, R., Gong, J. and Wong, V. W. (2020). The origin, transport, and evolution of ash in engine particulate filters. Applied Energy, 263, 114631.

    Article  Google Scholar 

  • Yao, S., Shen, X., Zhang, X., Han, J., Wu, Z., Tang, X., Lu, H. and Jiang, B. (2017). Sustainable removal of particulate matter from diesel engine exhaust at low temperature using a plasma-catalytic method. Chemical Engineering J., 327, 343–350.

    Article  Google Scholar 

  • Youngk, R. D. (2000). Automobile engine reliability, maintainability and oil maintenance. Annual Reliability and Maintainability Symp. 2000 Proc. Int. Symp. Product Quality and Integrity. Los Angeles, CA, USA.

Download references

Acknowledgement

This work is currently supported by the National Natural Science Foundation of China (No. 51806085, 51676089), China Postdoctoral Science Foundation (2018M642175), Jiangsu Planned Projects for Postdoctoral Research Fund (2018K 101C) and the Double Innovation talents of Jiangsu Province.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yunxi Shi.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, N., Cai, Y., Shi, Y. et al. Effect of Aged Lubricating Oil on the Regeneration of Diesel Particulate Filters and Ash Physical Characteristics with Non-Thermal Plasma Technology. Int.J Automot. Technol. 22, 1189–1200 (2021). https://doi.org/10.1007/s12239-021-0105-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12239-021-0105-4

Key Words

Navigation