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Air Quality, Atmosphere & Health

, Volume 11, Issue 5, pp 521–534 | Cite as

Impact of mixed anthropogenic and natural emissions on air quality and eco-environment—the major water-soluble components in aerosols from northwest to offshore isle

  • Yilun Jiang
  • Guoshun Zhuang
  • Qiongzhen Wang
  • Kan Huang
  • Congrui Deng
  • Guangyuan Yu
  • Chang Xu
  • Qingyan Fu
  • Yanfen Lin
  • Joshua S. Fu
  • Mei Li
  • Zhen Zhou
Article

Abstract

Based on more than 300 atmospheric TSP and PM2.5 samples collected at five sites over China in 2007 and 2008, characteristics, sources, and interactions of the major water-soluble species were investigated for a better understanding of their role in urban air quality and offshore eco-environment. From the dust source regions in Northwestern China to an offshore isle over the East China Sea, concentration levels and fine/coarse particle distributions of five representative water-soluble components were well elucidated, reflecting the distinct differences of geo-history, location, and present economic situation among the target areas. NO3/SO42− mass ratios reflected significant divergence of motorization among the studied regions. Specifically, a case study during the World Car-Free Day proved that traffic restriction measures could indeed help mitigate the aerosol species formed from vehicle emissions. Investigation on the molar concentration stoichiometry and mass percentage variations of particulate NO3, SO42−, and NH4+ revealed that NH3 was a driving factor in the formation of major secondary water-soluble ions in atmospheric fine particles over urban areas. Based on the prevailing wind analysis, observation over an offshore isle clearly indicated the influence of the relative strength of anthropogenic sources and ocean-related natural sources on the formation and size distribution of MSA (methanesulfonic acid), a major water-soluble organic component in aerosol. Annual dry deposition flux of particulate NO3 and NH4+ over the East China Sea was estimated based on the strength of an improved calculation formula. Reductive nitrogen was found to be the major form of the deposited atmospheric inorganic nitrogen, accounting for ~ 69% of the total nitrogen depositions.

Keywords

Water-soluble component Mobile sources Ammonia/ammonium East China Sea Methanesulfonic acid Dry deposition flux 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 41429501 (fund for collaboration with overseas scholars), 91644105, and 41405115). Y.L.J., M.L., and Z.Z. would like to acknowledge the National Natural Science Foundation of China (21607056) and Natural Fund of Guangdong Province (2015A030313339). C.X. is sponsored by the Natural Science Foundation of Shanghai (15ZR1434900).

Author contributions

Y.J., K.H., and C.D. conceived the study. Y.J., K.H., G.Z., and G.Y. conducted the data analysis and wrote the paper. All authors contributed to interpreting the results and writing the manuscript.

Compliance with ethical standards

Conflict of interest

The authors declare they have no conflict of interest.

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  • Yilun Jiang
    • 1
    • 2
    • 3
  • Guoshun Zhuang
    • 1
  • Qiongzhen Wang
    • 1
    • 4
  • Kan Huang
    • 1
    • 5
    • 6
  • Congrui Deng
    • 1
    • 4
  • Guangyuan Yu
    • 1
  • Chang Xu
    • 1
    • 7
  • Qingyan Fu
    • 8
  • Yanfen Lin
    • 8
  • Joshua S. Fu
    • 9
  • Mei Li
    • 2
  • Zhen Zhou
    • 2
  1. 1.Center for Atmospheric Chemistry Study, Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and EngineeringFudan UniversityShanghaiChina
  2. 2.Institute of Mass Spectrometer and Atmospheric EnvironmentJinan UniversityGuangzhouChina
  3. 3.Baosteel Environmental Monitoring CenterShanghaiChina
  4. 4.Environmental Science Research and Design Institute of Zhejiang ProvinceHangzhouChina
  5. 5.Institue of Atmospheric SciencesFudan UniversityShanghaiChina
  6. 6.Shanghai Institute of Eco-Chongming (SIEC)ShanghaiChina
  7. 7.Shanghai Academy of Environmental SciencesShanghaiChina
  8. 8.Shanghai Environmental Monitoring CenterShanghaiChina
  9. 9.Department of Civil and Environmental EngineeringThe University of TennesseeKnoxvilleUSA

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