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Optical detection of sodium salts of fluoride, acetate and phosphate by a diacylhydrazine ligand by the formation of a colour alkali metal complex

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Abstract

A solution of N, N’-diacylhydrazine ligand in organic solvent is potential for colourimetric detection of F − /AcO − /PO\(_{4}^{3-}\) via -NH deprotonation, tautomerization and its stabilization as a colour alkali metal complex.

Colourimetric detection of fluoride, acetate and phosphate in a semi-aqueous solvent system via deprotonation, tautomerization followed by complex formation which is established by single crystal X-ray structural analysis.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A and 2B Raja S C Mullick Road, Kolkata, 700032, India

    PURNANDHU BOSE, RANJAN DUTTA, I RAVIKUMAR & PRADYUT GHOSH

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  1. PURNANDHU BOSE
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  2. RANJAN DUTTA
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  3. I RAVIKUMAR
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  4. PRADYUT GHOSH
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Correspondence to PRADYUT GHOSH.

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BOSE, P., DUTTA, R., RAVIKUMAR, I. et al. Optical detection of sodium salts of fluoride, acetate and phosphate by a diacylhydrazine ligand by the formation of a colour alkali metal complex. J Chem Sci 123, 869–874 (2011). https://doi.org/10.1007/s12039-011-0154-8

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