Skip to main content

Advertisement

Log in

Influence of Biomass Composition and Microwave Pyrolysis Conditions on Biochar Yield and its Properties: a Machine Learning Approach

  • Published:
BioEnergy Research Aims and scope Submit manuscript

Abstract

The investigation of microwave pyrolysis behavior and interactive effects of process parameters through machine learning is necessary to systematically determine the combined effects on the yield and characteristics of biochar. This study involves the prediction of microwave biochar yield and its property using various machine learning approaches. Based on the input data of feedstock characteristics (elemental and proximate composition) and operating conditions of microwave pyrolysis (microwave power, time, weight, absorber), the output targets like biochar yield and higher heating value (HHV) have been predicted. The results suggested that eXtreme Gradient Boosting (XGB) model with optimal hyper-parameters could predict the yield and HHV of microwave-derived biochar with higher correlation coefficient (R2) of 0.91. The impact of each factor on output target and their interactions during microwave pyrolysis has been observed from SHAP (SHapley Additive exPlanations) dependence plots. The study outcome revealed that microwave power is the most significant feature influencing the yield of biochar and its property (HHV). The present work gives an insight through computational approach in improving microwave pyrolysis of biomass for enhanced biochar yield and its properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

Data Availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

References

  1. Wang T, Li Y, Zhi D, et al (2019) Assessment of combustion and emission behavior of corn straw biochar briquette fuels under different temperatures. Journal of environmental management 250:109399

  2. Mohamed I, Ali M, Ahmed N et al (2018) Cow manure-loaded biochar changes Cd fractionation and phytotoxicity potential for wheat in a natural acidic contaminated soil. Ecotoxicol Environ Saf 162:348–353

    Article  CAS  PubMed  Google Scholar 

  3. Mohan D, Sarswat A, Ok YS, Pittman CU Jr (2014) Organic and inorganic contaminants removal from water with biochar, a renewable, low cost and sustainable adsorbent–a critical review. Biores Technol 160:191–202

    Article  CAS  Google Scholar 

  4. Velusamy K, Periyasamy S, Kumar PS, et al (2021) Analysis on the removal of emerging contaminant from aqueous solution using biochar derived from soap nut seeds. Environmental Pollution 287:117632

  5. Qambrani NA, Rahman MM, Won S et al (2017) Biochar properties and eco-friendly applications for climate change mitigation, waste management, and wastewater treatment: a review. Renew Sustain Energy Rev 79:255–273

    Article  CAS  Google Scholar 

  6. Periyasamy S, Temesgen T (2021) Application of Biochar for Wastewater Treatment. In: Biochar and its Application in Bioremediation. Springer, pp 363–380

  7. Ding Y, Liu Y, Liu S et al (2016) Biochar to improve soil fertility. A review Agronomy for sustainable development 36:1–18

    Article  Google Scholar 

  8. Diatta AA, Fike JH, Battaglia ML et al (2020) Effects of biochar on soil fertility and crop productivity in arid regions: a review. Arab J Geosci 13:1–17

    Article  Google Scholar 

  9. Xiong Z, Shihong Z, Haiping Y et al (2013) Influence of NH3/CO2 modification on the characteristic of biochar and the CO2 capture. BioEnergy Research 6:1147–1153

    Article  CAS  Google Scholar 

  10. Koide RT, Nguyen BT, Howard Skinner R et al (2018) Comparing biochar application methods for switchgrass yield and C sequestration on contrasting marginal lands in Pennsylvania, USA. BioEnergy Research 11:784–802

    Article  CAS  Google Scholar 

  11. Behera B, Dey B, Balasubramanian P (2020) Algal biodiesel production with engineered biochar as a heterogeneous solid acid catalyst. Bioresource technology 310:123392

  12. Chi NTL, Anto S, Ahamed TS, et al (2021) A review on biochar production techniques and biochar based catalyst for biofuel production from algae. Fuel 287:119411

  13. Al-Wabel MI, Hussain Q, Usman ARA et al (2018) Impact of biochar properties on soil conditions and agricultural sustainability: a review. Land Degrad Dev 29:2124–2161

    Article  Google Scholar 

  14. Selvam SM, Janakiraman T, Paramasivan B (2021) Characterization of engineered corn cob biochar produced in allothermal pyrolysis reactor. Materials Today: Proceedings 47:312–317

    Google Scholar 

  15. Sahoo D, Remya N (2020) Influence of operating parameters on the microwave pyrolysis of rice husk: biochar yield, energy yield, and property of biochar. Biomass Conversion and Biorefinery 1–10

  16. Chandra S, Bhattacharya J (2019) Influence of temperature and duration of pyrolysis on the property heterogeneity of rice straw biochar and optimization of pyrolysis conditions for its application in soils. J Clean Prod 215:1123–1139

    Article  CAS  Google Scholar 

  17. Weber K, Quicker P (2018) Properties of biochar. Fuel 217:240–261

    Article  CAS  Google Scholar 

  18. Tag AT, Duman G, Ucar S, Yanik J (2016) Effects of feedstock type and pyrolysis temperature on potential applications of biochar. J Anal Appl Pyrol 120:200–206

    Article  CAS  Google Scholar 

  19. Mašek O, Budarin V, Gronnow M et al (2013) Microwave and slow pyrolysis biochar—comparison of physical and functional properties. J Anal Appl Pyrol 100:41–48

    Article  Google Scholar 

  20. Li J, Dai J, Liu G et al (2016) Biochar from microwave pyrolysis of biomass: a review. Biomass Bioenerg 94:228–244

    Article  CAS  Google Scholar 

  21. Chu G, Zhao J, Chen F et al (2017) Physi-chemical and sorption properties of biochars prepared from peanut shell using thermal pyrolysis and microwave irradiation. Environ Pollut 227:372–379

    Article  CAS  PubMed  Google Scholar 

  22. Mubarak NM, Sahu JN, Abdullah EC, Jayakumar NS (2016) Plam oil empty fruit bunch based magnetic biochar composite comparison for synthesis by microwave-assisted and conventional heating. J Anal Appl Pyrol 120:521–528

    Article  CAS  Google Scholar 

  23. Abas FZ, Ani FN (2014) Comparing characteristics of oil palm biochar using conventional and microwave heating. Jurnal Teknologi 68:

  24. Haeldermans T, Campion L, Kuppens T, et al (2020) A comparative techno-economic assessment of biochar production from different residue streams using conventional and microwave pyrolysis. Bioresource Technology 318:124083

  25. Mohamed BA, Ellis N, Kim CS et al (2016) Engineered biochar from microwave-assisted catalytic pyrolysis of switchgrass for increasing water-holding capacity and fertility of sandy soil. Sci Total Environ 566:387–397

    Article  PubMed  Google Scholar 

  26. Foong SY, Liew RK, Yang Y, et al (2020) Valorization of biomass waste to engineered activated biochar by microwave pyrolysis: progress, challenges, and future directions. Chemical Engineering Journal 389:124401

  27. Selvam SM, Paramasivan B (2022) Microwave assisted carbonization and activation of biochar for energy-environment nexus: a review. Chemosphere 286:131631

  28. Lo SL, Huang YF, te Chiueh P, Kuan WH (2017) Microwave pyrolysis of lignocellulosic biomass. Enrgy Proced 105:41–46

    Article  CAS  Google Scholar 

  29. el Naqa I, Murphy MJ (2015) What is machine learning? In: Machine learning in radiation oncology. Springer, pp 3–11

  30. Xing J, Luo K, Wang H, et al (2019) A comprehensive study on estimating higher heating value of biomass from proximate and ultimate analysis with machine learning approaches. Energy 188:116077

  31. Tang Q, Chen Y, Yang H et al (2020) Prediction of bio-oil yield and hydrogen contents based on machine learning method: effect of biomass compositions and pyrolysis conditions. Energy Fuels 34:11050–11060

    Article  CAS  Google Scholar 

  32. Umenweke G, Afolabi IC, Epelle EI, Okolie JA (2022) Machine learning methods for modeling conventional and hydrothermal gasification of waste biomass: a review. Bioresource Technology Reports 100976

  33. Cao H, Xin Y, Yuan Q (2016) Prediction of biochar yield from cattle manure pyrolysis via least squares support vector machine intelligent approach. Biores Technol 202:158–164

    Article  CAS  Google Scholar 

  34. Zhu X, Li Y, Wang X (2019) Machine learning prediction of biochar yield and carbon contents in biochar based on biomass characteristics and pyrolysis conditions. Bioresource technology 288:121527

  35. Pathy A, Meher S, Balasubramanian P (2020) Predicting algal biochar yield using eXtreme Gradient Boosting (XGB) algorithm of machine learning methods. Algal Research 50:102006

  36. Narde SR, Remya N (2021) Biochar production from agricultural biomass through microwave-assisted pyrolysis: predictive modelling and experimental validation of biochar yield. Environment, Development and Sustainability 1–14

  37. Huang Z, Manzo M, Xia C, et al (2022) Effects of waste-based pyrolysis as heating source: meta-analyze of char yield and machine learning analysis. Fuel 318:123578

  38. Tang Q, Chen Y, Yang H, et al (2021) Machine learning prediction of pyrolytic gas yield and compositions with feature reduction methods: effects of pyrolysis conditions and biomass characteristics. Bioresource Technology 339:125581

  39. Cheng F, Luo H, Colosi LM (2020) Slow pyrolysis as a platform for negative emissions technology: an integration of machine learning models, life cycle assessment, and economic analysis. Energy Conversion and Management 223:113258

  40. Nguyen XC, Ly QV, Peng W, et al (2021) Vertical flow constructed wetlands using expanded clay and biochar for wastewater remediation: a comparative study and prediction of effluents using machine learning. Journal of hazardous materials 413:125426

  41. Li J, Pan L, Suvarna M, et al (2020) Fuel properties of hydrochar and pyrochar: prediction and exploration with machine learning. Applied Energy 269:115166

  42. Olatunji OO, Akinlabi S, Madushele N, Adedeji PA (2019) Estimation of the elemental composition of biomass using hybrid adaptive neuro-fuzzy inference system. BioEnergy Research 12:642–652

    Article  CAS  Google Scholar 

  43. Nzediegwu C, Arshad M, Ulah A, et al (2021) Fuel, thermal and surface properties of microwave-pyrolyzed biochars depend on feedstock type and pyrolysis temperature. Bioresource Technology 320:124282

  44. Yadav K, Tyagi M, Kumari S, Jagadevan S (2019) Influence of process parameters on optimization of biochar fuel characteristics derived from rice husk: a promising alternative solid fuel. BioEnergy Research 12:1052–1065

    Article  CAS  Google Scholar 

  45. Abd NI, Al-Mayah AM, Muallah SK (2018) Microwave pyrolysis of water Hyacinth for biochar production using Taguchi method. Int J Eng Technol 7:121–126

    Article  CAS  Google Scholar 

  46. Salema AA, Yeow YK, Ishaque K et al (2013) Dielectric properties and microwave heating of oil palm biomass and biochar. Ind Crops Prod 50:366–374

    Article  CAS  Google Scholar 

  47. Fodah AEM, Ghosal MK, Behera D (2021) Bio-oil and biochar from microwave-assisted catalytic pyrolysis of corn stover using sodium carbonate catalyst. J Energy Inst 94:242–251

    Article  Google Scholar 

  48. Zhao B, O’Connor D, Zhang J et al (2018) Effect of pyrolysis temperature, heating rate, and residence time on rapeseed stem derived biochar. J Clean Prod 174:977–987

    Article  CAS  Google Scholar 

  49. Zhang X, Zhang P, Yuan X, et al (2020) Effect of pyrolysis temperature and correlation analysis on the yield and physicochemical properties of crop residue biochar. Bioresource technology 296:122318

  50. Yadav K, Jagadevan S (2021) Effect of pyrolysis of rice husk–derived biochar on the fuel characteristics and adsorption of fluoride from aqueous solution. BioEnergy Research 14:964–977

    Article  CAS  Google Scholar 

  51. Li S, Harris S, Anandhi A, Chen G (2019) Predicting biochar properties and functions based on feedstock and pyrolysis temperature: a review and data syntheses. J Clean Prod 215:890–902

    Article  CAS  Google Scholar 

  52. Mathiarasu A, Pugazhvadivu M (2019) Production of bio-oil from soapnut seed by microwave pyrolysis. In: IOP conference series: Earth and environmental science. IOP Publishing, p 012022

  53. Gahane D, Biswal D, Mandavgane SA (2022) Life Cycle Assessment of Biomass Pyrolysis. BioEnergy Research 1–20

  54. Gronnow MJ, Budarin VL, Mašek O et al (2013) Torrefaction/biochar production by microwave and conventional slow pyrolysis–comparison of energy properties. Gcb Bioenergy 5:144–152

    Article  CAS  Google Scholar 

  55. Zhou J, Liu S, Zhou N et al (2018) Development and application of a continuous fast microwave pyrolysis system for sewage sludge utilization. Biores Technol 256:295–301

    Article  CAS  Google Scholar 

  56. Huang Y-F, Cheng P-H, Chiueh P-T, Lo S-L (2017) Leucaena biochar produced by microwave torrefaction: fuel properties and energy efficiency. Appl Energy 204:1018–1025

    Article  Google Scholar 

  57. Liew RK, Nam WL, Chong MY et al (2018) Oil palm waste: an abundant and promising feedstock for microwave pyrolysis conversion into good quality biochar with potential multi-applications. Process Saf Environ Prot 115:57–69

    Article  CAS  Google Scholar 

  58. Chen L, Yu Z, Xu H et al (2019) Microwave-assisted co-pyrolysis of Chlorella vulgaris and wood sawdust using different additives. Biores Technol 273:34–39

    Article  CAS  Google Scholar 

  59. Said MSM, Azni AA, Ghani WAWAK, et al (2022) Production of biochar from microwave pyrolysis of empty fruit bunch in an alumina susceptor. Energy 240:122710

  60. Menya E, Olupot PW, Storz H et al (2020) Optimization of pyrolysis conditions for char production from rice husks and its characterization as a precursor for production of activated carbon. Biomass Conversion and Biorefinery 10:57–72

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors thank the Department of Biotechnology and Medical Engineering of National Institute of Technology Rourkela for providing the research facility.

Funding

This work was supported by [Science and Engineering Research Board, Department of Science and Technology (SERB-DST), India] (Grant numbers [ECR/ES/2017/003397]. The author MSS has received PhD research support from Ministry of Education (MoE), Government of India (GoI).

Author information

Authors and Affiliations

Authors

Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by [Mari Selvam S], [Balasubramanian P]. The first draft of the manuscript was written by [Mari Selvam S] and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Paramasivan Balasubramanian.

Ethics declarations

Competing Interests

The authors declare no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mari Selvam, S., Balasubramanian, P. Influence of Biomass Composition and Microwave Pyrolysis Conditions on Biochar Yield and its Properties: a Machine Learning Approach. Bioenerg. Res. 16, 138–150 (2023). https://doi.org/10.1007/s12155-022-10447-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12155-022-10447-9

Keywords

Navigation