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Scavenging Mechanism of Textile Dyes in Water by Enol-Keto Tautomerism Covalent Organic Framework/Chitosan Composites

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Abstract

In view of the serious environmental pollution caused by organic dyestuff in textile printing and dyeing wastewater, a kind of covalent organic framework (COF) with high water stability—TpPa COF was synthesized by a combination of reversible Schiff-base reaction and irreversible enol-keto tautomerism. The TpPa COF was mechanically blended with chitosan (CS) and was used as a composite adsorbent, i.e., TpPa COF/CS. The aqueous solutions containing acid mordant brown (AMB) dye and methylene blue (MB) dye were employed to simulate anionic and cationic dyeing wastewater, respectively. The adsorption mechanism of TpPa COF/CS composites for the anionic and cationic dyes was investigated and the adsorption thermodynamics and kinetics were studied. The TpPa COF/CS composites (WCOF/WCS: 1/4 and 2/1) exhibited high adsorbing capacities (qmax: 1287.6 and 831.3 mg/g) for AMB and MB dyes at initial pH 4.0 and 9.0, respectively. The adsorption kinetics of both the ionic dyes followed the pseudo-second-order kinetic model well. In addition, the adsorption isotherms of both the dyes fitted well with Langmuir model. The COF/CS composite adsorbent was a promising economical material for the removal of ionic dyes from aqueous solutions.

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Acknowledgements

This work was financially supported by Technological Research Project for Public Welfare of Zhejiang Province (LGG18B070002; LGG21E030005; LGG22E030002), Postdoctoral Research Program of Zhejiang Province of China (276089), and Project of Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province (QJRZ1902).

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Authors and Affiliations

  1. College of Textiles and Apparel, Shaoxing University, Shaoxing, 312000, China

    Zhihao Ji, Manli Li & Enqi Jin

  2. Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing, 312000, China

    Zhihao Ji & Manli Li

  3. Shaoxing Yongfeng Textile Printing and Dyeing Co. Ltd., Shaoxing, 312073, China

    Xiaohong Li

  4. College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, 312000, China

    Wensheng Linghu

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  1. Zhihao Ji
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Correspondence to Enqi Jin or Wensheng Linghu.

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Ji, Z., Li, M., Li, X. et al. Scavenging Mechanism of Textile Dyes in Water by Enol-Keto Tautomerism Covalent Organic Framework/Chitosan Composites. Fibers Polym 24, 2039–2053 (2023). https://doi.org/10.1007/s12221-023-00193-w

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