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Characterization and Application to Fiber Reinforced Composite of Catechol/polyethyleneimine Modified Polyester Fabrics by Mussel-inspiration

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Abstract

In order to nondestructively prepare polyamine modified polyethylene glycol terephthalate (PET) fabric, codeposition of catechol and polyethyleneimine onto PET fiber was conducted by the means of mussel-inspired method. The surface morphology, composition of woven fabric were investigated by FESEM and ATR-FTIR, XPS, respectively, whose results demonstrated successful modification has taken place on PET fiber surface. The TG-DSC data proved that the melting temperature and decomposition temperature increased from 253.78 °C and 394.08 °C to 255.01 C and 398.21 °C, respectively. The surface polarity was characterized through the dynamic contact angle. The results indicated that the fabric displayed optimal surface properties at the PEI-CA mass ratio of 1:1. The modified PET fabric was utilized to prepare the fiber reinforced epoxy composite and its mechanical performances including tensile, flexural and short beam shear strength were evaluated. The obtained results indicated that the interlaminar shear strength (ILSS) has been significantly improved by 57.02 %. The novel way to modify fabrics has great potential in recycling waste fabric for preparing fiber reinforced composite.

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Acknowledgments

This research was supported by the National Natural Science Foundation of China (No. 51678409, 51708406 and 51708407), the Science and Technology Plans of Tianjin (No. 18YFJLCG00110, 15ZCZDSF00880, 17PTSYJC00040, 18ZXJMTG00120, and 16PTGCCX00070), the Program for Innovative Research Team in University of Tianjin (No. TD13-5042) and the National Natural Science Foundation of Tianjin (No. 17JCQNJC08700).

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Authors and Affiliations

  1. State Key Laboratory of Separation Membranes and Membrane Processes/National Center for International Joint Research on Separation Membranes, Tiangong University, Tianjin, 300387, China

    Junfu Wei

  2. School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China

    Yuan Chen, Xiaoqing Wu & Hailiang Wu

  3. School of Chemistry and Chemical Engineering, Tiangong University, Tianjin, 300387, China

    Junfu Wei

  4. TianJin Engineering Center for Safety Evaluation of Water Quality & Safeguards Technology, Tianjin, 300387, China

    Junfu Wei

  5. Tianjin Dongqi Wind Turbine Blade Engineering Co., Ltd., Tianjin, 300387, China

    Hailiang Wu

Authors
  1. Yuan Chen
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  2. Xiaoqing Wu
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  3. Junfu Wei
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  4. Hailiang Wu
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Corresponding authors

Correspondence to Xiaoqing Wu or Junfu Wei.

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12221_2020_1161_MOESM1_ESM.pdf

Characterization and Application to Fiber Reinforced Composite of Catechol/polyethyleneimine Modified Polyester Fabrics by Mussel-inspiration

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Chen, Y., Wu, X., Wei, J. et al. Characterization and Application to Fiber Reinforced Composite of Catechol/polyethyleneimine Modified Polyester Fabrics by Mussel-inspiration. Fibers Polym 21, 2625–2634 (2020). https://doi.org/10.1007/s12221-020-1161-5

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  • DOI: https://doi.org/10.1007/s12221-020-1161-5

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