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Synthesis, characterization and crystal structure of new nickel molybdenum complex with the pyridine dicarboxylic acid ligand: Novel precursors for nickel molybdate nanoparticles

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Abstract

A novel nickel molybdenum complex with the 2,6-pyridine dicarboxylic acid ligand was successfully synthesized and characterized by thermogravimetric analysis and single crystal X-ray crystallography. The single-crystal X-ray data revealed that the structure is a hydrated 1-D polymer with two different Ni sites. The synthesized complex was then used as a new precursor for the preparation of the related nickel molybdate nanoparticles. The crystallinity and morphology of the nickel molybdate nanoparticles were characterized by powder X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), transmittance electron microscopy (TEM), and Photoluminescence (PL) spectroscopy.

A novel nickel molybdenum complex with the 2,6-pyridine dicarboxylic acid ligand was synthesized. The results confirmed that monodispersed nanoparticles of NiMoO4 were obtained by thermal decomposition of the complex at 450°C for 8 h.

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Acknowledgements

The authors gratefully acknowledge the financial support from Iran National Science Foundation (INSF).

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Authors and Affiliations

  1. School of Chemistry, University College of Science, University of Tehran, Tehran, Iran

    HAMID EMADI, BAHAREH TAMADDONI JAHROMI & ALI NEMATI KHARAT

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  1. HAMID EMADI
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Correspondence to ALI NEMATI KHARAT.

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EMADI, H., JAHROMI, B.T. & KHARAT, A.N. Synthesis, characterization and crystal structure of new nickel molybdenum complex with the pyridine dicarboxylic acid ligand: Novel precursors for nickel molybdate nanoparticles. J Chem Sci 129, 373–380 (2017). https://doi.org/10.1007/s12039-017-1241-2

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  • DOI: https://doi.org/10.1007/s12039-017-1241-2

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