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Analysis of Cl…Cl and C-H…Cl intermolecular interactions involving chlorine in substituted 2-chloroquinoline derivatives

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Abstract

Six crystal structures of substituted 2-chloroquinoline derivatives have been analysed to evaluate the role of Cl atom as a self recognizing unit resulting in the formation of Cl…Cl and C-H…Cl interactions to generate supramolecular assembly in the solid state. The features of Type I and Type II geometries associated with Cl…Cl interactions have been analysed to show directional preferences leading to differences in the packing motifs in these crystal structures. C-H…Cl interactions are generated exclusively in structures depicting Type II Cl…Cl interaction have been observed in these structures.

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Authors and Affiliations

  1. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, 560 012, India

    Venkatesha R. Hathwar & T. N. Guru Row

  2. Organic Chemistry Division, School of Advanced Sciences, Vellore Institute of Technology University, Vellore, 632 014, India

    S. Mohana Roopan, R. Subashini & F. Nawaz Khan

Authors
  1. Venkatesha R. Hathwar
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  2. S. Mohana Roopan
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  3. R. Subashini
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  4. F. Nawaz Khan
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  5. T. N. Guru Row
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Correspondence to T. N. Guru Row.

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Hathwar, V.R., Roopan, S.M., Subashini, R. et al. Analysis of Cl…Cl and C-H…Cl intermolecular interactions involving chlorine in substituted 2-chloroquinoline derivatives. J Chem Sci 122, 677–685 (2010). https://doi.org/10.1007/s12039-010-0056-1

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  • DOI: https://doi.org/10.1007/s12039-010-0056-1

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