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Design of non-molecular coordination solids from aqueous solution: [CuIILnX(H2O)], where X=SO4, Cl or H2O and L=pyrazole, imidazole or glutamic acid and n=1 or 4

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Abstract

We have successfully crystallized four new non-molecular coordination solids utilizing the synthons–Cu–OSO3– and –Cu–Cl– in the presence of four organic ligands:[{Cu(pz)4SO4}{Cu(pz)4SO4 (H2O)}]. H2O2, [Cu(imi)4SO4]3, [Cu(imi)4(NO3)2]4 and [Cu(glu)Cl(H2O)]5. Use of glutamic acid resulted in two chiral coordination polymers 5 and [Cu(glu)(H2O)]. H2O 6 depending on the copper source. The paper provides chemical insights to the supramolecular aggregation of a crystal driven by the various competing intermolecular forces.

Crystallization of chiral coordination polymers engineered through extended copper glutamate interactions.

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Acknowledgements

Vineet Kumar acknowledges University Grants Commission (UGC) for a Research Fellowship. Arunachalam Ramanan acknowledges DST for providing continuous funding for the past two decades and infrastructural support.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology Delhi, New Delhi, 110 016, India

    VINEET KUMAR, ARITRA KUNDU, MONIKA SINGH & ARUNACHALAM RAMANAN

  2. Department of Chemistry and Biochemistry, Rowan University, Glassboro, New Jersey, 08028, USA

    KANDALAM V RAMANUJACHARY

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  1. VINEET KUMAR
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  2. ARITRA KUNDU
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  4. KANDALAM V RAMANUJACHARY
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Correspondence to ARUNACHALAM RAMANAN.

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KUMAR, V., KUNDU, A., SINGH, M. et al. Design of non-molecular coordination solids from aqueous solution: [CuIILnX(H2O)], where X=SO4, Cl or H2O and L=pyrazole, imidazole or glutamic acid and n=1 or 4. J Chem Sci 126, 1433–1442 (2014). https://doi.org/10.1007/s12039-014-0678-9

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  • DOI: https://doi.org/10.1007/s12039-014-0678-9

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