Abstract
In the present study, we address the combined response of iron (Fe) and nickel (Ni) metal powders on the microwave absorption properties of nanographite (NG) particles in the 8–18 GHz frequency band. NG was synthesized from graphite via high-energy planetary ball mill (wet milling). Similarly, hybrid Fe-Ni-NG particles in two individual (25:25:50 and 37.5:37.5:25) ratios were synthesized and characterized for studying their structural and morphological properties. Further, the samples were dispersed in epoxy-based aero-grade paints to analyze their particle size and rheological properties. Thus, produced nanocomposite paints were coated on aluminum sheets for analyzing their functional properties including impedance measurement and microwaves absorbency measurements. The hybrid nanoparticle coatings exhibited a reflection loss of − 21 dB for 25:25:50 (Fe-Ni-NG) sample at 18 GHz and nearly − 18 dB for 37.5:37.5:25 (Fe-Ni-NG) sample for a wider frequency range from 14 to 18 GHz with a coating thickness of 1.8 mm. These advanced nanoparticles can be used for the development of flexible coatings in various defense applications including stealth aircrafts and low observable technologies in the future.
Graphic abstract
Similar content being viewed by others
Data availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
Bhattacharyya, A, Joshi, M, “Functional Properties of Microwave-absorbent Nanocomposite Coatings Based on Thermoplastic Polyurethane-based and Hybrid Carbon-based Nanofillers.” Polym. Adv. Technol., 23 (6) 975–983. https://doi.org/10.1002/pat.2000 (2012)
Jamal, EMA, Mohanan, P, Joy, PA, Kurian, P, Anantharaman, MR, “Effect of Nickel Nanofillers on the Dielectric and Magnetic Properties of Composites Based on Rubber in the X-Band.” Appl. Phys. A, 97 (1) 157–165. https://doi.org/10.1007/s00339-009-5284-1 (2009)
Folgueras, LDC, Alves, MA, Rezende, MC, “Dielectric Properties of Microwave Absorbing Sheets Produced with Silicone and Polyaniline.” Mater. Res., 13 (2) 197–201. https://doi.org/10.1590/S1516-14392010000200013 (2010)
Das, S, Nayak, GC, Sahu, SK, Routray, PC, Roy, AK, Baskey, H, “Titania-Coated Magnetite and Ni-Ferrite Nanocomposite-Based RADAR Absorbing Materials for Camouflaging Application.” Polym. Plast. Technol. Eng., 54 (14) 1483–1493 (2015)
Zhang, M, Jiang, Z, Si, H, Zhang, X, Liu, C, Gong, C, Zhang, Y, Zhang, J, “Heterogeneous Iron–Nickel Compound/RGO Composites with Tunable Microwave Absorption Frequency and Ultralow Filler Loading.” Phys. Chem. Chem. Phys., 22 (16) 8639–8646. https://doi.org/10.1039/D0CP00290A (2020)
Zhong, B, Liu, W, Yu, Y, Xia, L, Zhang, J, Chai, Z, Wen, G, “Enhanced Microwave Absorption Properties of Graphite Nanoflakes by Coating Hexagonal Boron Nitride Nanocrystals.” Appl. Surf. Sci., 420 858–867. https://doi.org/10.1016/j.apsusc.2017.05.232 (2017)
Cui, X, Sun, S, Han, B, Yu, X, Ouyang, J, Zeng, S, Ou, J, “Mechanical, Thermal and Electromagnetic Properties of Nanographite Platelets Modified Cementitious Composites.” Compos. Part A: Appl. Sci. Manuf., 93 49–58. https://doi.org/10.1016/j.compositesa.2016.11.017 (2017)
Prakash, A, Narayanan, S, Thangavelu, K, Srivastava, AK, Pandey, MK, Nagarajan, R, Bhattacharyya, A, “Functional Properties of Zinc-Nanographite Based Nanocomposite Paints for 2–9 GHz Microwave Absorption.” J. Coat. Technol. Res. https://doi.org/10.1007/s11998-021-00484-y (2021)
Verma, M, Chauhan, SS, Dhawan, SK, Choudhary, V, “Graphene Nanoplatelets/Carbon Nanotubes/Polyurethane Composites as Efficient Shield Against Electromagnetic Polluting Radiations.” Compos. Part B: Eng., 120 118–127. https://doi.org/10.1016/j.compositesb.2017.03.068 (2017)
Liu, W, Tan, S, Yang, Z, Ji, G, “Hollow Graphite Spheres Embedded in Porous Amorphous Carbon Matrices as Lightweight and Low-Frequency Microwave Absorbing Material Through Modulating Dielectric Loss.” Carbon, 138 143–153. https://doi.org/10.1016/j.carbon.2018.06.009 (2018)
Liu, H, Wu, S, You, C, Tian, N, Li, Y, Chopra, N, “Recent Progress in Morphological Engineering of Carbon Materials for Electromagnetic Interference Shielding.” Carbon. https://doi.org/10.1016/j.carbon.2020.10.067 (2020)
Wu, N, Xu, D, Wang, Z, Wang, F, Liu, J, Liu, W, Shao, Q, Liu, H, Gao, Q, Guo, Z, “Achieving Superior Electromagnetic Wave Absorbers Through the Novel Metal-Organic Frameworks Derived Magnetic Porous Carbon Nanorods.” Carbon, 145 433–444. https://doi.org/10.1016/j.carbon.2019.01.028 (2019)
Jeddi, J, Katbab, AA, “The Electrical Conductivity and EMI Shielding Properties of Polyurethane Foam/Silicone Rubber/Carbon Black/Nanographite Hybrid Composites.” Polym. Compos., 39 (10) 3452–3460. https://doi.org/10.1002/pc.24363 (2018)
Bhattacharyya, A, Joshi, M, “Co-deposition of Iron and Nickel on Nanographite for Microwave Absorption Through Fluidized Bed Electrolysis.” Int. J. Nanosci., 10 (04no5) 1125–1130. https://doi.org/10.1142/S0219581X11009490 (2011)
Gunanto, YE, Izaak, MP, Sitompul, H, Adi, WA, April. “Reflection Loss Characteristic as Coating Thickness Function on the Microwave Absorbing Paint at a Frequency of 8-12 GHz.” In: IOP Conference Series: Materials Science and Engineering (Vol. 515, No. 1, p. 012074) (2019). IOP Publishing. https://doi.org/10.1088/1757-899X/515/1/012074
Chen, CY, Pu, NW, Liu, YM, Huang, SY, Wu, CH, Ger, MD, Gong, YJ, Chou, YC, “Remarkable Microwave Absorption Performance of Graphene at a Very Low Loading Ratio.” Compos. Part B: Eng., 1 (114) 395–403. https://doi.org/10.1016/j.compositesb.2017.02.016 (2017)
Nasir, A, Kausar, A, Younus, A, “Polymer/Graphite Nanocomposites: Physical Features, Fabrication and Current Relevance.” Polym. Plast. Technol. Eng., 54 (7) 750–770. https://doi.org/10.1080/03602559.2014.979503 (2015)
Tientong, J, Garcia, S, Thurber, CR, Golden, TD, “Synthesis of Nickel and Nickel Hydroxide Nanopowders by Simplified Chemical Reduction.” J. Nanotechnol.,. https://doi.org/10.1155/2014/193162 (2014)
Bhattacharyya, A, Joshi, M, “Synthesis of Hybrid Nanographite Particles Using Fluidized Bed System.” J. Solid State Electrochem., 15 (9) 1943–1952. https://doi.org/10.1007/s10008-010-1215-5 (2011)
Gogoi, JP, Bhattacharyya, NS, Bhattacharyya, S, “Single Layer Microwave Absorber Based on Expanded Graphite–Novolac Phenolic Resin Composite for X-Band Applications.” Compos. Part B: Eng., 58 518–523. https://doi.org/10.1016/j.compositesb.2013.10.078 (2014)
Khurram, AA, Rakha, SA, Zhou, P, Shafi, M, Munir, A, “Correlation of Electrical Conductivity, Dielectric Properties, Microwave Absorption, and Matrix Properties of Composites Filled with Graphene Nanoplatelets and Carbon Nanotubes.” J. Appl. Phys., 118 (4) 044105. https://doi.org/10.1063/1.4927617 (2015)
Lee, SE, Choi, O, Hahn, HT, “Microwave Properties of Graphite Nanoplatelet/Epoxy Composites.” J. Appl. Phys., 104 (3) 033705. https://doi.org/10.1063/1.2965195 (2008)
Wang, L, Guan, Y, Qiu, X, Zhu, H, Pan, S, Yu, M, Zhang, Q, “Efficient Ferrite/Co/Porous Carbon Microwave Absorbing Material Based on Ferrite@Metal–Organic Framework.” Chem. Eng. J., 326 945–955. https://doi.org/10.1016/j.cej.2017.06.006 (2017)
Hernandez-Gomez, P, Munoz, JM, Valente, MA, “Field-Induced Microwave Absorption in Ni Ferrite Nanoparticles.” IEEE Trans. Magn., 46 (2) 475–478. https://doi.org/10.1109/TMAG.2009.2033814 (2010)
Wu, H, Huang, X, Qian, L, “Recent Progress on the Metacomposites with Carbonaceous Fillers.” Eng. Sci., 2 (16) 17–25. https://doi.org/10.30919/es8d656 (2018)
Park, KY, Han, JH, Lee, SB, Kim, JB, Yi, JW, Lee, SK, “Fabrication and Electromagnetic Characteristics of Microwave Absorbers Containing Carbon Nanofibers and NiFe Particles.” Compos. Sci. Technol., 69 (7–8) 1271–1278. https://doi.org/10.1016/j.compscitech.2009.02.033 (2009)
Funding
Authors express their gratitude to the ER&IPR, DRDO, Govt. of India for the financial (ERIP/ER/1502251/M/01/1674) and PSG Institutions for their laboratory support.
Author information
Authors and Affiliations
Contributions
AP contributed to original manuscript preparation, structural characterization, editing. AKS contributed to microwave absorbency measurements, reviewing. MKP contributed to manuscript preparation, reviewing. RN contributed to impedance, rheology characterization and analysis. AB contributed to conceptualization, supervision, reviewing.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no known competing financial interests or personal relationships that could have appeared to influence the work reported here.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Prakash, A., Srivastava, A.K., Pandey, M.K. et al. Influence of iron and nickel on the microwave absorption and other functional properties of nanographite-based nanocomposite paints. J Coat Technol Res 18, 1691–1698 (2021). https://doi.org/10.1007/s11998-021-00531-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-021-00531-8