Abstract
This study deals with the synthesis, characterization and gas sensing interrogations of pure and Cr (5 and 15%) doped ZrO2. The conventional precipitation route is committed for the synthesis of the pure and Cr-doped ZrO2 powder and the films were formulated by drop casting mode by exploiting ZrOCl2·8H2O as precursor, CrO3 as doping agent and NH4OH as stabilizing agent. The structural properties, optical properties and electrical properties of the handled samples were anatomized by X-ray diffraction (XRD), scanning electron microscopy, ultraviolet–differential reflectance spectroscopy (UV-DRS) spectroscopy, photoluminescence (PL) studies and current–voltage (I–V) measurement. The structure and size of the crystal were resolved by XRD. The uniform spherical-like morphology of the particles was favoured by SEM investigation. The bandgap of the materials was reckoned by UV-DRS report. The occupancy of oxygen vacancies in the samples was conceded by PL studies. The ohmic contact of the samples with the electrodes has been professed by I–V measurements. The gas sensing competency of the drop casted films were monitored by the exposure of the different concentrations of reducing gases like ammonia, acetone, ethanol, formaldehyde and xylene. The output data render that all the processed samples exhibits a peak response towards ammonia gas, exclusively 15% of Cr-doped ZrO2 sensor shows an utmost gas response of about 48%, excellent response time and recovery time of about 68 and 72 s, respectively, among other samples. Thus, the fusion of Cr stimulates the gas sensing proficiency of ZrO2.
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Valentina F, Silvia C S, Sara B, Stefania Z and Eugenio B 2018 Asthma Res. Pract. 4 1
Alex P, Wojciech F, Johannes W, Clemens A, Helmut W, Róbert K et al 2018 J. Breath Res. 12 036002
Yuichi S, Yutaro K, Hiroaki T, Toyoaki H, Kazuo S, Toshio I et al 2017 Sensors 17 287
Sara I and Andrea M 2019 Brain Sci. 9 84
Agnes W B, van Berkel J J B N, Jan W D, Agnieszka S, Emile F W and van Schooten F J 2012 J. Breath Res. 6 027108
Durán C M, Monsalve P A G and Mosquera C 2016 J. Mater. Sci. Eng. 157 012029
Chalasani S and Mohan Kumar Ch 2017 IJCIET 8 614
Qiong W and Yunbo S 2015 IJDSN 2015 1
Dimple Rani M, Gomathi T and Maflin Shaby S 2017 IJDR 7 15419
Haoshuang G, Zhao W and Yongming H 2012 Sensors 12 5517
Lado F and Ayoub L 2018 J. Electrochem. Soc. 165 B862
Yu-Feng S, Shao-Bo L, Fan-Li M, Jin-Yun L, Zhen J, Ling-Tao K et al 2012 Sensors 12 2610
Sofian M K, Oussama M E, Imad A A and Marsha C K 2009 Sensors 9 8158
Deshmukh S B, Bari R H, Patil G E, Kajale D D, Jain G H and Patil L A 2012 Int. J. Smart Sensing Intell. Syst. 5 540
Xiangxing X and Xun W 2009 Nano Res. 2 891
Bari R H, Patil S B and Deshmukh S B 2016 J. Nanosci. Nanotechnol. 2 181
John Berlin I 2017 IJARSE 6 204
Suresh S, Jiban P and Isha D 2016 J. Mater Sci. Mater. Electron 27 5622
John Berlin I and Joy K 2015 Physica B 457 182
Shengzhao W and Jun S 2013 J. Sol-Gel Sci. Technol. 67 339
Nian-Qi Y, Zhi-Chao L, Guang-Rui G and Bao-Jia W 2017 Chin. Phys. B 26 106801
Singh A K and Umesh T N 2014 Sci. World J. 2014 1
Aysar S K, Elias S, Azmi Z and Nayereh S 2016 J. Nanomater. 2016 1
Apiwat D, Gamonpetch P, Manop P and Bussarin K 2017 Sens. Actuators B Chem. 242 202
Elisabeth W L, Robert M P, do R Jefferson J, Pavel N D, Sebastian D, Anke P et al 2016 J. Mater. Chem. C 4 62
Deshmukh S B and Bari R H 2015 ILCPA 56 120
Nor Monica A, Jaafar A, Nor Azah Y, Ahmad Hazri A R, Samsulida Abd R and Md. Rakibul H 2016 Biosensors 6 31
Feng Z, Dengyue S, Jiuming X, Shimin X, Huagui H, Jun L et al 2017 IJHT 35 765
Masciandaro S, Torrell M, Leone P and Tarancón A 2019 J. Eur. Ceram. Soc. 39 9
Zeynep O Z and Ender K L 2010 J. Prosthodont. 19 64
Mingji J, SangChul H, TaeHyun S and Kwangsoo N 2000 Physica C 334 243
George F F, Leon M C, Ayo A and Russell B 2010 Sensors 10 5469
Xiaoming F 2014 Adv. Mater. Res 873 164
Dorothée V S and Sabine S 2014 Inorganics 2 468
Rais A, Taibi K, Addou A, Zanoun A and Al-Douri Y 2014 Ceram. Int. 40 14413
Sue-min C and Ruey-an D 2005 Thin Solid Films 489 17
Shi-Wei W, Xiao-Xian H and Jing-Kun G 1996 J. Eur. Ceram. Soc. 16 1057
Ales S, David S, Craig E B and Jiri P 2017 Catalysts 7 168
Geethalakshmi K, Prabhakaran T and Hemalatha J 2012 IJMME 6 256
Mude K M, Mude B M, Raulkar K B, Yawale S S and Yawale S P 2017 Int. J. Chem. Tech. Res. 10 494
Thomas G, Wolfgang W, Michael S P, Bernhard K and Simon P 2016 AIP Adv. 6 025119
Nahida B H, Ghuson H M and Murtada M A 2014 IJCET 4 1627
Deo P, Chernet A, Keya D, Bedvir S, Rishipal S, Shaaban E R et al 2016 Ceram. Int. 42 5600
Khayatian A, Safa S, Azimirad R, AlmasiKashi M and Akhtarianfar S F 2016 Physica E 84 71
Safa S, Azimirad R, Mohammadi Kh, Hejazi R and Khayatian A 2015 Measurement 73 588
Deshmukh S B 2018 IJCPS 7 435
Rifki S, Suhandaa S and Bambang S P 2015 J. Ceram. Process Res. 16 438
Viruthagiri G, Gopinathan E, Shanmugam N and Gobi R 2014 Spectrochim. Acta 131 556
Vinoth E, Gowri Shankar S and Gopalakrishnan N 2018 Appl. Phys. A 124 433
Mote V D, Purushotham Y and Dole B N 2012 JTAP 6 6
Safa S, Azimirad R, Safalou M S and Rabbani M 2015 Desalin. Water Treat. 57 6723
Mishra S K, Roy H, Lohar A K, Samanta S K, Tiwari S and Dutta K 2015 Mater. Sci. Eng. 75 012001
Avner R and Yigal K 2004 J. Appl. Phys. 95 6374
Biener J, Wittstock A, Baumann T, Weissmüller J, Bäumer M and Hamza A 2009 Materials 2 2404
Chengxiang W, Longwei Y, Luyuan Z, Dong X and Rui G 2010 Sensors 10 2088
Wang Z, Yang B, Fu Z, Dong W, Yang Y and Liu W 2005 Appl. Phys. A 81 691
Lin H, Huang C P, Li W, Ni C, Ismat Shah S and Yao-Hsuan T 2006 Appl. Catal. B Environ. 68 1
Sue-min C and Ruey-an D 2007 Chem. Mater. 19 4804
Hemalatha E and Gopalakrishnan N 2019 Appl. Phys. A 125 493
Faisal M, Ruth P, Neil R M, Walter E J and Chintalapalle V R 2016 J. Appl. Phys. 120 2331
Vinoth E, Gowrishankar S and Gopalakrishnan N 2016 Mater. Manuf. Process. 32 377
Artur R and Aleksandra S 2015 Sensors 15 20069
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Hemalatha, E., Gopalakrishnan, N. Effect of Cr on ZrO2 nanostructures for gas sensing investigation. Bull Mater Sci 44, 292 (2021). https://doi.org/10.1007/s12034-021-02585-1
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DOI: https://doi.org/10.1007/s12034-021-02585-1