Abstract
Poly(vinyl chloride) (PVC)-based polymer electrolytes films consisting of lithium trifluromethanesulfonate (LiCF3SO3)-ethylene carbonate (EC) were prepared by the solution-casting method. Ionic conductivities of the electrolytes have been determined by an impedance studies in the temperature range of 298–373 K. Complexation of the prepared electrolytes is studied by X-ray diffraction (XRD) analysis. Thermogravimetric analysis (TGA) was used to confirm the thermal stability of the polymer electrolytes. The conductivity-temperature plots were found to followan Arrhenius nature. All these films are found to be thermally stable until 132–167°C.
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Bhide A, Hariharan K 2006 A new polymer electrolyte system (PEO)n:NaPO3. J. Power Sources 159: 1450–1457
Cha E H, Macfarlane D R, Forsyth M, Lee C W 2004 Ionic conductivity studies of polymeric electrolytes containing lithium salt with plasticizer. Electrochim. Acta 50: 335–338
Fan L Z, Maier J 2006 Composite effects in poly(ethylene oxide)-succinonitrile-based all-solid electrolytes. Electrochem. Commum. 8: 1753–1756
Li WL, Yuan MY, Yang MJ 2006 Dual-phase polymer electrolyte with enhanced phase compatibility based on Poly(MMA-g-PVC)/PMMA. Euro. Polym. J. 42: 1396–1402
Pradhan DK, Samantaray BK, Choudhary RNP, Thakur AK 2005 Effect of plasticizer on structure—property relationship in composite polymer electrolytes. J. Power Sources 139: 384–393
Qian X M, Gu N Y, Cheng Z L, Yang X R, Wang E K, Dong S J 2002 Plasticizer effect on the ionic conductivity of PEO-based polymer electrolyte. Mater. Chem. Phys. 74: 98–103
Rajendran S, Sivakumar M, Subadevi R 2004 Investigations on the effect of various plasticizers in PVA-PMMA solid polymer blend electrolytes. Mater. Lett. 58: 641–649
Ramesh S, Yahaya A H, Arof A K 2002 Dielectric behaviour of PVC-based polymer electrolytes. Solid State Ionics 152–153, 291–294
Santhosh P, Vasudevan T, Gopalan A, Lee K P 2006 Preparation and properties of new cross-linked polyurethane acrylate electrolytes for lithium batteries. J. Power Sources 160: 609–620
Stephan AM 2006 Review on gel polymer electrolytes for lithium batteries. Euro. Polym. J. 42: 21–42
Stephan A M, Kumar S G, Renganathan N G, Kulandainathan M A 2005 Characterization of poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) electrolytes complexed with different lithium salts. Euro. Polym. J. 41: 15–21
Stephan A M, Saito Y, Muniyandi N, Renganathan N G, Kalyanasundaram S, Elizabeth R N 2002 Preparation and characterization of PVC/PMMA blend polymer electrolytes complexed with LiN(CF3SO2)2. Solid State Ionics 148: 467–473
Sun X G, Liu G, Xie J B, Han Y B, Kerr J B 2004 New gel polyelectrolytes for rechargeable lithium batteries. Solid State Ionics 175: 713–716
Uma T, Mahalingan T, Stimming U 2005 Solid polymer electrolytes based on poly(vinylchloride)-lithium sulfate. Mater. Chem. Phys. 90: 239–244
Uma T, Mahalingam T, Stimming U 2004 Conductivity and thermal studies of solid polymer electrolytes prepared by blending polyvinylchloride, polymethylmethacrylate and lithium sulfate. Mater. Chem. Phys. 85: 131–136
Vickraman P, Ramamurthy S 2006 A study on the blending effect of PVDF in the ionic transport mechanism of plasticized PVC-LiBF4 polymer electrolyte. Mater. Lett. 60: 3431–3436
Yahya MZA, Arof AK 2003 Effect of oleic acid plasticizer on chitosan-lithium acetate solid polymer electrolytes. Euro. Polym. J. 39: 897–902
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Ramesh, S., Teh, G.B., Louh, RF. et al. Preparation and characterization of plasticized high molecular weight PVC-based polymer electrolytes. Sadhana 35, 87–95 (2010). https://doi.org/10.1007/s12046-010-0002-4
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DOI: https://doi.org/10.1007/s12046-010-0002-4