Abstract
The manganese(II) carbonate, MnCO3·H2O, cobalt(II) carbonate, CoCO3·4H2O, zinc(II) carbonate, ZnCO3 and cadmium(II) carbonate, CdCO3, respectively, were synthesis by a new simple unusual route during the reaction of aqueous solutions of MnX2, CoX2, ZnX2 and CdX2, where (X = Br− and ClO −4 ) with urea at high temperature within ∼ 90°C for 6 h. The infrared spectra of the reaction products clearly indicate the absence of the bands of urea, but show the characteristic bands of ionic carbonate, CO 2−3 . A general mechanism describing the preparation of manganese(II), cobalt(II), zinc(II) and cadmium(II) carbonate compounds are discussed.
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Refat, M.S., Al-Qahtani, M.M. Unusual route for preparation of manganese(II), cobalt(II), zinc(II) and cadmium(II) carbonate compounds: synthesis and spectroscopic characterizations. Bull Mater Sci 34, 853 (2011). https://doi.org/10.1007/s12034-011-0205-2
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DOI: https://doi.org/10.1007/s12034-011-0205-2