Abstract
Problems connected with quantitative EDXRF analysis of intermediate thickness samples are addressed. The first one is a systematic study of the various contributions to the total error of the E-T method. Special attention is also given to the enhancement effect for intermediate thickness samples; in this context both monochromatic and bichromatic approaches are adapted to a known theoretical model.
Similar content being viewed by others
References
J. LEROUX, MAHMUD, Anal. Chem., 38 (1966) 76.
R. D. GIAUQUE, F. S. GOULDING, J. M. JAKLEVIC, R. H. PEHL, Anal. Chem., 45 (1973) 671.
R. D. GIAUQUE, R. B. GARRETT, L. Y. GODA, Anal. Chem., 51 (1979) 511.
P. VAN DYCK, A. MARKOWICZ, R. VAN GRIEKEN, X-Ray Spectrom., 9 (1980) 70.
K. K. NIELSON, Anal. Chem., 49 (1977) 641.
A. MARKOWICZ, X-Ray Spectrom., 8 (1979) 14.
P. M. VAN DYCK, R. E. VAN GRIEKEN, Anal. Chem., 52 (1980) 1859.
A. MARKOWICZ, N. HASELBERGER, P. MULENGA, X-ray Spectrom., (in press).
AXIL X-Ray Analysis Software, Canberra Packard, Benelux.
R. TERTIAN, F. CLAISSE, Principles of Quantitative X-ray Fluorescence Analysis, Heyden, London-Philadelphia-Rheine, 1982, p. 75.
Austrian Matrix Correction Routine, Description of the Program, Technical University of Graz, Austria.
T. P. THINH, J. LEROUX, X-Ray Spectrom., 8 (1979) 85.
CH. POEHN, Y. WERNISCH, W. HANKE, X-Ray Spectrom., 14 (1985) 120.
K. DEBERTIN, R. G. HELMER, Gamma- and X-Ray Spectrometry with Semiconductor Detectors, North Holland, Amsterdam-Oxford-New York-Tokyo, 1988, p. 348.
G. POLLAI, M. MANTLER, H. EBEL, Spectrochim. Acta Part B, 26 (1971) 747.
P. M. VAN DYCK, SZ. B. TÖRÖK, R. E. VAN GRIEKEN, Anal. Chem., 58 (1986) 1761.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Markowicz, A., Haselberger, N., El Hassan, H.S. et al. Accuracy of the emission-transmission method applied in XRF analysis of intermediate thickness samples. Journal of Radioanalytical and Nuclear Chemistry, Articles 158, 409–415 (1992). https://doi.org/10.1007/BF02047126
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02047126