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Structural, optical spectroscopy, optical conductivity and dielectric properties of BaTi0.5(Fe0.33W0.17)O3 perovskite ceramic

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Abstract

Fe and W co-substituted BaTiO3 perovskite ceramics, compositional formula BaTi0.5(Fe0.33W0.17)O3, were synthesized by the standard solid-state reaction method and studied by X-ray diffraction, scanning electron microscopy and spectroscopy ellipsometry. The prepared sample remains as double phases with the perovskite structure. The structure refinement of BaTi0.5(Fe0.33W0.17)O 3 sample was performed in the cubic double and hexagonal setting of the \(\text {Fm}\boldsymbol {\bar {{3}}\mathrm {m}}\) and P6 3 /mmc space groups. Spectral dependence of optical parameters; real and imaginary parts of the dielectric function, refractive index, extinction coefficient and absorption coefficient were carried out in the range between 1.4 and 4.96 eV by using the ellipsometry experiments. Direct bandgap energy of 4.36 eV was found from the analysis of absorption coefficient vs. photon energy. In addition, the oscillator energy, dispersion energy and zero-frequency refractive index values were found from the analysis of the experimental data using Wemple–DiDomenico single-effective-oscillator model.

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Authors and Affiliations

  1. Laboratory of Condensed Matter and Nanosciences, Faculty of Sciences of Monastir, Monastir, 5019, Tunisia

    FAYÇAL BOURGUIBA & JEMAI DHAHRI

  2. Laboratoire de Physique Appliqué, Département de Physique, Faculté des Sciences de Sfax, 3018, Sfax, Tunisia

    AHMED DHAHRI & TAREK TAHRI

  3. Laboratoire de Science et Génie des Matériaux, Faculté de Génie Mécanique et Génie des Procédés, Université des Sciences et de la Technologie Houari Boumediene, BP32 El Alia, Bab Ezzouar, 16111, Algeria

    KAMEL TAIBI

  4. Institut Néel, CNRS-Université J. Fourier, B.P. 166, 38042, Grenoble, France

    E K HLIL

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  1. FAYÇAL BOURGUIBA
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Correspondence to FAYÇAL BOURGUIBA.

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BOURGUIBA, F., DHAHRI, A., TAHRI, T. et al. Structural, optical spectroscopy, optical conductivity and dielectric properties of BaTi0.5(Fe0.33W0.17)O3 perovskite ceramic. Bull Mater Sci 39, 1765–1774 (2016). https://doi.org/10.1007/s12034-016-1305-9

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  • DOI: https://doi.org/10.1007/s12034-016-1305-9

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