Abstract
We report experimental results on the reaction temperature dependence of luminescence properties in size-controlled CdSe nanocrystals. Such reaction temperature dependent property is also sizedependent. The diameter of the CdSe nanocrystals is tuned from 4–11.0 nm by varying the reaction temperatures. The growth process and characterization of CdSe nanocrystals are determined by photoluminescence (PL) spectroscopy, ultraviolet-visible (UV-Vis) spectroscopy, X-ray photoelectron spectrometry (XPS), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). The influence of reaction conditions on the growth of CdSe nanocrystals demonstrates that low reaction temperature is favourable for the formation of high quality CdSe nanocrystals.
Similar content being viewed by others
References
Alivisatos A P, Gu W and Larabell 2005 Annu. Rev. Biomed. Eng. 7 55
Artemyev M V, Woggon U, Wannemacher R, Jaschinski H and Langbein W 2001 Nano. Lett. 1 309
Bruchez Jr M, Moronne M, Gin P, Weiss S and Alivisatos A P 1998 Science 281 2013
Kornowski A, Eichberger R, Giersig M, Weller H and Eychmuller 1996 J. Phys. Chem. 100 12467
Lee J, Sundar V C and Heine J R 2000 Adv. Mater. 12 1102
Manna L, Scher E C and Alivisatos A P 2000 J. Am. Chem. Soc. 122 12700
Maskaly G R, Petruska M A, Nanda J, Bezel I V, Schaller R D and Htoon H 2006 Adv. Mater. 18 343
Michalet X, Pinaud F F, Bentolila L A, Tsay J M, Doose S, Li J J, Wu A M, Gambhir S S and Weiss S 2005 Science 307 538
Murray C B, Norris D J and Bawendi M G 1993 J. Am. Chem. Soc. 115 8706
Peng X G 2002 Chem. Eur. J. 8 335
Peng Z A and Peng X G 2001 J. Am. Chem. Soc. 123 183
Qu L H, Peng Z A and Peng X G 2001 Nano. Lett. 1 333
Schlamp M C, Peng X G and Alivisatos A P 1997 J. Appl. Phys. 82 5837
Schaller R D, Sykora N, Pietryga J M and Klimov V I 2006 Nano. Lett. 6 424
Steigerwald M L and Brus L E 1990 Acc. Chem. Res. 23 183
Suri P and Mehra R M 2007 Sol. Ener. Mat. & Sol. C. 91 518
Wang F, Shan J, Islam M A, Herman I P, Bonn M and Heinz T F 2006 Nat. Mater. 5 861
Weller H 1993 Angew. Chem. Int. Ed. Engl. 32 41
Yu W W and Peng X G 2002 Angew. Chem. Int. Ed. 41 2368
Zhang H, Wang L P, Xiong H M, Hu L, Yang B and Li W 2003 Adv. Mater. 15 1712
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chen, S., Zhang, X., Zhao, Y. et al. Effects of reaction temperature on size and optical properties of CdSe nanocrystals. Bull Mater Sci 33, 547–552 (2010). https://doi.org/10.1007/s12034-010-0084-y
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-010-0084-y