Abstract
The electron paramagnetic resonance parameters, zero-field splittings (ZFSs) b 02 , b 04 , b 44 , b 06 , b 46 and the g factors for Gd3+ on the tetragonal Y3+ site in KY3F10 are theoretically studied from the superposition model for the ZFSs and the approximation formula for the g factor containing the admixture of the ground 8S7/2 and the excited 6L7/2 (L=P, D, F, G) states via the spin-orbit coupling interactions, respectively. By analysing the above ZFSs, the local structure information for the impurity Gd3+ is obtained, i.e., the impurity-ligand bonding angles related to the four-fold (C4) axis for the impurity Gd3+ center are found to be about 0.6° larger than those for the host Y3+ site in KY3F10. The calculated ZFSs based on the above angular distortion as well as the g factors are in reasonable agreement with the observed values. The present studies on the ZFSs and the local structure would be helpful to understand the optical and magnetic properties of this material with Gd dopants.
Similar content being viewed by others
References
S L Chamberlain, G Luo and L R Corruccini, Phys. Rev. B67, 134414 (2003)
S L Chamberlain and L R Corruccini, Phys. Rev. B71, 24434 (2005)
S T Bramwell and M J P Gingras, Science 294, 1495 (2001)
M Diaf, E Boulma and Z Chouahda, Proceedings of SPIE 5036, 419 (2003)
P Porcher and P Caro, J. Chem. Phys. 68, 4176, 4183 (1978)
A Braud, S Girard, J L Doualan, M Thuau, R Moncorge and A M Tkachuk, Phys. Rev. B61, 5280 (2000)
E Boulma, M Diaf, J P Jouart, M Bouffard, J L Doualan and R Moncorge, J. Phys.: Condens. Matter 18, 6721 (2006).
K J Kim, A Jouini, A Yoshikawa, R Simura, G Boulon and T Fukuda, J. Crystal Growth 299, 171 (2007)
A Braud, P Y Tigreat, J L Doualan and R Moncorge, Appl. Phys. B72, 909 (2001)
P Y Tigreat, J L Doualan, C Budasca and R Moncorge, J. Lumin. 94/95, 23 (2001)
A Grzechnik, W A Crichton and J Y Gesland, Solid State Sci. 5, 757 (2003)
M Yamaga, M Honda, J-P R Wells, T P J Han and H G Gallagher, J. Phys.: Condens. Matter 12, 8727 (2000)
V F Tarasov, G S Shakurov, B Z Malkin and C A Hutchinson, J. Alloys Compounds 250, 364 (1997)
B Z Malkin, V F Tarasov and G S Sakurov, JETP Lett. 62, 811 (1995)
M F Joubert, G Boulon and F Gaume, Chem. Phys. Lett. 80, 367 (1981)
A M Debaud-Minorel, M Mortier, J Y Buzare and J Y Gesland, Solid State Commun. 95, 167 (1995)
R C Weast, CRC handbook of chemistry and physics (CRC Press, Boca Raton, 1989) p. F187
M Moreno, M T Barriuso and J A Armaburu, Appl. Magn. Reson. 3, 283 (1992)
Z M Li and W L Shuen, J. Phys. Chem. Solids 57, 1673 (1996)
H N Dong, Z. Naturforsch. A60, 615 (2005)
D J Newman and B Ng, Rep. Prog. Phys. 52, 699 (1989)
D J Newman and W Urban, Adv. Phys. 24, 793 (1975)
Vishwamittar and S P Puri, J. Chem. Phys. 61, 3720 (1974)
C Rudowicz, J. Phys. C20, 6033 (1987)
J Y Buzare, M Fayet-Bonnel and J C Fayet, J. Phys. C14, 67 (1981)
R G Wybourne, Phys. Rev. 148, 317 (1966)
A Abragam and B Bleaney, Electron paramegnetic resonance of transition ions (Oxford University Press, London, 1970)
R T Wegh, H Donker and A Meijerink, Phys. Rev. B56, 13841 (1997)
W T Carnall, G L Goodman, K Rajnak and R S Rana, Argonne National Laboratory Report No. ANL-88-8 (1988)
J Y Buzare, M Fayet-Bonnel and J C Fayet, J. Phys. C14, 67 (1981)
D J Newman and G E Stedman, J. Chem. Phys. 51, 3013 (1969)
T Revai, Sov. Phys. Solid State 10, 1014 (1968)
J M Baker and F I B Williams, Proc. Phys. Soc. 78, 1340 (1961)
J Sierro, Helv. Phys. Acta 36, 505 (1963)
W T Carnall, P R Fields and K Rajnak, J. Chem. Phys. 49, 4443 (1968)
P G Fernandez, M T Barriuso, J A Aramburu and M Moreno, Chem. Phys. Lett. 374, 151 (2003)
J M Garcia-Lastra, J A Aramburu, M T Barriuso and M Moreno, Chem. Phys. Lett. 385, 286 (2004)
M T Barriuso, J M Garcia-Lastra, J A Aramburu and M Moreno, Solid State Commun. 120, 1 (2001)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wu, SY., Zhang, HM., Lu, GD. et al. Electron paramagnetic resonance parameters and local structure for Gd3+ in KY3F10 . Pramana - J Phys 69, 451–457 (2007). https://doi.org/10.1007/s12043-007-0146-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12043-007-0146-x