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Enhancing Performances of Polyamide 66 Short Fiber/Natural Rubber Composites via In Situ Vulcanization Reaction

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Abstract

This paper details a new method for improving the interfacial bonding between PA66 short fiber (PSF) and natural rubber (NR) by reaction of the methacrylic acid (MAA)-grafting-modified PSF with rubber during vulcanization. Carbon-carbon double bonds introduced to the SF surface by MAA grafting were opened, and a vulcanization reaction occurred between the modified PSF and rubber in the presence of sulfur. The chemical reactions were verified by FTIR and XPS. The processing rheological behaviors of the compounded composites were investigated by a rubber processing analyzer (RPA). The morphology of modified PSF was characterized by AFM and SEM. The improved interfacial bonding was confirmed by DMA, which enhanced deformational stress at definite elongation of the NR/PSF composites. The volume concentration of the MAA solution for grafting on the SF surface had a great influence on the interfacial bonding and mechanical properties of the composites; when the volume concentration was 30 %, the modified PSF-reinforced NR/CB had the best interfacial bonding and mechanical properties.

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Acknowledgments

This work is financially supported by the National Natural Science Foundation of China (51763004).

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Authors and Affiliations

  1. College of Materials & Metallurgy, Guizhou University, Guiyang, 550025, China

    Zhi Hao, Junqi Shen, Xiang Sheng, Zong Shen, Le Yang, Xuefeng Lu & Zhu Luo

  2. Gui Zhou Province Engineering Laboratory for Rubber Composite, Guiyang, 550025, China

    Xuefeng Lu & Zhu Luo

  3. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, China

    Qiang Zheng

Authors
  1. Zhi Hao
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  2. Junqi Shen
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  3. Xiang Sheng
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  4. Zong Shen
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  5. Le Yang
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  6. Xuefeng Lu
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  7. Zhu Luo
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  8. Qiang Zheng
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Correspondence to Zhu Luo or Qiang Zheng.

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Hao, Z., Shen, J., Sheng, X. et al. Enhancing Performances of Polyamide 66 Short Fiber/Natural Rubber Composites via In Situ Vulcanization Reaction. Fibers Polym 21, 392–398 (2020). https://doi.org/10.1007/s12221-020-9475-x

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  • DOI: https://doi.org/10.1007/s12221-020-9475-x

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