Abstract
Silver nanoplates were synthesized in aqueous solution by photoinduced chemical reduction method with tungsten lamp as light source. The growth process was analyzed and characterized. The linear absorption spectra showed that, along with the growth process, the surface plasmon resonance of silver seed nanoparticles at 395 nm decreased gradually, while a new plasmon band at 740 nm corresponding to silver nanoplates appeared and increased gradually. Z-scan technique was used to explore the nonlinear optical properties of silver nanoplates. The results displayed that with the reaction time increases from 0 h to 24 h, the value of nonlinear absorption (NLA) coefficient and the value of nonlinear refraction (NLR) index of the products increased from 0 to 3.167 cm/GW and from 0.64×10−4 to 6.83×10−4 cm2/GW, respectively.
Similar content being viewed by others
References
Lal S, Link S, Halas N J. Nano-optics from sensing to waveguiding [J]. Nature Photonics, 2007, 1: 641–648.
Eustis S, El-Sayed M A. Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shaps [J]. Chemical Society Reviews, 2006, 35: 209–217.
Liu Fuken, Chang Yucheng, Ko F H, et al. Microwave rapid heating for the synthesis of gold nanorods [J]. Materials Letters, 2004, 58(3–4): 373–377.
Xiong Yujie, Washio Isao, Chen Jingyi, et al. Poly(vinyl pyrrolidone): A dual functional reductant and stabilizer for the facile synthesis of noble metal nanoplates in aqueous solutions [J]. Langmuir, 2006, 22: 8563–8570.
Capek I. Preparation of metal nanoparticles in water-in-oil (W/O) microemulsions [J]. Advances in Cllloid and Interface Science, 2004, 110(1–2): 49–74.
Lim B, Camargo P H C, Xia Younan. Mechanistic study of the synthesis of Au nanotadpoles, nanokites, and microplates by reducing aqueous HAuCl4 with poly (vinyl pyrrolidone) [J]. Langmuir, 2008, 24: 10437–10442.
Daniel M C, AStruc D. Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J]. Chem Rev, 2004, 104(1): 293–346.
Ah C S, Yun Y J, Park H J, et al. Size-controlled synthesis of machinable single crystalline gold nanoplates [J]. Chemistry Letters, 2005, 17: 5558–5561.
Burda C, Chen Xiaobo, Narayanan R, et al. Chemistry and properties of nanocrystals of different shapes [J]. Chem Rev, 2005, 105: 1025–1102.
Hu Jianqiang, Chen Qing, Xie Zhaoxiong, et al. A simple and effective route for the synthesis of crystalline silver nanorods and nanowires [J]. Adv Funct Mater, 2004, 14(2): 183–189.
Li Yat, Qian Fang, Xiang Jie, et al. Nanowires electronic and optoelectronic devices [J]. Materials today, 2006, 9(10): 18–27.
Haes A J, Chang Lei, Klein W L, et al. Detection of a biomarker for alzheimer’s disease from synthetic and clinical samples using a nanoscale optical biosensor [J]. J Am Chem Soc, 2005, 127: 2264–2271.
Haes A J, Van Duyne R P. A nanoscale optical biosensor: sensitivity and selectivity of an approach based on the localized surface plasmon resonance spectroscopy of triangular silver nanoparticles [J]. J Am Chem Soc, 2002, 124: 10596–10604.
Zhou Min, Chen shenhao, Zhao Shiyong, et al. Preparation of gold nanoplates by an electrochemical method [J]. Chemistry Letters, 2005, 34(12): 1670–1671.
Garnett E C, Cai W S, Cha J J, et al. Self-limited plasmonic welding of silver nanowire junctions [J]. Nature Materials, 2012, 11: 241–149.
Li Xiaoling, Zhang Junhu, Xu Weiqing, et al. Mercaptoacetic acid-capped silver nanoparticles colloid: Formation, morphology, and SERS activity [J]. Langmuir, 2003, 19: 4285–4290.
Ajayan P M, Lijima S. Capillarity-induced filling of carbon nanotubes [J]. Nature, 1993, 361: 333–334.
Han yongjin, Kim Jiman, Stucky G D. Preparation of noble metal nanowires using hexagonal mesoporous silica SBA-15 [J]. Chem Mater, 2000, 12: 2068–2069.
Jakab A, Rosman C, Khalavka Y, et al. Highly sensitive plasmonic silver nanorods [J]. ACS Nano, 2011, 5(9): 6880–6885.
Jin Rongchao, Cao Yunwei, Mirkin C A, et al. Photoinduced conversion of silver nanospheres to nanoprisms [J]. Science, 2001, 294: 1901–0904.
Shiraishi Y, Toshima N. Oxidation of ethylene catalyzed by colloidal dispersions of poly(sodium acrylate)-protected silver nanoclusters [J]. Colloids and Surf A, 2000, 169: 59–66
Sun Tao, Seff K. Silver clusters and chemistry in zeolites [J]. Chem Rev, 1994, 94(4): 857–870.
Sun Yugang, Wiederrecht Gary P. Surfactantless synthesis of silver nanoplates and their application in SERS [J]. Small, 2007, 3(11): 1964–1975.
Xie Yingwei, Ye Ruqiang, Liu Honglai, et al. Synthesis of silver nanoparticles in reverse micelles stabilized by natural biosurfactant [J]. Colloids and Surf A, 2006, 279(1–3): 175–178.
Liu Xiaolan, Peng Xiaoniu, Yang Zhongjian, et al. Linear and nonlinear optical properties of micrometer-scale gold nanoplates [J]. Chinese Physics Letters, 2011, 28(5): 057805.
Anger P, Bharadwaj P, Novotny L. Enhancement and quenching of single-molecule fluorescence [J]. Phys Rev Lett, 2006, 96(113002): 1–4.
Wang Ququan, Han Junbo, Guo Donglai, et al. Highly efficient avalanche multiphoton luminescence from coupled Au nanowires in the visible region [J]. Nano Lett, 2007, 7(3): 723–728.
Wang Yuehui, Zhou Xinran, Wang Ting, et al. Enhanced luminescence from lanthanide complex by silver nanoparticles [J]. Materials Letters, 2008, 62(20): 3582–3584.
Jiang X C, Yu A B. Silver Nanoplates: A highly sensitive material toward inorganic anions [J]. Langmuir, 2008, 24: 4300–4309.
Homan K A, Souza M, Truby R, et al. Silver nanoplate contrast agents for in vivo molecular photoacoustic imaging [J]. ACS Nano, 6(1): 641–650.
Li Min, Zhang Zongsuo, Yu Xuefeng, et al. Optical properties of Au/Ag core/shell nanoshuttles [J]. Opt Express, 2008, 16(18): 14288–14293.
Zhou Li, Yu Xuefeng, Fu Xiaofeng, et al. Surface plasmon resonance and field enhancement of Au/Ag alloyed hollow nanoshells [J]. Chin Phys Lett, 2008, 25(5): 1776–1779.
Wang Kai, Long Hua, Lu Peixiang, et al. Size-related third-order optical nonlinearities of Au nanoparticles arrays [J]. Opt Express, 2010, 18(13): 13874–13879.
Wang Ququan, Han Junbo, Gong Hongmei, et al. Linear and nonlinear optical properties of Ag nanowire polarizing glass [J]. Adv Funct Mater, 2006, 16: 2405–2408.
Sheik-Bahae M, Said A A, Wei T H, et al. Sensitive measurement of optical nonlinear using a single beam [J]. IEEE Journal of Quantum Electronics, 1990, 26(5): 760–769.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Supported by the National Natural Science Foundation of China (11174229)
Biography: WANG Xiaofang, female, Master candidate, research direction: nonlinear optics.
Rights and permissions
About this article
Cite this article
Wang, X., Nan, F., Liang, S. et al. Optical properties of silver nanoplates synthesized by photoinduced method. Wuhan Univ. J. Nat. Sci. 18, 201–206 (2013). https://doi.org/10.1007/s11859-013-0915-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11859-013-0915-y
Key words
- photoinduced chemical reduction method
- silver nanoplates
- surface plasmon
- nonlinear absorption
- nonlinear refraction