Skip to main content
Log in

Copper oxide-carbon nanotube (CuO/CNT) nanocomposite: Synthesis and photocatalytic dye degradation from colored textile wastewater

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

In this paper, CuO/CNT nanocomposite was synthesized and its photocatalytic dye degradation ability for colored textile wastewater was studied. The characteristics of the nanocomposite were investigated by XRD, SEM and FTIR. The photodegradation of Direct Red 31 (DR31) and Reactive Red 120 (RR120) by CuO/CNT in presence of H2O2 was investigated. Photocatalytic dye degradation was determined by UV-vis spectrophotometer. Effects of catalyst dosage, initial dye concentration and salt on photodegradation performance were studied. The photocatalytic dye degradation ability of pure CuO and CuO/CNT nanocomposite is 78 % and 89 % for DR31 and 70 % and 87 % for RR120, respectively. The results showed that CNT increased the photocatalytic activity of CuO. The presence of salt decreases dye degradation efficiency. The dye degradation kinetics by nanocomposite followed first-order kinetic model. The reaction rate at 0.005 g catalyst was 0.0137 and 0.0105 min-1 for DR31 and RR120, respectively. It was found that the CuO/CNT nanocomposite as a photocatalyst could be used to degrade dyes from colored wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. N. M. Mahmoodi, Environ. Monit. Assess., 186, 5595 (2014).

    Article  CAS  Google Scholar 

  2. N. M. Mahmoodi, Fiber. Polym., 15, 273 (2014).

    Article  CAS  Google Scholar 

  3. E. Kordouli, K. Bourikas, A. Lycourghiotis, and C. Kordulis, Catal. Today, 252, 128 (2015).

    Article  CAS  Google Scholar 

  4. K. Mageshwari, R. Sathyamoorthy, and J. Park, Powder Technol., 278, 150 (2015).

    Article  CAS  Google Scholar 

  5. I. K. Konstantinou and T. A. Albanis, Appl. Catal. B: Environ., 49, 1 (2004).

    Article  CAS  Google Scholar 

  6. K. Mageshwari, D. Nataraj, T. Pal, R. Sathyamoorthy, and J. Park, J. Alloys Compd., 625, 362 (2015).

    Article  CAS  Google Scholar 

  7. N. M. Mahmoodi, J. Environ. Eng., 139, 1382 (2013).

    Article  CAS  Google Scholar 

  8. N. M. Mahmoodi, J. Ind. Eng. Chem., 27, 251 (2015).

    Article  CAS  Google Scholar 

  9. N. M. Mahmoodi, J. Taiwan Inst. Chem. Eng., 45, 2008 (2014).

    Article  CAS  Google Scholar 

  10. N. M. Mahmoodi, J. Ind. Eng. Chem., 20, 2050 (2014).

    Article  CAS  Google Scholar 

  11. N. M. Mahmoodi, Water, Air, and Soil Pollution., 224, 1419 (2013).

    Article  Google Scholar 

  12. T. A. Saleh and V. K. Gupta, Environ. Sci. Pollut. Res., 19, 1224 (2012).

    Article  CAS  Google Scholar 

  13. A. Mittal, J. Mittal, A. Malviya, D. Kaur, and V. K. Gupta, J. Colloid Interface Sci., 342, 518 (2010).

    Article  CAS  Google Scholar 

  14. A. Mittal, J. Mittal, A. Malviya, and V. K. Gupta, J. Colloid Interface Sci., 344, 497 (2010).

    Article  CAS  Google Scholar 

  15. T. A. Saleh and V. K. Gupta, Adv. Colloid Interface Sci., 211, 93 (2014).

    Article  CAS  Google Scholar 

  16. V. K. Gupta, R. Kumar, A. Nayak, T. A. Saleh, and M. A. Barakat, Adv. Colloid Interface Sci., 193-194, 24 (2013).

    Article  CAS  Google Scholar 

  17. K. Zhang, N. Heo, X. Shi, and J. H. Park, J. Phys. Chem. C, 117, 24023 (2013).

    Article  CAS  Google Scholar 

  18. K. Zhang, F. J. Zhang, M. L. Chen, and W. C. Oh, Ultrasonics Sonochemistry, 18, 765 (2011).

    Article  CAS  Google Scholar 

  19. Y. L. Min, G. Q. He, Q. J. Xu, and Y. C. Chen, J. Mater. Chem. A, 2, 2578 (2014).

    Article  CAS  Google Scholar 

  20. Y. L. Min, G. Q. He, Q. J. Xu, and Y. C. Chen, J. Mater. Chem. A, 2, 1294 (2014).

    Article  CAS  Google Scholar 

  21. V. K. Gupta, R. Jain, A. Mittal, T. A. Saleh, A. Nayak, S. Agarwal, and S. Sikarwar, Mater. Sci. Eng. C, 32, 12 (2012).

    Article  CAS  Google Scholar 

  22. T. A. Saleh and V. K. Gupta, J. Colloid Interface Sci., 371, 101 (2012).

    Article  CAS  Google Scholar 

  23. S. Karthikeyan, V. K. Gupta, R. Boopathy, A. Titus, and G. Sekaran, J. Mol. Liquids, 173, 153 (2012).

    Article  CAS  Google Scholar 

  24. V. K. Gupta, I. Ali, T. A. Saleh, A. Nayak, and S. Agarwal, RSC Adv., 2, 6380 (2012).

    Article  CAS  Google Scholar 

  25. N. M. Mahmoodi, Desalin. Water Treat., 53, 84 (2015).

    Article  CAS  Google Scholar 

  26. N. M. Mahmoodi, J. Mol. Catal. A: Chem., 366, 254 (2013).

    Article  CAS  Google Scholar 

  27. N. M. Mahmoodi, J. Environ. Eng., 139, 1368 (2013).

    Article  CAS  Google Scholar 

  28. N. M. Mahmoodi, Water, Air, & Soil Pollution., 224, 1612 (2013).

    Article  Google Scholar 

  29. D. Sudha and P. Sivakumar, Chem. Eng. Process.: Process Inten., 97, 112 (2015).

    Article  CAS  Google Scholar 

  30. S. Sonia, S. Poongodi, P. S. Kumar, D. Mangalaraj, N. Ponpandian, and C. Viswanathan, Mater. Sci. Semicond. Process., 30, 585 (2015).

    Article  CAS  Google Scholar 

  31. S. Muthulingam, I. H. Lee, and P. Uthirakumar, J. Colloid Interface Sci., 455, 101 (2015).

    Article  CAS  Google Scholar 

  32. S. Maensiri, C. Masingboon, B. Boonchom, and S. Eraphin, Scripta Materialia, 56, 797 (2007).

    Article  CAS  Google Scholar 

  33. M. Mouallem-Bahout, S. Bertrand, and O. Pena, J. Solid State Chem., 178, 1080 (2005).

    Article  CAS  Google Scholar 

  34. D. L. Pavia, G. M. Lampman, and G. S. Kaiz, “Introduction to Spectroscopy: A Guide for Students of Organic Chemistry”, W.B Saunders Company, New York, 1987.

    Google Scholar 

  35. Y. B. Luo, Q. W. Yu, B. F. Yuan, and Y. Q. Feng, Talanta, 90, 123 (2012).

    Article  CAS  Google Scholar 

  36. T. T. Baby and S. Ramaprabhu, Talanta, 80, 2016 (2010).

    Article  CAS  Google Scholar 

  37. B. Li and Y. Wang, Superlatt. Microstruct., 47, 615 (2010).

    Article  CAS  Google Scholar 

  38. C. Yang, J. Wang, L. Mei, and X. Wang, J. Mater. Sci. Technol., 30, 1124 (2014).

    Article  CAS  Google Scholar 

  39. T. Liu, X. Li, X. Yuan, Y. Wang, and F. Li, J. Mol. Catal. A: Chem., 414, 122 (2016).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Niyaz Mohammad Mahmoodi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mahmoodi, N.M., Rezaei, P., Ghotbei, C. et al. Copper oxide-carbon nanotube (CuO/CNT) nanocomposite: Synthesis and photocatalytic dye degradation from colored textile wastewater. Fibers Polym 17, 1842–1848 (2016). https://doi.org/10.1007/s12221-016-6645-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-016-6645-y

Keywords

Navigation