Skip to main content
SpringerLink
Log in

Study on optimum coagulation conditions of high molecular weight pan fiber in wet spinning by orthogonal experimental design

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

Orthogonal experimental design (I) and (II) were used to study optimum coagulation technology in wet spinning of high molecular weight PAN nascent fiber. Relationship between shape factor (De) and coagulation conditions such as coagulation bath concentration, temperature, and minus draw ratio was investigated to obtain nascent fiber with the minimum De value and smooth surface morphology. The nascent PAN fiber fabricated at the conditions of 80 wt% coagulation bath concentration (in this paper, the coagulation bath concentration refers to the mass concentration of DMSO in coagulation bath), 0 % minus draw ratio, and 40 °C coagulation bath temperature has the smallest fiber diameter, the most circular cross sectional (minimum shape factor) and smooth surface morphology, and the maximum density, which resulted in the most excellent mechanical properties of nascent PAN fiber.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Chen, H. Y. Ge, X. G. Dong, and C. G. Wang, J. Appl. Polym. Sci., 106, 692 (2007).

    Article  CAS  Google Scholar 

  2. W. S. Lyoo, S. G. Lee, J. P. Kim, S. S. Han, and C. J. Lee, Colloid. Polym. Sci., 276, 951 (1998).

    Article  CAS  Google Scholar 

  3. A. K. Gupta, D. K. Paliwal, and P. Bajaj, J. Macromol. Sci. Rev. Macromol. Chem. Phys., C31, 1 (1991).

    CAS  Google Scholar 

  4. Showa, Japan Patent, 6312609 (1988).

  5. J. S. Tsai and C. H. Lin, J. Appl. Polym. Sci., 42, 3045 (1991).

    Article  CAS  Google Scholar 

  6. W. X. Zhang, “PAN-based Carbon Fiber”, pp.38–39, Donghua University Press, Shanghai, 2005.

    Google Scholar 

  7. Wilkinson and Kenneth, U. S. Patent, 5708111 (1996).

  8. M. Takahashi, Y. Nukushina, and S. Kosugi, Text. Res. J., 34, 87 (1964).

    Article  CAS  Google Scholar 

  9. J. P. Knudsen, Text. Res. J., 33, 13 (1963).

    CAS  Google Scholar 

  10. P. Bajaj, T. V. Sreekumar, and K. Sen, J. Appl. Polym. Sci., 86, 773 (2002).

    Article  CAS  Google Scholar 

  11. J. Mittal, R. B. Mathur, and O. P. Bahl, Carbon, 35, 1713 (1997).

    Article  CAS  Google Scholar 

  12. A. I. Stoyanov and V. P. Kpestev, J. Appl. Polym. Sci., 24, 583 (1979).

    Article  CAS  Google Scholar 

  13. J. S. Tsai and W. C. Su, J. Mater. Sci. Lett., 10, 1253 (1991).

    Article  CAS  Google Scholar 

  14. D. X. He, C. G. Wang, Y. J. Bai, and B. Zhu, J. Mater. Sci. Technol., 21, 376 (2005).

    CAS  Google Scholar 

  15. J. C. Chen and I. R. Harrison, Carbon, 40, 25 (2002).

    Article  CAS  Google Scholar 

  16. W. G. Cui, X. H. Li, S. B. Zhou, and J. Weng, J. Appl. Polym. Sci., 103, 3105 (2007).

    Article  CAS  Google Scholar 

  17. J. Zhang, F. J. Bu, Y. Q. Dai, L. W. Xue, Z. X. Xu, S. K. Ryu, and R. G. Jin, Carbon Letters, 11, 22 (2010).

    Article  Google Scholar 

  18. P. Bajaj and K. M. Surya, Text. Res. J., 60, 113 (1990).

    Article  CAS  Google Scholar 

  19. Y. D. Wang, C. X. Feng, J. Wang, Y. C. He, and Z. C. Zou, Silicone Materials and Applications, 6, 1 (1999).

    Google Scholar 

  20. W. X. Zhang, J. Liu, and G. Wu, Carbon, 41, 2805 (2003).

    Article  CAS  Google Scholar 

  21. G. Q. Peng, X. H. Zhang, Y. F. Wen, Y. G. Yang, and L. Liu, J. Macromol. Sci., Part B: Phys., 47, 1130 (2008).

    Article  CAS  Google Scholar 

  22. J. Chen, H. Y. Ge, H. S. Liu, G. Z. Li, and C. G. Wang, Journal of Wuhan University of Technology-Material Science Edition, 25, 200 (2010).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Department of Material Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

    Kai Yi & Riguang Jin

Authors
  1. Kai Yi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Riguang Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kai Yi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yi, K., Jin, R. Study on optimum coagulation conditions of high molecular weight pan fiber in wet spinning by orthogonal experimental design. Fibers Polym 13, 1259–1265 (2012). https://doi.org/10.1007/s12221-012-1259-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-012-1259-5

Keywords

Search

Navigation