Abstract
The utilization of biosynthesis in the production of copper oxide nanoparticles from ‘Urtica Dioica’ (UD) leaves is gaining increasing global popularity due to its sustainable, efficient, and cost-effective nature. In this study, copper nitrate served as the precursor for obtaining the copper oxide (CuO) nanoparticles. The focus of the research was on the development of bio-epoxy and a hybrid bio-epoxy/Ramie fiber-based laminate with the incorporation of copper oxide nanoparticles. To create the bio-epoxy-based organic fiber materials, the hand-layup molding process was adapted, with different quantities of nanoCuO particles (ranging from 0 to 7.5 wt%) being added. The study comprehensively examined the mechanical, physical, and thermal effects of incorporating fibers of a uniform 30 mm size into the green epoxy laminate. The characterization of the produced CuO nanoparticles was conducted through various analytical techniques, including UV spectroscopy (UVS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). Notably, the absorption peaks at 234 and 362 nm were attributed to the inter-band transitions of the core electrons within the copper metal present in CuO nanoparticles. Furthermore, the XRD pattern indicated an average crystallite size of the synthesized nanoparticles at 7.34 nm, while the strong bands in the FTIR spectrum at 916, 797, and 743 cm–1 provided evidence of phenolic and alcoholic compounds within the leaf extract. Mechanical testing revealed significant improvements in the tensile strength (72 MPa to 167 MPa), bending strength (26.41 MPa to 56.18 MPa), hardness (27.82 to 34.1 Barcol), and Izod impact strength (3.86 kJ/m2 to 12.01 kJ/m2) characteristics of all integrated hybrid fibers with the inclusion of nanopowder up to 4.5 wt%. Consequently, the mechanical properties of the fiber were enhanced, and the temperature-dependent behaviors of the storage modulus, loss modulus, and damping factor (tan δ) showed favorable changes. This enhanced stiffness and durability within the fiber series can be attributed to their improved load-bearing and stress-distribution capabilities within the biocomposites. Furthermore, the effective dispersion and strong matrix/nanoCuO/ramie fiber adhesion contributed to the creation of a robust structure, resulting in improved mechanical and temperature-dependent properties and ultimately addressing the thermal performance issues associated with Ramie fibers.
Similar content being viewed by others
Data and Code Availability
The data used to support the findings of this study are included in the article. Should further data or information be required, these are available from the corresponding author upon request.
References
L. Medina, R. Schledjewski, A.K. Schlarb, Compos. Sci. Technol. 69, 1404 (2009)
P. Balakrishnan, M. J. John, L. Pothen, M. S. Sreekala, and S. Thomas, in Advanced Composite Materials for Aerospace Engineering (Elsevier, 2016), pp. 365–383
C.S. Boland, R. De Kleine, G.A. Keoleian, E.C. Lee, H.C. Kim, T.J. Wallington, J. Ind. Ecol. 20, 179 (2016)
V. Ganesan, V. Shanmugam, B. Kaliyamoorthy, S. Sanjeevi, S.K. Shanmugam, V. Alagumalai, Y. Krishnamoorthy, M. Försth, G. Sas, S.M.J. Razavi, O. Das, Polymers 13, 2471 (2021)
M. R. Mansor, A. H. Nurfaizey, N. Tamaldin, and M. N. A. Nordin, in Biomass, Biopolymer-Based Materials, and Bioenergy (Elsevier, 2019), pp. 203–224
Ç. Gül, E.D. Kocak, Sustain. Des. Text. Fash. (2021). https://doi.org/10.1007/978-981-16-2466-7_2
J. Zhang, C. Guan, W.-H. Kang, L. Tong, Q. Xue, Compos. Struct. 202, 967 (2018)
Y. Du, N. Yan, and M. T. Kortschot, in Biofiber Reinforcements in Composite Materials (Elsevier, 2015), pp. 104–137
B. K. Hadi and Y. S. Nuril, in J Phys Conference Series (IOP Publishing, 2018), p. 12006
K. Kapila, S. Samanta, and S. Kirtania, in Recent advances in mechanical engineering: select proceedings of ICRAME 2020 (Springer, 2021), pp. 839–848
S. Habibie, N. Suhendra, B.A. Setiawan, M. Hamzah, N. Aisah, D.A. Fitriani, R. Tasomara, M. Anggaravidya, Int. Jf Compos. Mater. 11, 43 (2021)
D. Rajesh, N. Lenin, R. Cep, P. Anand, M. Elangovan, Polymers 14, 4887 (2022)
X. Song, F. Song, X.-M. Ding, J.-M. Wu, X.-H. Wang, F. Wang, R. Feng, X.-L. Wang, Y.-Z. Wang, Ind. Crops Prod. 194, 116281 (2023)
Y. Sun, L. Bao, C. Luo, A. Xu, C. Chen, Ind. Crops Prod. 187, 115525 (2022)
A. N. Netravali, Natural Fibers, Plastics and Composites 321 (2004)
D. Letchumanan, S. P. M. Sok, S. Ibrahim, N. H. Nagoor, and N. M. Arshad, (2021)
A. Saravanan, P.S. Kumar, S. Karishma, D.-V.N. Vo, S. Jeevanantham, P.R. Yaashikaa, C.S. George, Chemosphere 264, 128580 (2021)
P. Manogar, J.E. Morvinyabesh, P. Ramesh, G.D. Jeyaleela, V. Amalan, J.S. Ajarem, A.A. Allam, J.S. Khim, N. Vijayakumar, Mater. Lett. 311, 131569 (2022)
N. Rabiee, M. Bagherzadeh, M. Kiani, A. M. Ghadiri, F. Etessamifar, A. H. Jaberizadeh, A. Shakeri (2020)
A.A. Bhutto, J.A. Baig, T.G. Kazi, R. Sierra-Alvarez, K. Akhtar, S. Perveen, H.I. Afridi, H.E. Ali, A. Hol, S. Samejo, Ceram. Int. 55, 3345–3358 (2023)
O.J. Gbadeyan, S. Adali, G. Bright, B. Sithole, P. Lekha, J. Compos. Mater. 55, 3345 (2021)
H. S. Devi, M. A. Boda, S. Rubab, S. Parveen, A. H. Wani, M. A. Shah, Biosynthesis and Antifungal Activities of CuO and Al2O3 Nanoparticles, 1st ed. (Elsevier B.V., 2021)
V. Ganesan and B. Kaliyamoorthy, J. Nat Fibers (2020).
S. Rajeshkumar, N.T. Nandhini, K. Manjunath, P. Sivaperumal, G.K. Prasad, S.S. Alotaibi, S.M. Roopan, J. Mol. Struct. 1242, 130724 (2021)
S.K. Karuppannan, R. Ramalingam, S.B. Mohamed Khalith, M.J.H. Dowlath, G.I. Darul Raiyaan, K.D. Arunachalam, Biocatal. Agricult. Biotechnol. 31, 101904 (2021)
B. Sundararajan, G. Mahendran, R. Thamaraiselvi, B.D. Ranjith Kaumari, Bull. Mater. Sci. 39, 423 (2016)
K. Saravanakumar, S. Shanmugam, N.B. Varukattu, D. MubarakAli, K. Kathiresan, M.-H. Wang, J. Photochem. Photobiol. B. 190, 103 (2019)
E. Nagaraj, K. Karuppannan, P. Shanmugam, S. Venugopal, J. Cluster Sci. 30, 1157 (2019)
P. Kuppusamy, S. Ilavenil, S. Srigopalram, G.P. Maniam, M.M. Yusoff, N. Govindan, K.C. Choi, J. Clean. Prod. 141, 1023 (2017)
M. Garg, G.H. Abumeri, F. Abdi, Mater. Eval. 68, 542 (2010)
X. Yang, Y. Sun, D. Shi, J. Liu, Mater. Sci. Eng. A 528, 4830 (2011)
T. Ahmad, R. Ahmad, M. Kamran, B. Wahjoedi, I. Shakoor, F. Hussain, F. Riaz, Z. Jamil, S. Isaac, Q. Ashraf, Iran. Polym. J. 24, 21 (2015)
M. Radetić, D. Marković, Cellulose 26, 8971 (2019)
M.K. Hassanzadeh-Aghdam, M. Hasanzadeh, R. Ansari, Iranian Journal of Science and Technology. Trans. Mech. Eng. 44, 299 (2020)
G. Demircan, M. Kisa, M. Ozen, B. Aktas, Iran. Polym. J. 29, 253 (2020)
T. Uygunoğlu, B. Şimşek, Ö.B. Ceran, Ö. Eryeşil, J. Build. Eng. 44, 102641 (2021)
N.M. Barkoula, B. Alcock, N.O. Cabrera, T. Peijs, Polym. Polym. Compos. 16, 101 (2008)
V. G., J. S. Chohan, M. A. S. A., S. R., S. M. S., N. M., S. K. S., S. S. V., and E. R. D., Silicon (2023)
P. Khalili, B. Blinzler, R. Kádár, R. Bisschop, M. Försth, P. Blomqvist, Materials 12, 2648 (2019)
O.B. Gutiérrez-Acosta, S. Arriaga, V.A. Escobar-Barrios, S. Casas-Flores, A. Almendarez-Camarillo, J. Hazard. Mater. 201–202, 202 (2012)
C. Xia, J. Yu, S.Q. Shi, Y. Qiu, L. Cai, H.F. Wu, H. Ren, X. Nie, H. Zhang, Compos. B Eng. 114, 121 (2017)
T. Singh, B. Gangil, L. Ranakoti, A. Joshi, Polym. Compos. 42, 2396 (2021)
M.S. Chowdary, G. Raghavendra, M.S.R.N. Kumar, S. Ojha, V. Boggarapu, SILICON 14, 539 (2022)
R. Rajasekar, K. Pal, G. Heinrich, A. Das, C.K. Das, Mater. Des. 30, 3839 (2009)
V. G and N. L, Journal of Materials Research and Technology (2023)
G. Velmurugan and K. Babu, Materials Research Express 7, (2020)
M. Rajaei, N.K. Kim, S. Bickerton, D. Bhattacharyya, Compos. B Eng. 165, 65 (2019)
A. Atmakuri, A. Palevicius, A. Vilkauskas, and G. Janusas, Polymers 12, (2020)
S. Sanjeevi, V. Shanmugam, S. Kumar, V. Ganesan, G. Sas, D.J. Johnson, M. Shanmugam, A. Ayyanar, K. Naresh, R.E. Neisiany, O. Das, Sci. Rep. 11, 1 (2021)
V. Alagumalai, V. Shanmugam, N.K. Balasubramanian, Y. Krishnamoorthy, V. Ganesan, M. Försth, G. Sas, F. Berto, A. Chanda, O. Das, Polymers 13, 2591 (2021)
A. D. Latha, A. S. Kumar, S. J. Singh, and C. Velmurugan, Silicon (2023)
W.A.A. Sadik, A.G.M. El Demerdash, R. Abbas, A. Bedir, J. Polym. Environ. 29, 1600 (2021)
G. Rajeshkumar, S.A. Seshadri, S. Ramakrishnan, M.R. Sanjay, S. Siengchin, K.C. Nagaraja, Polym. Compos. 42, 3687 (2021)
N. Lakshmaiya, V. Ganesan, P. Paramasivam, S. Dhanasekaran, Appl Sci (Switzerland) 12, 13030 (2022)
V. G, S. S. V, K. R. M, E. R. D, N. M, and N. T J, Silicon (2023).
S. D. Ambekar and V. K. Tripathi, (n.d.).
F. Ashenai Ghasemi, A. Ghorbani, I. Ghasemi, Mech. Compos. Mater. 53, 131 (2017)
N. Lakshmaiya, S. Kaliappan, P.P. Patil, V. Ganesan, J.A. Dhanraj, C. Sirisamphanwong, T. Wongwuttanasatian, S. Chowdhury, S. Channumsin, M. Channumsin, K. Techato, Coatings 12, 1675 (2022)
A. Etaati, S. Pather, Z. Fang, H. Wang, Compos. B Eng. 62, 19 (2014)
K.M. Almgren, E.K. Gamstedt, Compos. Interfaces 17, 845 (2010)
G. Velmurugan, K. Babu, M. Nagaraj, and A. J. P. Kumar, Silicon (2023)
L.A. Pothan, Z. Oommen, S. Thomas, Compos. Sci. Technol. 63, 283 (2003)
S. Dong, R. Gauvin, Polym. Compos. 14, 414 (1993)
Acknowledgements
The authors would like to thank the Institute of Agricultural Engineering, Saveetha School of Engineering (SIMATS), Tamil Nadu, India for the technical assistance.
Funding
No funding was received for this research work.
Author information
Authors and Affiliations
Contributions
GV and SSK: conceptualization and methodology. JSC, TM, and AJPK: experimental design. DER and KS: investigation. MN and PB: testing and evaluations.
Corresponding author
Ethics declarations
Conflicts of Interest
The authors declare no competing interests.
Ethics Approval
Not applicable.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Velmurugan, G., Kumar, S.S., Chohan, J.S. et al. Experimental Investigations of Mechanical and Dynamic Mechanical Analysis of Bio-synthesized CuO/Ramie Fiber-Based Hybrid Biocomposite. Fibers Polym 25, 587–606 (2024). https://doi.org/10.1007/s12221-023-00432-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-023-00432-0