Abstract
MgO/few-layer graphene (FLG) nanocomposite is proven as an excellent electrode in aqueous supercapacitors (AS). The synergy between the pseudo-capacitive MgO and the double-layer charging nature of FLG that enhances the supercapacitors' specific capacitance (SC) was successfully tested. The SC could be further enhanced by combining MgO/FLG with a third component, such as a conducting polymer (with a Faradaic type of charge storage capability). Herein, such an attempt has been made. MgO/FLG was uniformly filled in polyaniline (PANI) by using a simple in situ polymerization method. X-ray diffraction, electron microscopy, and Raman and Fourier transform infrared spectroscopic analyses clearly showed the formation of a ternary nanocomposite constituted by MgO, FLG and PANI. As anticipated, the ternary nanocomposite (MgO/FLG-filled PANI (MFP)) exhibited an enhanced SC (compared to MgO/FLG) when tested as electrode material in AS. The MFP composite was evaluated for SC using a 3-electrode system. MFP composite exhibited a maximum SC of 347 F g−1 when tested at a scan rate of 5 mV s−1 using 1 M aqueous H2SO4 as the electrolyte. The electrode material assumable with symmetric capacitance achieved a maximum capacitance of 396 F g−1 at a current density of 1 A g−1 and showed a capacitance retention of 81%. In contrast, MgO/FLG exhibited much lower values under similar testing conditions.
Similar content being viewed by others
References
Jammula R K and Srikanth V V S S 2017 Diam. Relat. Mater. 80 18
Das P S, Bakuli S, Biswas I, Mallik A K, Dey A, Mukherjee S et al 2018 Ceram. Int. 44 424
Petnikota S, Srikanth V V S S, Toh J J, Srinivasan M, Bobba C V R, Adams S et al 2019 New J. Chem. 43 9793
Karthikeyan K, Amaresh S, Aravindan V and Lee Y S 2013 J. Mater. Chem. A 1 4105
Marimuthu M, Ganesan S and Johnbosco J Y 2020 Electrochim. Acta 357 136848
Gedela V R and Srikanth V V S S 2014 Appl. Phys. A: Mater. Sci. 115 189
Eftekhari A, Li L and Yang Y 2017 J. Power Sources 347 86
Gedela V, Puttapati S K, Nagavolu C and Srikanth V V S S 2015 Mater. Lett. 152 177
Wang X, Wu D, Song X, Du W, Zhao X and Zhang D 2019 Molecules 24 12
Iqbal J, Ansari M O, Numan A, Wageh S, Al-Ghamdi A, Alam M G et al 2020 Polymers 12 12
Petnikota S, Rotte N K, Reddy M V, Srikanth V V S S and Chowdari B V R 2015 ACS Appl. Mater. Interfaces 7 2301
Gholami Laelabadi K, Moradian R and Manouchehri I 2020 ACS Appl. Energy Mater. 3 5301
Morajkar P P, Abdrabou M K, Salkar A V, Raj A, Elkadi M and Anjum D H 2020 Energy Fuels 34 12960
Da Costa S, Salkar A, Krishnasamy A, Fernandes R and Morajkar P 2022 Fuel 309 122141
Hsiao Y S, Chang Jian C W, Huang T Y, Chen Y L, Huang J H, Wu N J et al 2022 J. Taiwan Inst. Chem. Eng. 134 104318
Lv P, Tang X, Zheng R, Ma X, Yu K and Wei W 2017 Nanoscale Res. Lett. 12 630
Acknowledgement
VVSSS acknowledges financial support to UoH-IoE by MHRD (F11/9/2019-U3(A)).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bejjanki, D., Puttapati, S.K., Pant, H. et al. Novel MgO/few-layer graphene-filled polyaniline ternary nanocomposite as efficient electrode material in aqueous supercapacitors. Bull Mater Sci 46, 48 (2023). https://doi.org/10.1007/s12034-022-02885-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12034-022-02885-0