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Preconcentrations of Zn(II) and Hg(II) in Environmental and Food Samples by SPE on B. licheniformis Loaded Amberlite XAD-4

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Abstract

In this work, the separations and preconcentrations of Zn(II) and Hg(II) ions on Bacillus lichenifoemis loaded onto Amberlite XAD-4 resin by solid-phase extraction has been performed. The biosorbent was characterized by using FT-IR, SEM, and EDX. pH, sample flow rate, eluent type and concentration, amount of B. licheniformis and XAD-4 resin, sample volume, and possible interfering ions effect were investigated in details as experimental variables in the SPE procedure. Limit of detection values for Zn(II) and Hg(II) were detected as 0.03 and 0.06 ng mL−1, respectively. 0.2–15 ng mL−1 linear range values were achieved for Zn(II) and Hg(II), respectively. Relative standard deviation values were found to be lower than 5%. For validation of the procedure, the certified standard reference materials (CWW-TM-D, EU-L-2, NCS ZC73O14, NCS ZC73350) were analyzed. The concentrations of Zn(II) and Hg(II) in water and food samples were measured by ICP-OES. Consequently, it can be inferred that the immobilized B. licheniformis microcolumn has ideal selectivity for Zn(II) and Hg(II) biosorption.

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Authors and Affiliations

  1. Food Processing Programme, Technical Science Vocational School, Mersin University, 33343, Mersin, Turkey

    Sadin Ozdemir

  2. Department of Chemistry and Chemical Processing Technologies, Vocational School of Technical Sciences, Dicle University, 21280, Diyarbakır, Turkey

    Ersin Kılınç

  3. Department of Medical Microbiology, Faculty of Medicine, Siirt University, 56100, Siirt, Turkey

    Ömer Acer

  4. Department of Chemistry, Faculty of Sciences, Erciyes University, 38030, Kayseri, Turkey

    Mustafa Soylak

  5. Technology Research & Application Center (TAUM), Erciyes University, 38039, Kayseri, Turkey

    Mustafa Soylak

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  1. Sadin Ozdemir
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  2. Ersin Kılınç
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Correspondence to Ömer Acer.

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Ozdemir, S., Kılınç, E., Acer, Ö. et al. Preconcentrations of Zn(II) and Hg(II) in Environmental and Food Samples by SPE on B. licheniformis Loaded Amberlite XAD-4. Biol Trace Elem Res 200, 1972–1980 (2022). https://doi.org/10.1007/s12011-021-03000-w

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