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Diffusion of propylene adsorbed in Na-Y and Na-ZSM5 zeolites: Neutron scattering and FTIR studies

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Abstract

Here we report the quasielastic neutron scattering and FTIR studies on the dynamics of propylene adsorbed in Na-Y and Na-ZSM5 zeolites. QENS data show that although the mechanism of translational motion of propylene is jump diffusion in both the cases of Na-Y and Na-ZSM5 zeolites, the diffusivity is affected by the host size and is hindered in the case of Na-ZSM5. FTIR studies showed that guest-host interaction in Na-ZSM5 is stronger than that in Na-Y zeolite corroborating the QENS results.

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References

  1. G Tomlinson, Modern zeolites, structure and function in detergents and petrochemicals (Traw Tech Publications Ltd., Switzerland, 1998)

    Google Scholar 

  2. H Jobic et al, Phys. Rev. Lett. 82, 4260 (1999)

    Article  ADS  Google Scholar 

  3. Ahmed Sayeed et al, J. Phys. Chem. B107, 527 (2003)

    Google Scholar 

  4. R Mukhopadhyay et al, Phys. Rev. E66, 061201 (2002)

  5. S Mitra et al, Pramana — J. Phys. 63, 449 (2004)

    Article  ADS  Google Scholar 

  6. Siddharth Gautam et al, Phys. Rev. E74, 041202 (2006)

  7. S Gautam et al, Chem. Phys. Lett. 442, 311 (2007)

    Article  ADS  Google Scholar 

  8. S Mitra et al, Appl. Phys. A74, S1308 (2002)

    ADS  Google Scholar 

  9. R Mukhopadhyay et al, Nucl. Instrum. Methods A474, 55 (2001)

    ADS  Google Scholar 

  10. M Bee, Quasielastic neutron scattering (Adam Hilger, Bristol, 1988)

    Google Scholar 

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Correspondence to S. Gautam.

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Gautam, S., Tripathi, A.K., Kamble, V.S. et al. Diffusion of propylene adsorbed in Na-Y and Na-ZSM5 zeolites: Neutron scattering and FTIR studies. Pramana - J Phys 71, 1153–1157 (2008). https://doi.org/10.1007/s12043-008-0239-1

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  • DOI: https://doi.org/10.1007/s12043-008-0239-1

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