Abstract
A complete normal coordinate analysis was performed for five-coordinate non-rigid triarylantimony diester SbPh3(O2CR)2, known to be a bioactive molecule, using Wilson G-F matrix method and Urey Bradley force field. The study of vibrational dynamics was performed using the concept of group frequencies and band intensities.
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H Barucki, S J Coles, J F Costello, T Gelbrich and M B Hursthouse, J. Chem Soc. Dalton Trans. 2319–2325 (2000)
D A Fletcher, R F McMeeking and D Parkin, J. Chem. Inf. Comput. Sci. 36, 746 (1996)
N C Norman, Phosphorous Sulfur Silicon Relat. Elem. 87, 167 (1994)
C J Carmelt, A H Cowley, A Decken and N C Norman, J. Organomet. Chem. 496, 59 (1995)
C Ludwig, M Dolny and H J Gotze, Spectrochim. Acta Part A 56, 547 (2000)
K A Jensen and H P Nielsen, Acta Chem. Scand. 17, 1875 (1963)
P Raj, K Singhal and R Misra, Euro. J. Chem. (2006) (communicated)
K Chandarshekhar, H M Behl, K Vishal, O P Sidhu, P Pushpangadan, C V Rao, S K Shukla, A Ranjan, R Kant, K Singhal and P Raj, Triorganoantimony compounds for pesticidal use, PCT/IN2004/000407; WO/2006/067800 K Singhal, P Raj, K Chandarshekhar, R Kant, A K Saxena and A Ranjan, Euro. J. Med. Chem. (2006) (communicated)
E B Wilson Jr., J C Decius and P C Cross, Molecular vibrations (Dover Publications, New York, 1980) pp. 11–31
H C Urey and C A Bradley, Phys. Rev. 38, 1969 (1931)
T Shimanouchi, Computer program for normal coordinate treatment of polyatomic molecules (University of Tokyo, 1968)
S Srivastava, S Srivastava, S Singh, V P Gupta and V D Gupta, Eur. Polym. J. 38(7), 1423 (2002)
H J Gotze, P Lemannczich and B Schaaf, Spectrochim. Acta Part A 50, 1871 (1994)
J R Scherer, Spectrochim. Acta 20, 345 (1964)
M Tasumi, T Urano and M Nakata, J. Mol. Structure 146, 383 (1986)
C L Lau and R G Snyder, Spectrochim. Acta Part A 27, 2073 (1971)
N Misra, O Prasad and L Sinha, Indian J. Biochem. Biophys. 43, 173 (2006)
P K Singh, T Hasan, O Prasad, L Sinha, K Raj and N Misra, Spectroscopy 20(5–6) 275 (2006)
N K Jha, P Sharma and J R Ugal, Indian J. Chem. A32, 74 (1993)
N S Biradar and V K Kulkarni, J. Inorganic Chem. 33, 3781 (1971)
J N R Ruddick and J R Sames, J. Organometal. Chem. 60, 233 (1973)
C Ludwig and H J Gotze, Spectrochim. Acta Part A 51, 2019 (1995)
K Shobatake, C Postmus, J R Ferraro and K Nakamoto, Appl. Spectrosc. 23(1), 12 (1969)
M K Khosa, M Mazhar, S Ali, K Shahid and F Malik, Turk. J. Chem. 30, 345 (2006)
D Shankar, A R Rai, Y P Singh, H Rehwani, V Khushalani and R S Gupta, Bioorgan. Chem. Appl. 2006, 1 (2006)
H A Meinema, A Mackor and J G Noltes, J. Organometal. Chem. 37, 285 (1972)
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Hasan, T., Singh, P.K., Misra, R. et al. Vibrational dynamics of the organometallic compound triarylorganoantimony (V) SbPh3[O2CC(OH)Ph2]2 . Pramana - J Phys 68, 875–881 (2007). https://doi.org/10.1007/s12043-007-0086-5
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DOI: https://doi.org/10.1007/s12043-007-0086-5