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Numerical and experimental study on the thermal characteristics of a steam reformer

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Abstract

In this study, the performance evaluation of a cylindrical natural-gas steam reformer is experimentally and numerically performed with a special focus on thermal operation conditions. The evaluation system is configured to probe the thermal and chemical characteristics of a steam reformer that does not employ a high temperature shift and a low temperature shift. The acquired experimental data is used to validate the proposed numerical model. A combination of experimental and numerical data provides detailed information leading to a better understanding of the internal reaction. An appropriate control of the heat source in the steam reformer is extremely important because the endothermic process is dominant throughout the catalyst layer. The results indicate that the thermal efficiency is enhanced by appropriately managing combustor heat, reactant concentration, and inflow rates as implemented by inlet gas control into the main reactor and combustor. A parametric study of operation control variables, such as Steam to carbon ratio (SCR) and combustible reactant ratio, could determine the optimal values for the highest thermal performance.

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References

  1. L. D. Andrew, Hydrogen generation from natural gas for the fuel cell systems of tomorrow, Int. J. Power Sources, 61 (1996) 113–124.

    Article  Google Scholar 

  2. A. F. Ghenciu, Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems, Curr. Opin. Solid State Mater. Sci., 6 (2002) 389–399.

    Article  Google Scholar 

  3. N. T. Rostrup, Manufacture of hydrogen, Catal. Today, 106 (2005) 293–296.

    Article  Google Scholar 

  4. N. A. John, Review the multiple roles for catalysis in the production of H2, Appl. Catal., A., 176 (1999) 159–176.

    Article  Google Scholar 

  5. A. C. D. Joelmir and J. M. Assaf, Autothermal reforming of methane over Ni-Al2O3 catalysts: The enhancement effect of small quantities of noble metals, Int. J. Power Sources, 130 (2004) 106–110.

    Article  Google Scholar 

  6. J. Larmine and A. Dicks, Fuel cell systems explained, Second Edition, England: Wiley (2003).

    Book  Google Scholar 

  7. R. P. O'hayre, S.-W. Cha, G. C. Whitney and F. B. Prinz, Fuel cell fundamentals, America Wiley (2006).

    Google Scholar 

  8. S. Lee, W. R. Schwartz, J.-R. Choi, J.-G. Ahn, D.-H. Kim, I.-H. Son, W. C. Shin and J.-Y. Kim, Start-up characteristics of commercial propane steam reformer for 200 We portable fuel cell system, Int. J. Hydrogen Energy, 351 (2010) 12286–12294.

    Article  Google Scholar 

  9. M. Zanr and A. Gavriilidis, Catalytic combustion assisted methane steam reforming in a catalytic plate reactor, Chem. Eng. (London), 58 (2003) 3947–3960.

    Google Scholar 

  10. A. E. Lutza, R. W. Bradshawa, J. O. Kellera and D. E. Witmerb, Thermodynamic analysis of hydrogen production by steam reforming, Int. J. Hydrogen Energy, 28 (2003) 159–167.

    Article  Google Scholar 

  11. K. Hou and R. Hughes, The kinetics of methane steam reforming over a Ni/a-Al2O catalyst, Chem. Eng. J., 8 (2001) 311–328.

    Article  Google Scholar 

  12. K.-S. Cha, H.-S. Kim, B.-K. Yoo, Y.-S. Lee, K.-S. Kang, C.-S. Park and Y.-H. Kim, Reaction characteristics of twostep methane reforming over a Cu-ferriteCe_ZrO2 medium reforming, Int. J. Hydrogen Energy, 34 (2009) 1801–1808.

    Article  Google Scholar 

  13. J. R. Rostrup-Nielsen, Sulfur-passivated nickel catalysts for carbon-free steam reforming of methane, J. Catal., 85 (1984) 31–43.

    Article  Google Scholar 

  14. S.-T. Lin, Y.-H. Chen, C. C. Yu, Y.-C. Liu and C.-H. Lee, Modelling an experimental methane fuel processor, Journal of Power Sources, 148 (2005) 44–53.

    Article  Google Scholar 

  15. G. George, Dimopoulos, C. S. Iason and M. P. K. Nikolaos, Exergy analysis and optimisation of a steam methane prereforming system, Energy, 58 (2013) 17–27.

    Article  Google Scholar 

  16. A. Serrano-Lotina and L. Daza, Influence of the operating parameters over dry reforming of methane to syngas, International J. of Hydrogen Energy, 39 (2014) 4089–4094.

    Article  Google Scholar 

  17. N. Morlanes, Reaction mechanism of naphtha steam reforming on nickel-based catalysts, and FTIR spectroscopy with CO adsorption to elucidate real active sites, International Journal of Hydrogen Energy, 38 (2013) 3588–3596.

    Article  Google Scholar 

  18. J. Park, S. Lee, S. Kim and J. Bae, Numerical analysis of the heat and mass transfer characteristics in an autothermal methane reformer, J. Fuel Cell Sci. Technol., 7 (2010) 051018–1.

    Article  Google Scholar 

  19. M. Nijemeisland, A. G. Dixona and E. H. Stitt, Catalyst design by CFD for heat transfer and reaction in steam reforming, Chem. Eng. J., 59 (2004) 5185–5191.

    Article  Google Scholar 

  20. M. Ni, 2D heat and mass transfer modeling of methane steam reforming for hydrogen production in a compact reformer, Energy Convers. Manage, 65 (2013) 155–163.

    Article  Google Scholar 

  21. A. G. Dixon, M. E. Taskin, M. Nijemeisland and E. H. Stitt, A CFD method to couple 3D transport and reaction in fixed bed catalyst pellets to the external flow field, Ind. Eng. Chem. Res., 49 (2010) 9012–9025.

    Article  Google Scholar 

  22. D. D. Davieau and P. A. Erickson, The effect of geometry on reactor performance in the steam-reformation process, Int. J. Power Sources, 32 (2007) 1192–1200.

    Google Scholar 

  23. J. S. Lee, J. Seo, H. Y. Kim, J. T. Chung and S. S. Yoon, Effects of combustion parameters on reforming performance of a steam-methane reformer, Fuel, 111 (2013).

  24. M. Behnam, A. G. Dixon, P. M. Wright, M. Nijemeisland and E. H. Stitt, Comparison of CFD simulations to experiment under methane steam reforming reacting conditions, Chem. Eng. J., 207–208 (2012) 690–700.

    Article  Google Scholar 

  25. Y. Matsumura and T. Nakamori, Reaction temperature, Appl. Catal. A., 258 (2004) 107–114.

    Article  Google Scholar 

  26. E. Kikuchi, Y. Nemoto, M. Kajuwara, S. Uemiya and T. Kojima, Steam reforming of methane in membrane reactors: comparison of electroless-plating and CVD membranes and catalyst packing modes, Catal. Today, 56 (2000) 75–81.

    Article  Google Scholar 

  27. J. Xu and G. F. Froment, Methane steam reforming, methanation and water-gas shift: I. intrinsic kinetics, AIChE. J., 35 (1989) 88–96.

    Article  Google Scholar 

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Correspondence to Dohyung Lee.

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Recommended by Associate Editor Seongwon Kang

Tae-Hyun Jo is in Ph.D. course at Applied Computational Design & Fluid Dynamics Laboratory, Department of Mechanical Design Engineering, University of Hanyang, Ansan, Korea. His interests include computational fluid dynamics, design optimization, and renewable energy study.

Do-Hyung Lee received his Ph.D. degree in aerospace engineering from University of Michigan, United States of America, in 1996. He was Postdoctoral Fellow in NASA Ames Research Center, in 2000. He is a Professor of Mechanical Design Engineering in University of Hanyang, Ansan, Korea.

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Jo, T., Koo, B., Lee, Y. et al. Numerical and experimental study on the thermal characteristics of a steam reformer. J Mech Sci Technol 32, 679–687 (2018). https://doi.org/10.1007/s12206-018-0115-3

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  • DOI: https://doi.org/10.1007/s12206-018-0115-3

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