Abstract
A new organic-inorganic hybrid compound, H(C5N5H5)2(C5N5H6)2[Al(OH6)Mo6O18]·10H2O, has been synthesized and structurally characterized by single crystal X-ray diffraction, elemental analyses, IR, UV-Vis spectra and thermogravimetric analyses. This compound crystallized in the triclinic system, space group P-1, with a = 8.033(5) Å, b = 9.960(4) Å, c = 16.797(7) Å, α = 73.43(3)°, β = 87.85(1)°, γ = 81.47(1)° and Z = 1. The crystal structure can be described by infinite polyanions [Al(OH)6Mo6O18]3− organized in layers parallel to the c-direction alternating with organic cations associated in ribbons spreading along the b-direction. Multiple hydrogen bonds originating from amine, hydroxyl groups and water molecules connect different components of the lattice.
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Thabet, S., Ayed, B. & Haddad, A. A novel organic-inorganic hybrid based on Anderson-type polyoxometalate: H(C5N5H5)2(C5N5H6)2[Al(OH6)Mo6O18]·10H2O. Bull Mater Sci 37, 1503–1508 (2014). https://doi.org/10.1007/s12034-014-0103-5
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DOI: https://doi.org/10.1007/s12034-014-0103-5