Skip to main content

Advertisement

Log in

Influence of iron and nickel on the microwave absorption and other functional properties of nanographite-based nanocomposite paints

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

In the present study, we address the combined response of iron (Fe) and nickel (Ni) metal powders on the microwave absorption properties of nanographite (NG) particles in the 8–18 GHz frequency band. NG was synthesized from graphite via high-energy planetary ball mill (wet milling). Similarly, hybrid Fe-Ni-NG particles in two individual (25:25:50 and 37.5:37.5:25) ratios were synthesized and characterized for studying their structural and morphological properties. Further, the samples were dispersed in epoxy-based aero-grade paints to analyze their particle size and rheological properties. Thus, produced nanocomposite paints were coated on aluminum sheets for analyzing their functional properties including impedance measurement and microwaves absorbency measurements. The hybrid nanoparticle coatings exhibited a reflection loss of − 21 dB for 25:25:50 (Fe-Ni-NG) sample at 18 GHz and nearly − 18 dB for 37.5:37.5:25 (Fe-Ni-NG) sample for a wider frequency range from 14 to 18 GHz with a coating thickness of 1.8 mm. These advanced nanoparticles can be used for the development of flexible coatings in various defense applications including stealth aircrafts and low observable technologies in the future.

Graphic abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Data availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

References

  1. Bhattacharyya, A, Joshi, M, “Functional Properties of Microwave-absorbent Nanocomposite Coatings Based on Thermoplastic Polyurethane-based and Hybrid Carbon-based Nanofillers.” Polym. Adv. Technol., 23 (6) 975–983. https://doi.org/10.1002/pat.2000 (2012)

    Article  CAS  Google Scholar 

  2. Jamal, EMA, Mohanan, P, Joy, PA, Kurian, P, Anantharaman, MR, “Effect of Nickel Nanofillers on the Dielectric and Magnetic Properties of Composites Based on Rubber in the X-Band.” Appl. Phys. A, 97 (1) 157–165. https://doi.org/10.1007/s00339-009-5284-1 (2009)

    Article  CAS  Google Scholar 

  3. Folgueras, LDC, Alves, MA, Rezende, MC, “Dielectric Properties of Microwave Absorbing Sheets Produced with Silicone and Polyaniline.” Mater. Res., 13 (2) 197–201. https://doi.org/10.1590/S1516-14392010000200013 (2010)

    Article  CAS  Google Scholar 

  4. Das, S, Nayak, GC, Sahu, SK, Routray, PC, Roy, AK, Baskey, H, “Titania-Coated Magnetite and Ni-Ferrite Nanocomposite-Based RADAR Absorbing Materials for Camouflaging Application.” Polym. Plast. Technol. Eng., 54 (14) 1483–1493 (2015)

    Article  CAS  Google Scholar 

  5. Zhang, M, Jiang, Z, Si, H, Zhang, X, Liu, C, Gong, C, Zhang, Y, Zhang, J, “Heterogeneous Iron–Nickel Compound/RGO Composites with Tunable Microwave Absorption Frequency and Ultralow Filler Loading.” Phys. Chem. Chem. Phys., 22 (16) 8639–8646. https://doi.org/10.1039/D0CP00290A (2020)

    Article  CAS  Google Scholar 

  6. Zhong, B, Liu, W, Yu, Y, Xia, L, Zhang, J, Chai, Z, Wen, G, “Enhanced Microwave Absorption Properties of Graphite Nanoflakes by Coating Hexagonal Boron Nitride Nanocrystals.” Appl. Surf. Sci., 420 858–867. https://doi.org/10.1016/j.apsusc.2017.05.232 (2017)

    Article  CAS  Google Scholar 

  7. Cui, X, Sun, S, Han, B, Yu, X, Ouyang, J, Zeng, S, Ou, J, “Mechanical, Thermal and Electromagnetic Properties of Nanographite Platelets Modified Cementitious Composites.” Compos. Part A: Appl. Sci. Manuf., 93 49–58. https://doi.org/10.1016/j.compositesa.2016.11.017 (2017)

    Article  CAS  Google Scholar 

  8. Prakash, A, Narayanan, S, Thangavelu, K, Srivastava, AK, Pandey, MK, Nagarajan, R, Bhattacharyya, A, “Functional Properties of Zinc-Nanographite Based Nanocomposite Paints for 2–9 GHz Microwave Absorption.” J. Coat. Technol. Res. https://doi.org/10.1007/s11998-021-00484-y (2021)

    Article  Google Scholar 

  9. Verma, M, Chauhan, SS, Dhawan, SK, Choudhary, V, “Graphene Nanoplatelets/Carbon Nanotubes/Polyurethane Composites as Efficient Shield Against Electromagnetic Polluting Radiations.” Compos. Part B: Eng., 120 118–127. https://doi.org/10.1016/j.compositesb.2017.03.068 (2017)

    Article  CAS  Google Scholar 

  10. Liu, W, Tan, S, Yang, Z, Ji, G, “Hollow Graphite Spheres Embedded in Porous Amorphous Carbon Matrices as Lightweight and Low-Frequency Microwave Absorbing Material Through Modulating Dielectric Loss.” Carbon, 138 143–153. https://doi.org/10.1016/j.carbon.2018.06.009 (2018)

    Article  CAS  Google Scholar 

  11. Liu, H, Wu, S, You, C, Tian, N, Li, Y, Chopra, N, “Recent Progress in Morphological Engineering of Carbon Materials for Electromagnetic Interference Shielding.” Carbonhttps://doi.org/10.1016/j.carbon.2020.10.067 (2020)

    Article  Google Scholar 

  12. Wu, N, Xu, D, Wang, Z, Wang, F, Liu, J, Liu, W, Shao, Q, Liu, H, Gao, Q, Guo, Z, “Achieving Superior Electromagnetic Wave Absorbers Through the Novel Metal-Organic Frameworks Derived Magnetic Porous Carbon Nanorods.” Carbon, 145 433–444. https://doi.org/10.1016/j.carbon.2019.01.028 (2019)

    Article  CAS  Google Scholar 

  13. Jeddi, J, Katbab, AA, “The Electrical Conductivity and EMI Shielding Properties of Polyurethane Foam/Silicone Rubber/Carbon Black/Nanographite Hybrid Composites.” Polym. Compos., 39 (10) 3452–3460. https://doi.org/10.1002/pc.24363 (2018)

    Article  CAS  Google Scholar 

  14. Bhattacharyya, A, Joshi, M, “Co-deposition of Iron and Nickel on Nanographite for Microwave Absorption Through Fluidized Bed Electrolysis.” Int. J. Nanosci., 10 (04no5) 1125–1130. https://doi.org/10.1142/S0219581X11009490 (2011)

    Article  CAS  Google Scholar 

  15. Gunanto, YE, Izaak, MP, Sitompul, H, Adi, WA, April. “Reflection Loss Characteristic as Coating Thickness Function on the Microwave Absorbing Paint at a Frequency of 8-12 GHz.” In: IOP Conference Series: Materials Science and Engineering (Vol. 515, No. 1, p. 012074) (2019). IOP Publishing. https://doi.org/10.1088/1757-899X/515/1/012074

  16. Chen, CY, Pu, NW, Liu, YM, Huang, SY, Wu, CH, Ger, MD, Gong, YJ, Chou, YC, “Remarkable Microwave Absorption Performance of Graphene at a Very Low Loading Ratio.” Compos. Part B: Eng., 1 (114) 395–403. https://doi.org/10.1016/j.compositesb.2017.02.016 (2017)

    Article  CAS  Google Scholar 

  17. Nasir, A, Kausar, A, Younus, A, “Polymer/Graphite Nanocomposites: Physical Features, Fabrication and Current Relevance.” Polym. Plast. Technol. Eng., 54 (7) 750–770. https://doi.org/10.1080/03602559.2014.979503 (2015)

    Article  CAS  Google Scholar 

  18. Tientong, J, Garcia, S, Thurber, CR, Golden, TD, “Synthesis of Nickel and Nickel Hydroxide Nanopowders by Simplified Chemical Reduction.” J. Nanotechnol.,. https://doi.org/10.1155/2014/193162 (2014)

    Article  Google Scholar 

  19. Bhattacharyya, A, Joshi, M, “Synthesis of Hybrid Nanographite Particles Using Fluidized Bed System.” J. Solid State Electrochem., 15 (9) 1943–1952. https://doi.org/10.1007/s10008-010-1215-5 (2011)

    Article  CAS  Google Scholar 

  20. Gogoi, JP, Bhattacharyya, NS, Bhattacharyya, S, “Single Layer Microwave Absorber Based on Expanded Graphite–Novolac Phenolic Resin Composite for X-Band Applications.” Compos. Part B: Eng., 58 518–523. https://doi.org/10.1016/j.compositesb.2013.10.078 (2014)

    Article  CAS  Google Scholar 

  21. Khurram, AA, Rakha, SA, Zhou, P, Shafi, M, Munir, A, “Correlation of Electrical Conductivity, Dielectric Properties, Microwave Absorption, and Matrix Properties of Composites Filled with Graphene Nanoplatelets and Carbon Nanotubes.” J. Appl. Phys., 118 (4) 044105. https://doi.org/10.1063/1.4927617 (2015)

    Article  CAS  Google Scholar 

  22. Lee, SE, Choi, O, Hahn, HT, “Microwave Properties of Graphite Nanoplatelet/Epoxy Composites.” J. Appl. Phys., 104 (3) 033705. https://doi.org/10.1063/1.2965195 (2008)

    Article  CAS  Google Scholar 

  23. Wang, L, Guan, Y, Qiu, X, Zhu, H, Pan, S, Yu, M, Zhang, Q, “Efficient Ferrite/Co/Porous Carbon Microwave Absorbing Material Based on Ferrite@Metal–Organic Framework.” Chem. Eng. J., 326 945–955. https://doi.org/10.1016/j.cej.2017.06.006 (2017)

    Article  CAS  Google Scholar 

  24. Hernandez-Gomez, P, Munoz, JM, Valente, MA, “Field-Induced Microwave Absorption in Ni Ferrite Nanoparticles.” IEEE Trans. Magn., 46 (2) 475–478. https://doi.org/10.1109/TMAG.2009.2033814 (2010)

    Article  CAS  Google Scholar 

  25. Wu, H, Huang, X, Qian, L, “Recent Progress on the Metacomposites with Carbonaceous Fillers.” Eng. Sci., 2 (16) 17–25. https://doi.org/10.30919/es8d656 (2018)

    Article  Google Scholar 

  26. Park, KY, Han, JH, Lee, SB, Kim, JB, Yi, JW, Lee, SK, “Fabrication and Electromagnetic Characteristics of Microwave Absorbers Containing Carbon Nanofibers and NiFe Particles.” Compos. Sci. Technol., 69 (7–8) 1271–1278. https://doi.org/10.1016/j.compscitech.2009.02.033 (2009)

    Article  CAS  Google Scholar 

Download references

Funding

Authors express their gratitude to the ER&IPR, DRDO, Govt. of India for the financial (ERIP/ER/1502251/M/01/1674) and PSG Institutions for their laboratory support.

Author information

Authors and Affiliations

Authors

Contributions

AP contributed to original manuscript preparation, structural characterization, editing. AKS contributed to microwave absorbency measurements, reviewing. MKP contributed to manuscript preparation, reviewing. RN contributed to impedance, rheology characterization and analysis. AB contributed to conceptualization, supervision, reviewing.

Corresponding author

Correspondence to Amitava Bhattacharyya.

Ethics declarations

Conflict of interest

The authors declare no known competing financial interests or personal relationships that could have appeared to influence the work reported here.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Prakash, A., Srivastava, A.K., Pandey, M.K. et al. Influence of iron and nickel on the microwave absorption and other functional properties of nanographite-based nanocomposite paints. J Coat Technol Res 18, 1691–1698 (2021). https://doi.org/10.1007/s11998-021-00531-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-021-00531-8

Keywords

Navigation