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An overview of quantification methods in energy-dispersive X-ray fluorescence analysis

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Abstract.

This paper reviews the major factors influencing the accuracy of the energy-dispersive X-ray fluorescence (EDXRF) analysis including physical and chemical matrix effects (resulting from particle size, surface irregularity, mineralogy, moisture, absorption and enhancement) as well as the correction procedures with emphasis on the analysis of unprepared samples. Quantification methods for thin samples, samples with intermediate thickness and thick samples are presented including fundamental parameter methods, influence coefficient algorithms, empirical coefficient algorithms and quantification methods based on scattered primary radiation. Quality control procedures are also reviewed.

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References

  1. R Jenkins, R W Gould and D Gedcke, Quantitative X-ray spectrometry, 2nd edn (Marcel Dekker, New York, 1995)

    Google Scholar 

  2. R Tertian and F Claisse, Principles of quantitative X-ray fluorescence analysis (Wiley, New York, 1982)

    Google Scholar 

  3. R E Van Grieken and A A Markowicz (eds) Handbook of X-ray spectrometry, 2nd edn, revised and expanded (Marcel Dekker, New York, Basel, 2002)

    Google Scholar 

  4. A A Markowicz, in: Portable X-ray fluorescence spectrometry – capabilities for in situ analysis edited by P J Potts and M West (RSC Publishing, Cambridge, 2008) p. 13

    Chapter  Google Scholar 

  5. IUPAC, Commission on Spectrochemical and Other Optical Procedures for Analysis (Analytical Chemistry Division), Nomenclature, symbols, units and their usage in spectrochemical analysis – II, Spectrochim. Acta. B33, 242 (1978)

    Google Scholar 

  6. D Wegrzynek, A Markowicz, E Chinea-Cano and S Bamford, X-Ray Spectrom. 32, 317 (2003)

    Article  Google Scholar 

  7. P F Berry, T Furuta and J R Rhodes, Advances in X-Ray Anal. 12, 612 (1969)

    Google Scholar 

  8. R P Gardner, D Betel and K Verghese, Int. J. Appl. Radiat. Isot. 24, 135 (1973)

    Article  Google Scholar 

  9. P Van Dyck, A Markowicz and R Van Grieken, X-Ray Spectrom. 14, 183 (1985)

    Article  Google Scholar 

  10. B Holynska and A Markowicz, X-Ray Spectrom. 11, 117 (1982)

    Article  Google Scholar 

  11. P J Potts, P C Webb and O Williams-Thorpe, J. Anal. Atomic Spectrom. 12, 769 (1997)

    Article  Google Scholar 

  12. G Liangquan, Z Ye, C Yeshun and L Wangchang, Appl. Radiat. Isot. 49, 1713 (1998)

    Article  Google Scholar 

  13. P Potts, O Williams-Thorpe and P C Webb, J. Geostandards Geoanal. 21, 29 (1997)

    Article  Google Scholar 

  14. S Piorek, in: Current protocols in field analytical chemistry edited by V Lopez-Avila, D Barcelo, W Beckert, S C Goheen, K Jinno, L H Keith and J H Rittenburg (John Wiley & Sons, New York, 1998) Chapter 3, p. 3B1.1

    Google Scholar 

  15. G Liangquan, Y Zhang, Y Cheng, S Zhou, T Xie and S Hou, X-Ray Spectrom. 26, 303 (1997)

    Article  Google Scholar 

  16. A Markowicz, N Haselberger and U Whai Zin Oo, X-Ray Spectrom. 22, 160 (1992)

    Article  Google Scholar 

  17. P Kregsamer, C Streli and P Wobrauschek, in: Handbook of X-ray spectrometry, 2nd edn, revised and expanded, edited by R E Van Grieken and A A Markowicz (Marcel Dekker, New York, Basel, 2002) Chapter 9, p. 582

    Google Scholar 

  18. A A Markowicz and R E Van Grieken, in: Handbook of X-ray spectrometry, 2nd edn, revised and expanded, edited by R E Van Grieken and A A Markowicz (Marcel Dekker, New York, Basel, 2002) Chapter 6, p. 407

    Google Scholar 

  19. A Markowicz and A A Abdunnabi, X-Ray Spectrom. 20, 97 (1991)

    Article  Google Scholar 

  20. R D Giauque, R B Garrett and L Y Goda, Anal. Chem. 51, 511 (1979)

    Article  Google Scholar 

  21. A Markowicz and N Haselberger, Appl. Radiat. Isot. 43, 777 (1992)

    Article  Google Scholar 

  22. D Wegrzynek, B Holynska and T Pilarski, X-Ray Spectrom. 22, 80 (1993)

    Article  Google Scholar 

  23. Austrian Matrix Correction Routine, Description of the program (Technical University of Graz, Austria, 1990)

  24. A Markowicz, N Haselberger, H S El Hassam and M S A Sewando, J. Radioanal. Nucl. Chem. 158, 409 (1992)

    Article  Google Scholar 

  25. D Wegrzynek, A Markowicz and E Chinea-Cano, X-Ray Spectrom. 32, 119 (2003)

    Article  Google Scholar 

  26. A A Markowicz, in: Handbook of X-ray spectrometry, 2nd edn, revised and expanded, edited by R E Van Grieken and A A Markowicz (Marcel Dekker, New York, Basel, 2002) Chapter 1, p. 33

    Google Scholar 

  27. J L de Vries and B A R Vrebos, in: Handbook of X-ray spectrometry, 2nd edn, revised and expanded, edited by R E Van Grieken and A A Markowicz (Marcel Dekker, New York, Basel, 2002) Chapter 5, p. 341

    Google Scholar 

  28. A Markowicz, X-Ray Spectrom. 13, 166 (1984)

    Article  Google Scholar 

  29. J Kikkert, Adv. X-Ray Anal. 26, 401 (1983)

    Google Scholar 

  30. L G Livingstone, X-Ray Spectrom. 11, 89 (1082)

  31. F He and P J Van Espen, Anal. Chem. 63, 2247 (1991)

    Article  Google Scholar 

  32. T Shiraiwa and N Fujino, Jpn J. Appl. Phys. 5, 886 (1966)

    Article  ADS  Google Scholar 

  33. J W Criss and L S Birks, Anal. Chem. 40, 1080 (1968)

    Article  Google Scholar 

  34. R M Rousseau, The Rigaku J. 18, 8 (2001)

    Google Scholar 

  35. R Padilla Alvarez, A Markowicz, D Wegrzynek, E Chinea-Cano and S A Bamford, X-Ray Spectrom. 36, 27 (2007)

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Nuclear Sciences and Applications, Division of Physical and Chemical Sciences, Nuclear Spectrometry & Applications Laboratory, International Atomic Energy Agency, P.O. Box 100, Wagramer Strasse 5, 1400, Vienna, Austria

    A MARKOWICZ

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MARKOWICZ, A. An overview of quantification methods in energy-dispersive X-ray fluorescence analysis. Pramana - J Phys 76, 321–329 (2011). https://doi.org/10.1007/s12043-011-0045-z

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