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\({\hbox {SO}}_{3}\hbox {H}\)-functionalized magnetic \({\hbox {Fe}}_{3} {\hbox {O}}_{4}\) nanoparticles as an efficient and reusable catalyst for one-pot synthesis of \({\upalpha }\)-amino phosphonates

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Abstract

Nanomagnetic \(\hbox {Fe}_{{3}} \hbox {O}_{{4}} @ \hbox {SiO}_{{2}}\hbox {-SO}_{{3}}\hbox {H}\) (\(\hbox {SO}_{{3}}\hbox {H-MNPs}\)) was prepared via grafting sulfonic acid on the silica-coated \(\hbox {Fe}_{{3}} \hbox {O}_{{4}}\) magnetite nanoparticles (MNPs). The catalytic activity of the prepared \(\hbox {SO}_{{3}}\hbox {H-MNPs}\) was probed through the one-pot synthesis of N-hydroxy-\({\upalpha }\)-amino phosphonates and \({\upalpha }\)-amino phosphonates via three-component couplings of phenylhydroxylamine or amines with aldehydes and trialkyl phosphites at room temperature. The synthesized \(\hbox {SO}_{{3}}\hbox {H-MNPs}\) were characterized by XRD, FT-IR, and SEM. The recoverability of the catalyst was achieved by a simple magnetic decantation and reused at least five times without significant degradation in catalytic activity.

Graphical Abstract

The catalytic activity of the prepared \(\hbox {SO}_{{3}}\hbox {H-MNPs}\) was probed through the one-pot synthesis of N-hydroxy-\({\upalpha }\)-amino phosphonates and \({\upalpha }\)-amino phosphonates via three-component couplings of phenylhydroxylamine or amines with aldehydes and trialkyl phosphites at room temperature.

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Acknowledgements

The authors thank Shahid Chamran University of Ahvaz for financial support (Grant No. 31400.02.3.95).

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  1. Chemistry Department, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Hosein Hamadi & Meysam Norouzi

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  1. Hosein Hamadi
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Correspondence to Hosein Hamadi.

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Hamadi, H., Norouzi, M. \({\hbox {SO}}_{3}\hbox {H}\)-functionalized magnetic \({\hbox {Fe}}_{3} {\hbox {O}}_{4}\) nanoparticles as an efficient and reusable catalyst for one-pot synthesis of \({\upalpha }\)-amino phosphonates. J Chem Sci 130, 128 (2018). https://doi.org/10.1007/s12039-018-1530-4

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