Abstract
Although doped hole-transport materials (HTMs) offer an efficiency benefit for perovskite solar cells (PSCs), they inevitably diminish the stability. Here, we describe the use of various chlorinated small molecules, specifically fluorenone-triphenylamine (FO-TPA)-x-Cl [x = para, meta, and ortho (p, m, and o)], with different chlorine-substituent positions, as dopant-free HTMs for PSCs. These chlorinated molecules feature a symmetrical donor–acceptor–donor structure and ideal intramolecular charge transfer properties, allowing for self-doping and the establishment of built-in potentials for improving charge extraction. Highly efficient hole-transfer interfaces are constructed between perovskites and these HTMs by strategically modifying the chlorine substitution. Thus, the chlorinated HTM-derived inverted PSCs exhibited superior efficiencies and air stabilities. Importantly, the dopant-free HTM FO-TPA-o-Cl not only attains a power conversion efficiency of 20.82% but also demonstrates exceptional stability, retaining 93.8% of its initial efficiency even after a 30-day aging test conducted under ambient air conditions in PSCs without encapsulation. These findings underscore the critical role of chlorine-substituent regulation in HTMs in ensuring the formation and maintenance of efficient and stable PSCs.
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Introduction
Perovskite solar cells (PSCs) have received much attention in recent years due to their outstanding power conversion efficiency (PCE) of up to 26% [1,2,3]. Inverted planar PSCs, denoted as positive–intrinsic–negative (p − i − n), hold greater promise and appeal when contrasted with the conventional n − i − p-structured PSCs, owing to their promising stability under ambient air, ease of fabrication, and use of flexible substrates [4,5,6,7]. Furthermore, the p − i − n architecture advances the technology of silicon/perovskite tandem cells, potentially expediting the widespread commercial adoption of PSCs.
The function of hole-transport materials (HTMs) is pivotal in p − i − n PSCs, as HTMs facilitate the efficient extraction and transport of photoinduced holes while preventing undesired interfacial charge recombination [8, 9]. HTMs can be categorized into three primary classes within the framework of p − i − n planar PSCs: inorganic HTMs, organic small-molecule HTMs, and polymeric HTMs [10,11,12]. Initially, the polymeric HTM poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) gained widespread recognition for its exceptional attributes, which include high optical transparency, adequate electrical conductivity, and superior wettability. However, growing evidence suggests that the acidic and hygroscopic nature of the PSS components, coupled with energy-level mismatches between HTMs and perovskite materials, may impose limitations on the maximum efficiency of these devices and their stability [13]. Although alternative HTMs like poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine (PTAA) have been used in high-efficiency PSCs, the reliance on deliquescent dopants inevitably compromises the long-term durability of PSCs [14]. 2,2′,7,7′-tetrakis[N, N-di(4-methoxyphenyl) amino]-9,9′-spirobifluorene (Spiro-OMeTAD) and PTAA suffer from low conductivity when used as HTMs in PSCs, which leads to inferior performance. Dopants like lithium bis(trifluoro-methane-sulfonyl)-imide (Li-TFSI) are added to enhance conductivity. However, these dopants can create pinholes, exposing the perovskite layer and reducing the PSC efficiency [15,16,17]. Hence, there exists a pressing need for cost-effective, readily available, and dopant-free HTMs that can deliver exceptional performance and enhanced stability in p − i − n PSCs.
Dopant-free small molecules are still considered the best alternative HTMs due to their facile synthesis, excellent solubility, and modifiable molecular configurations and energy states. To date, p − i − n PSCs employing dopant-free small-molecule HTMs have demonstrated impressive PCE exceeding 20%, and recent advancements with self-assembled monolayers have pushed the efficiency beyond 26%, as illustrated in Fig. S1 and Table S1 in Supplementary Materials [18,19,20,21,22,23,24,25,26,27,28,29]. Most high-performance dopant-free HTMs adopt symmetrical donor–acceptor–donor (D–A–D) structures. This strategy allows for precise control over the energy levels of the highest occupied molecular orbital (HOMO) and the establishment of a harmonious energy alignment with perovskite materials. Molecules with D–A–D structures exhibit favorable intramolecular charge transfer (ICT) characteristics. These attributes enable self-doping phenomena and built-in potentials, thereby augmenting their charge-extraction capabilities [30, 31].
Moreover, halogenation as a molecular design strategy has proven effective in fine-tuning optoelectronic properties and enhancing the film morphology of small molecules [32,33,34,35,36]. Specifically, the C–Cl bond, among the four carbon–halogen bonds, exhibits the highest dipole moment and best intensifies the ICT effect. Furthermore, chlorinated compound synthesis is more straightforward compared to that of their fluorinated counterparts, making chlorination a particularly appealing and promising avenue for designing highly efficient and cost-effective HTMs for PSCs [37,38,39,40]. Despite its potential, the chlorine substitution of HTMs in PSCs had not received adequate attention until recently. Notably, Guo and colleagues [36] have reported the successful development of a chlorinated HTM, mCl-SFXDA, based on the spiro[fluorene-9,9′-xanthene] architecture. This HTM achieved an impressive PCE of 22.14% when used with dopants in n − i − p PSCs.
In this research, we have systematically explored the synthesis and application of chlorinated small-molecule HTMs in dopant-free p − i − n PSCs. The designed chlorinated HTMs, namely fluorenone-triphenylamine (FO-TPA)-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl, are illustrated in Fig. 1a. These HTMs feature fluorenone as the A unit and triphenylamine (TPA) with various chlorine atoms as the D units, forming a D − A − D molecular framework. The specific chlorine substitution positions (para, meta, and ortho) on the terminal benzene units significantly influence the optoelectronic, thermal, and morphological properties of these conjugated organic small molecules. Compared to the chlorine-free FO-TPA-CH3, the FO-TPA-x-Cl (x = p, m, and o) HTMs exhibit markedly improved film coverage, enhanced hole extraction efficiency, and appropriately aligned energy levels with perovskite, resulting in an enhancement of PCE by 0.68–3.15%. Remarkably, the FO-TPA-o-Cl-based device achieved an exceptional PCE of 20.82%, featuring an open-circuit voltage (Voc) of 1.09 V, a short-circuit current density (Jsc) of 24.13 mA/cm2, and a commendable fill factor (FF) of 0.80 under standard AM 1.5G illumination conditions (100 mW/cm2). These performance metrics surpass those of the other two chlorinated HTMs and the chlorine-free FO-TPA-CH3-based devices. Significantly, the unencapsulated devices using FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl HTMs demonstrated robust operational stability, retaining 88.3%, 89.7%, and 93.8% of their initial PCEs, respectively, after an extended 720-h aging test under ambient air conditions. In contrast, the device using chlorine-free FO-TPA-CH3 retained a mere 86.9% of its initial PCE throughout the identical testing duration.
Results and Discussion
The synthesis of these dopant-free small-molecule HTMs is elucidated in Fig. S2, and comprehensive experimental procedures can be found in Supplementary Materials. Initially, Intermediate 2 was obtained through a Suzuki–Miyaura coupling reaction, wherein 2, 7-dibromo-9-fluorenone was coupled with 2-methoxyphenyl boronic acid in the presence of a Pd(PPh3)4 catalyst. The resulting intermediate was further modified to yield the dibromo-substituted compound FO-Br, employing N-bromo succinimide as the brominating agent, with a commendable yield of approximately 85%. Following this, C − N bond formations were executed through Buchwald–Hartwig cross-coupling reactions between FO-Br and diphenylamine derivatives, namely 4, 4'-dimethyldiphenylamine, 4-chlorodiphenylamine, 3-chlorodiphenylamine, and 2, 6-dichlorodiphenylamine. These reactions yielded the desired small-molecule HTMs, namely FO-TPA-CH3, FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl, respectively, with respectable yields ranging from 60 to 78%. Purification of the synthesized small-molecule HTMs was achieved through column chromatography, using silica gel and petroleum ether: CH2Cl2 eluent mixture in a 3:1 ratio, followed by recrystallization from methanol. The structural confirmation of the intermediates and the final small-molecule HTMs was accomplished through 1H nuclear magnetic resonance spectra, as depicted in Figs. S3 − S7.
Figure 1b and S8a display the UV − Vis absorption and fluorescence emission spectra of these HTMs in CH2Cl2 solutions and thin film, with pertinent data summarized in Table S2. The newly developed HTMs display distinct absorption characteristics, featuring a prominent absorption peak at approximately 285 nm that can be attributed to the π–π* local electron transition. Simultaneously, the comparatively weaker absorption at 437 nm is attributed to intramolecular charge transitions between the fluorenone core and the TPA moiety [41, 42]. The optical bandgap values (Egopt) for FO-TPA-CH3, FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl were established as 2.68, 2.65, 2.65, and 2.66 eV, respectively, by analyzing the overlapping regions of their normalized absorption and emission spectra (Fig. 1b). As illustrated in Fig. S8b, all HTMs exhibit efficient optical transmittance within the spectral range spanning from 500 to 800 nm, effectively reducing parasitic absorption. Furthermore, the first oxidation potentials (Eox), indicative of the highest occupied molecular orbital (HOMO) energy levels of the HTMs, were determined via cyclic voltammetry, as shown in Fig. S9. To determine the lowest unoccupied molecular orbital (LUMO) energy levels, Egopts were combined with the corresponding HOMO energy levels (LUMO = HOMO + Egopt). Energy-band diagrams of the perovskite and these HTMs are presented in Fig. 1c. Compared with FO-TPA-CH3 (− 5.19 eV), the HOMO energy levels of the three chlorinated HTMs are slightly deeper due to the strong electronegativity of chlorine atoms, measuring approximately − 5.26, − 5.29, and − 5.39 eV for FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl, respectively [43, 44]. The introduction of chlorine substituents into these HTMs enhances the alignment between their HOMO and the valence band of the perovskite, effectively reducing the interfacial energy barrier and promoting hole transfer within p − i − n PSCs. Furthermore, their calculated LUMO energy levels range from − 2.61 to − 2.73 eV, representing a significant increase compared to the perovskite conduction band (− 3.93 eV) and providing efficient electron-blocking properties at the perovskite/HTM interface.
We performed thermogravimetric analysis (TGA) and differential scanning calorimetry to assess the thermal characteristics of these small-molecule HTMs, as shown in Fig. S10. Figure S10a reveals exceptional thermal stability in the chlorinated derivatives, with each exhibiting a thermal decomposition temperature (Td) for a 5% weight loss surpassing that of chlorine-free FO-TPA-CH3. Figure S10b illustrates a distinctive glass transition occurring at 136 °C for FO-TPA-CH3. Conversely, no phase transition was observed in the three chlorinated HTMs up to 300 °C, indicating limited molecular mobility in response to temperature changes. This finding implies that the chlorinated HTMs possess a more rigid molecular structure via the internal heavy-atom effect when compared to their chlorine-free counterpart [45].
Electronic and geometrical properties of the molecules were investigated through density functional theory (DFT) calculations using the B3LYP/6-31G level of theory in the Gaussian 09 software [46, 47]. The optimized geometries of the four small-molecule HTMs are shown in Fig. 2a. The results, illustrated in Fig. 2b, reveal that the electron densities of the HOMOs for the four small-molecule HTMs are predominantly situated on the peripheral TPA moieties, while their LUMOs are concentrated on the fluorenone cores. However, clear differences in HOMOs can be observed as the positions of the Cl atoms change. The terminal Cl atoms exhibit noticeable HOMO distribution for FO-TPA-p-Cl, whereas no such distribution is evident at the Cl atoms for both FO-TPA-m-Cl and FO-TPA-o-Cl. The theoretical calculations also indicate that the introduction of a chlorine atom into the molecule results in reduced HOMO and LUMO energy levels, a trend consistent with the experimental results. Furthermore, the DFT calculation was also performed to obtain the electrostatic potential (ESP) surface (Fig. 2c). The electronegative charges are predominantly situated on the fluorenone moieties, particularly in the vicinities of oxygen atoms, signifying their possession of Lewis base properties conducive to secondary interactions with under-coordinated and electropositive Pb2+ on the perovskite surface [48]. Moreover, in comparison with chlorine-free FO-TPA-CH3, the ESP surface images of all the chlorinated HTMs exhibited negative potential distribution around the Cl atoms due to their pronounced electron-withdrawing capacity. The electron-rich property of the chlorinated area may also function as a soft Lewis base to stabilize the uncoordinated Pb sites in perovskite, passivating the defects at the HTM and perovskite interface [49].
The film morphologies and quality of these HTMs on indium tin oxide (ITO) substrates were assessed using atomic force microscopy (AFM), as illustrated in Fig. 3a. The root-mean-square roughness of the chlorinated HTM layers of FO-TPA-p-Cl (5.80 nm), FO-TPA-m-Cl (6.44 nm), and FO-TPA-o-Cl (2.44 nm) is notably smaller compared to the chlorine-free FO-TPA-CH3 (8.39 nm), indicating that modifying the position of chlorine atoms in HTMs can optimize the film morphology. The improved coverage of chlorinated films efficiently mitigates shunt paths between perovskite and ITO, thereby suppressing nonradiative recombination at the junction. We further investigated the surface wettability of these four HTMs through water contact-angle testing (Fig. 3b). The water contact angles for FO-TPA-CH3, FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl were measured at 82.2°, 92.0°, 93.8°, and 84.2°, respectively, which are significantly larger than those of benchmark HTMs like small-molecule Spiro-OMeTAD (38.7°) and polymeric PEDOT:PSS (16.9°). All the newly developed HTMs, along with the conventional PTAA (with a contact angle of 90.6°), display hydrophobic properties. These properties can potentially serve as a barrier, preventing moisture ingress that might lead to perovskite absorber degradation. This, in turn, promotes the formation of high-caliber perovskite crystals and facilitates the overall stability of environmental devices [50,51,52].
a Atomic force microscopy (AFM) height images depicting the hole-transport materials (HTMs) on indium tin oxide (ITO) substrates; b visual representation of the water contact angles exhibited by the HTMs on ITO substrates; c scanning electron microscopy (SEM) images, captured from a top-view perspective, showcasing the prepared perovskite films atop the HTMs; d X-ray diffraction (XRD) analysis of the perovskite films grown on HTMs; e photoluminescence (PL) spectra of the perovskite films deposited on glass substrates: glass/fluorenone-triphenylamine (FO-TPA)-CH3, glass/FO-TPA-p-Cl, glass/FO-TPA-m-Cl, and glass/FO-TPA-o-Cl
Figure. 3c shows scanning electron microscopy (SEM) images of perovskite films that grew on layers of FO-TPA-CH3, FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl. The FO-TPA-CH3/perovskite film has a random perovskite crystal-size distribution, and pinholes appear at the grain boundaries, while perovskite growth on FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl films is more homogeneous and compact. The better coverage and crystallization of perovskite film may profit from the improved film morphology of chlorinated HTMs [53]. We performed X-ray diffraction (XRD) on perovskite thin films for further assessment of perovskite crystal quality (Fig. 3d). When contrasted with FO-TPA-CH3, perovskite films grown on FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl exhibit more pronounced X-ray diffraction peaks. This observation suggests the superior crystallization of the perovskite film, which in turn contributes to the improved efficiency and stability of the devices [54]. These findings align with the SEM results, which illustrate a denser arrangement of perovskite grains. Thus, manipulating the chlorine atom positions within the HTMs can effectively optimize perovskite film morphology and enhance perovskite crystallinity.
We conducted steady-state photoluminescence (PL) measurements on perovskite films deposited on both glass and various HTMs to explore the dynamics of hole extraction and charge transfer at the interfaces between the HTMs and perovskite (Fig. 3e). Compared to the original perovskite films on glass, the PL spectra of the four HTM/perovskite films exhibit significant quenching, indicating the rapid extraction of holes at the HTM/perovskite interface. The three chlorinated HTMs demonstrate superior quenching of PL emitted by the perovskite films compared to FO-TPA-CH3 HTM, facilitating enhanced charge transfer from the perovskite into the HTM layer. Intriguingly, the FO-TPA-o-Cl/perovskite exhibits the weakest PL intensity among these chlorinated HTMs, signifying a more efficient hole transfer from perovskite to the HTM. This could be ascribed to the inherent advantage of producing high-quality chlorinated HTM films and forging an enhanced interfacial chemical interaction at the HTM/perovskite junction [55].
Building upon these investigations, we assembled dopant-free planar p − i − n PSCs (ITO/HTM/LiF/perovskite/LiF/C60/bathocuproine (BCP)/Ag) using the developed HTMs. The complete device configuration, along with an SEM cross-sectional image depicting the p − i − n PSC, is presented in Fig. 4a and b, respectively. The comprehensive photovoltaic parameters are consolidated in Table 1. Analysis of the current–voltage (J–V) plots reveals that devices incorporating FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl exhibited excellent FF values (ranging from 0.77 to 0.80), surpassing the FF of the device based on FO-TPA-CH3 (0.72) (Fig. 4c). Particularly noteworthy are the Voc values of the PSCs containing FO-TPA-m-Cl and FO-TPA-o-Cl (ranging from 1.04 V to 1.09 V), which exceed those of the device using FO-TPA-CH3 (1.02 V). This enhancement in Voc can be ascribed to the improved alignment of HOMO energy levels between chlorinated HTMs and perovskite, along with the Lewis base passivation of under-coordinated Pb2+ ion defects at the HTM/perovskite interface [45, 56]. Comparing the performance of PSCs based on FO-TPA-CH3, which achieved a PCE of 17.67%, with those based on the three chlorinated HTMs (PCEs of 18.35%–20.82%), reveals significant efficiency gains. Notably, the FO-TPA-o-Cl-derived PSC exhibited the highest Voc of 1.09 V during reverse scanning, Jsc of 24.13 mA/cm2, and FF of 0.80, resulting in the best PCE of 20.82%. This performance surpasses that of PTAA (without doping) and PEDOT:PSS-based devices (Fig. S11), establishing it as a frontrunner compared to other recently documented small-molecule HTMs in dopant-free p–i–n PSCs (Fig. S1 and Table S1). Despite these small-molecule HTMs sharing identical core backbones, the variations in substituent groups exert a considerable influence on the photovoltaic efficacy of PSCs [57].
a Device architecture of the inverted perovskite solar cells (PSCs); b scanning electron microscopy (SEM) cross-sectional image of the device based on fluorenone-triphenylamine (FO-TPA)-o-Cl; c current–voltage (J–V) characteristics of the best-performing devices employing various hole-transport materials (HTMs); d J–V curves for the most efficient device under reverse and forward scans with FO-TPA-o-Cl; e external quantum efficiency (EQE) spectra and integrated Jsc curves; f Histograms depicting the statistical distribution of power conversion efficiencies (PCEs) with FO-TPA-o-Cl
During forward scanning, the FO-TPA-o-Cl device achieves a PCE of 20.14% (Fig. 4d). To evaluate device hysteresis, we employ the hysteresis index (HI), calculated as HI = (PCEreverse − PCEforward)/PCEreverse [58]. For FO-TPA-o-Cl-based devices, the HI measures 3.27%. Figure 4e presents the external quantum efficiency (EQE) spectra of FO-TPA-o-Cl-based devices, revealing impressive EQE values exceeding 80% throughout the spectral span from 400 to 800 nm. The integrated Jsc value of 24.10 mA/cm2 aligns with the measured J–V data, affirming the reliability of our measurements. To assess the reproducibility of FO-TPA-o-Cl-based PSCs, we fabricated and characterized 20 devices, and the statistical distribution is presented in Fig. 4f. The mean PCE of FO-TPA-o-Cl PSCs, determined from the results of these 20 devices, is 20.41%.
Subsequent stability assessments were performed under ambient air conditions with relative humidity ranging from approximately 20% to 30%, all conducted without the use of encapsulation. As depicted in Figs. 5 and S12, the attenuation curve illustrates the gradual declines in PCEs for these devices over time. In contrast to devices using the chlorine-free HTM FO-TPA-CH3, which retained 86.9% of its initial PCE, PSCs employing FO-TPA-p-Cl, FO-TPA-m-Cl, and FO-TPA-o-Cl as dopant-free HTMs demonstrate significantly improved stability. Specifically, they maintained 88.3%, 89.7%, and 93.8% of their initial PCEs after 720 h, respectively. In the aging study (Fig. S13), XRD analysis revealed that the chlorine-free FO-TPA-CH3 showed signs of perovskite decomposition with the emergence of PbI2 peaks indicating material degradation, while the chlorinated HTM FO-TPA-o-Cl maintained its perovskite structure but exhibited changes in peak intensities, suggesting alterations at the material interfaces that might contribute to efficiency losses. This enhanced stability can be attributed to a combination of factors that stem from the synergistic interactions between the chlorine atoms and C=O groups present in the chlorinated HTMs, including optimized film morphology, enhanced crystallinity, and the passivation of interfacial and grain boundary defects within the perovskite layer. Consequently, PSCs featuring these chlorinated HTMs exhibit exceptional initial performance and long-term stability when exposed to ambient conditions.
Conclusion
Our study has developed high-performance dopant-free HTMs for p − i − n perovskite solar cells by synthesizing a series of chlorinated small molecules, specifically FO-TPA-x-Cl (x = p, m, and o). The strategic incorporation of chlorine substituents into these small-molecule HTMs optimizes the energy level alignment for efficient hole extraction, improves HTM film morphology for enhanced coverage, and enlarges perovskite crystal grains, collectively boosting device performance. We observed remarkable improvements in key photovoltaic parameters in p − i − n PSCs from these enhancements, including Voc, Jsc, and FF. The FO-TPA-o-Cl variant exhibits exceptional performance—achieving a PCE of 20.82% and maintaining more than 93% of its initial efficiency after 720 h in ambient air. These outcomes not only demonstrate the profound impact of chlorine-substituent control but also highlight the potential of these chlorinated molecules as economical and effective organic HTMs, promising the future development of high-performance PSCs.
References
Min H, Lee DY, Kim J et al (2021) Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes. Nature 598(7881):444–450
Kojima A, Teshima K, Shirai Y et al (2009) Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J Am Chem Soc 131(17):6050–6051
Yang WS, Park BW, Jung EH et al (2017) Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells. Science 356(6345):1376–1379
Lin X, Cui D, Luo X et al (2020) Efficiency progress of inverted perovskite solar cells. Energy Environ Sci 13(11):3823–3847
Li W, Martínez-Ferrero E, Palomares E (2024) Self-assembled molecules as selective contacts for efficient and stable perovskite solar cells. Mater Chem Front 8(3):681–699
Kim D, Jung HJ, Park IJ et al (2020) Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites. Science 368(6487):155–160
Yang D, Sano T, Yaguchi Y et al (2019) Achieving 20% efficiency for low-temperature-processed inverted perovskite solar cells. Adv Funct Mater 29(12):1807556
Ameen S, Rub MA, Kosa SA et al (2016) Perovskite solar cells: influence of hole transporting materials on power conversion efficiency. Chemsuschem 9(1):10–27
Bakr ZH, Wali Q, Fakharuddin A et al (2017) Advances in hole transport materials engineering for stable and efficient perovskite solar cells. Nano Energy 34:271–305
Yuan J, Chen Y, Liu X et al (2021) Dopant-free hole-transporting materials for CH3NH3PbI3 inverted perovskite solar cells with an approximate efficiency of 20%. ACS Appl Energy Mater 4(6):5756–5766
Guo S, Zhang X, Li Z et al (2021) Dopant-free ternary conjugated polymeric hole-transporting materials for efficient inverted planar perovskite solar cells. Sol RRL 5(10):2100506
Zhang H, Wang H, Zhu H et al (2018) Low-temperature solution-processed CuCrO2 hole-transporting layer for efficient and photostable perovskite solar cells. Adv Energy Mater 8(13):1702762
Jeng JY, Chiang YF, Lee MH et al (2013) CH3NH3PbI3 perovskite/fullerene planar-heterojunction hybrid solar cells. Adv Mater 25(27):3727–3732
Shao Y, Yuan Y, Huang J (2016) Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells. Nat Energy 1:15001
Hawash Z, Ono LK, Qi Y (2021) Moisture and oxygen enhance conductivity of LiTFSI-doped spiro-MeOTAD hole transport layer in perovskite solar cells. Adv Mater Interfaces 8(23):1600117
Hawash Z, Ono LK, Raga SR et al (2015) Air-exposure induced dopant redistribution and energy level shifts in spin-coated spiro-MeOTAD films. Chem Mater 27(2):562–569
Niu G, Guo X, Wang L (2015) Review of recent progress in chemical stability of perovskite solar cells. J Mater Chem A 3(17):8970–8980
Yu X, Li Z, Sun X et al (2021) Dopant-free dicyanofluoranthene-based hole transporting material with low cost enables efficient flexible perovskite solar cells. Nano Energy 82:105701
Wang YK, Ma H, Chen Q et al (2021) Fluorinating dopant-free small-molecule hole-transport material to enhance the photovoltaic property. ACS Appl Mater Interfaces 13(6):7705–7713
Li R, Li C, Liu M et al (2022) Hydrogen-bonded dopant-free hole transport material enables efficient and stable inverted perovskite solar cells. CCS Chem 4(9):3084–3094
Huang J, Yang J, Sun H et al (2021) A cost-effective D-A-D type hole-transport material enabling 20% efficiency inverted perovskite solar cells. Chin J Chem 39(6):1545–1552
Chen W, Wang Y, Liu B et al (2021) Engineering of dendritic dopant-free hole transport molecules: enabling ultrahigh fill factor in perovskite solar cells with optimized dendron construction. Sci China Chem 64(1):41–51
Yang K, Liao Q, Huang J et al (2022) Intramolecular noncovalent interaction-enabled dopant-free hole-transporting materials for high-performance inverted perovskite solar cells. Angew Chem Int Edit 61(2):e202113749
Cai N, Li F, Chen Y et al (2021) Synergistical dipole-dipole interaction induced self-assembly of phenoxazine-based hole-transporting materials for efficient and stable inverted perovskite solar cells. Angew Chem Int Edit 60(37):20437–20442
Wu J, Hu M, Zhang L et al (2021) Fluorinated cross-linkable and dopant-free hole transporting materials for efficient and stable perovskite solar cells. Chem Eng J 422:130124
Zhou Z, Wu Q, Cheng R et al (2021) Orientation-engineered small-molecule semiconductors as dopant-free hole transporting materials for efficient and stable perovskite solar cells. Adv Funct Mater 31(20):2011270
Sun Q, Zhang J, Chen Q et al (2020) High-efficiency planar p–i–n perovskite solar cells based on dopant-free dibenzo[b, d]furan-centred linear hole transporting material. J Power Sources 449:227488
Zhang J, Sun Q, Chen Q et al (2020) Dibenzo[b, d]thiophene-cored hole-transport material with passivation effect enabling the high-efficiency planar p–i–n perovskite solar cells with 83% fill factor. Sol RRL 4(3):1900421
Wang Y, Chen Q, Fu J et al (2022) Annealing- and doping-free hole transport material for p–i–n perovskite solar cells with efficiency achieving over 21%. Chem Eng J 433:133265
Tian Y, Tao L, Chen C et al (2021) Facile synthesized fluorine substituted benzothiadiazole based dopant-free hole transport material for high efficiency perovskite solar cell. Dyes Pigments 184:108786
Tao L, Chen C, Wu C et al (2020) Fluorine-substituted benzotriazole core building block-based highly efficient hole-transporting materials for mesoporous perovskite solar cells. Sol RRL 4(3):1900362
Sun Y, Peng Y, Zhao C et al (2022) The strategy for high-efficiency hole conductors by engineering short-range intramolecular interactions. Dyes Pigments 197:109889
Bai QQ, Huang J, Guo H et al (2022) Regioisomeric polymer semiconductors based on cyano-functionalized dialkoxybithiophenes: structure–property relationship and photovoltaic performance. Trans Tianjin Univ 28(5):385–397
Ren J, Qu J, Chen J et al (2018) Fluorinated dopant-free hole-transporting material for efficient and stable perovskite solar cells with carbon cathode. J Power Sources 401:29–36
Li B, Li SY, Yang X et al (2022) Understanding the impact of fluorine substitution on the photovoltaic performance of block copolymers. Trans Tianjin Univ 28(5):406–413
Zhang Z, Shen L, Wang S et al (2023) Halogenated hole-transport molecules with enhanced isotropic coordination capability enable improved interface and light stability of perovskite solar cells. Adv Energy Mater 13(14):2204362
Zhao W, Li S, Yao H et al (2017) Molecular optimization enables over 13% efficiency in organic solar cells. J Am Chem Soc 139(21):7148–7151
Luo Z, Liu T, Wang Y et al (2019) Reduced energy loss enabled by a chlorinated thiophene-fused ending-group small molecular acceptor for efficient nonfullerene organic solar cells with 13.6% efficiency. Adv Energy Mater 9(18):1900041
Ma F, Zhao Y, Qu Z et al (2023) Developments of highly efficient perovskite solar cells. Acc Mater Res 4(8):716–725
Park J, Kim J, Yun HS et al (2023) Controlled growth of perovskite layers with volatile alkylammonium chlorides. Nature 616(7958):724–730
Zhang H, Wu Y, Zhang W et al (2018) Low cost and stable quinoxaline-based hole-transporting materials with a D-A-D molecular configuration for efficient perovskite solar cells. Chem Sci 9(27):5919–5928
Xu P, Liu P, Li Y et al (2018) D-A-D-typed hole transport materials for efficient perovskite solar cells: tuning photovoltaic properties via the acceptor group. ACS Appl Mater Interfaces 10(23):19697–19703
Zhang H, Yao H, Hou J et al (2018) Over 14% efficiency in organic solar cells enabled by chlorinated nonfullerene small-molecule acceptors. Adv Mater 30(28):e1800613
Zhang S, Qin Y, Zhu J et al (2018) Over 14% efficiency in polymer solar cells enabled by a chlorinated polymer donor. Adv Mater 30(20):e1800868
Yoon WS, Kim DW, Choi MW et al (2018) Designing 1, 5-naphthyridine-2, 6-dione-based conjugated polymers for higher crystallinity and enhanced light absorption to achieve 9.63% efficiency polymer solar cells. Adv Energy Mater 8(2):1701467
Finley JP (2004) Using the local density approximation and the LYP, BLYP and B3LYP functionals within reference-state one-particle density-matrix theory. Mol Phys 102(7):627–639
Lu T, Chen F (2012) Multiwfn: a multifunctional wavefunction analyzer. J Comput Chem 33(5):580–592
Fu Q, Liu H, Gao Y et al (2023) Tunable molecular packing of dopant-free hole-transport polymers for perovskite solar cells. ACS Energy Lett 8(7):2878–2885
Wang K, Liu J, Yin J et al (2020) Defect passivation in perovskite solar cells by cyano-based π-conjugated molecules for improved performance and stability. Adv Funct Mater 30(35):2002861
Gao Y, Wu Y, Liu Y et al (2020) Interface and grain boundary passivation for efficient and stable perovskite solar cells: the effect of terminal groups in hydrophobic fused benzothiadiazole-based organic semiconductors. Nanoscale Horiz 5(12):1574–1585
Li H, Wu G, Li W et al (2019) Additive engineering to grow micron-sized grains for stable high efficiency perovskite solar cells. Adv Sci 6(18):1901241
Bi C, Wang Q, Shao Y et al (2015) Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells. Nat Commun 6:7747
Tong T, Tan C, Keller T et al (2018) Two anthracene-based copolymers as the hole-transporting materials for high-performance inverted (p–i–n) perovskite solar cells. Macromolecules 51(18):7407–7416
Zhang T, Guo N, Li G et al (2016) A controllable fabrication of grain boundary PbI2 nanoplates passivated lead halide perovskites for high performance solar cells. Nano Energy 26:50–56
Stolterfoht M, Wolff CM, Márquez JA et al (2018) Visualization and suppression of interfacial recombination for high-efficiency large-area pin perovskite solar cells. Nat Energy 3:847–854
Belisle RA, Jain P, Prasanna R et al (2016) Minimal effect of the hole-transport material ionization potential on the open-circuit voltage of perovskite solar cells. ACS Energy Lett 1(3):556–560
Afraj SN, Zheng D, Velusamy A et al (2022) 2, 3-diphenylthieno[3, 4-b]pyrazines as hole-transporting materials for stable, high-performance perovskite solar cells. ACS Energy Lett 7(6):2118–2127
Liu P, Wang W, Liu S et al (2019) Fundamental understanding of photocurrent hysteresis in perovskite solar cells. Adv Energy Mater 9(13):1803017
Acknowledgements
This study was supported by the National Natural Science Foundation of China (No. 22379105), the Natural Science Foundation of Shanxi Province (Nos. 20210302123110 and 202303021211059), and the Open Fund Project of Ningxia Sinostar Display Material Co., Ltd.
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Liu, X., Zhang, X., Li, Z. et al. Chlorine-Substituent Regulation in Dopant-Free Small-Molecule Hole-Transport Materials Improves the Efficiency and Stability of Inverted Perovskite Solar Cells. Trans. Tianjin Univ. (2024). https://doi.org/10.1007/s12209-024-00401-5
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DOI: https://doi.org/10.1007/s12209-024-00401-5