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Detoxification and Extraction of Solid and Hazardous Wastes for the Preparation of Molecular Sieves

  • Recycling End of Life Products Containing Aluminium
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Abstract

The discharge of industrial solid/hazardous wastes (such as aluminum dross, spent cathode carbon blocks, coal gangue, and carbide slag) causes potential environmental problems and wastes resources. An innovative method for preparing molecular sieves using varied solid/hazardous wastes is proposed. Aluminum dross is deeply denitrified to extract alumina source under a high concentration of sodium hydroxide. Denitrified aluminum dross, desilicated coal gangue, spent cathode carbon blocks, and carbide slag are synergistically reacted at high temperature to further extract alumina source. Alumina and silica sources are obtained via desilication of coal gangue which is used as raw materials to synthesize molecular sieve materials. The results show that the reaction rate of aluminum nitride in aluminum dross after leaching with high-concentration alkali solution reaches more than 99%, while the extraction rate of alumina reaches 40% (the extraction rate of alkali-soluble alumina is almost 100%). The highest sodium oxide recovery rate for various solid/hazardous wastes is 96.23%, and the alumina extraction rate is 95.2%. The molecular sieve prepared from silica and alumina sources has good crystallinity with an average particle size of 4.46 μm, a whiteness of 94.9, and a calcium exchange capacity of 310 mg/g.

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References

  1. M.Z. Xie, H.L. Zhao, Z.G. Wu, W. Liu, R.B. Li, and F.Q. Liu, J. Sustain. Metall. 6, 715 https://doi.org/10.1007/s40831-020-00311-5 (2020).

    Article  Google Scholar 

  2. H. Lv, H.L. Zhao, Z.P. Zuo, R.B. Li, and F.Q. Liu, J. Mater. Res. Technol. 9, 9735 https://doi.org/10.1016/j.jmrt.2020.06.051 (2020).

    Article  Google Scholar 

  3. L. Chao, J.H. Wan, H.H. Sun, and L.T. Li, J. Hazard. Mater. 179, 515 https://doi.org/10.1016/j.jhazmat.2010.03.033 (2010).

    Article  Google Scholar 

  4. Y.J. Wang, B.F. Ye, Z.C. Hong, Y.H. Wang, and M.H. Liu, J. Clean. Prod. 253, 119930 https://doi.org/10.1016/j.jclepro.2019.119930 (2020).

    Article  Google Scholar 

  5. M. Mahinroosta, and A. Allahverdi, J. Environ. Manage. 223, 452 https://doi.org/10.1016/j.jenvman.2018.06.068 (2018).

    Article  Google Scholar 

  6. B.R. Das, B. Dash, B.C. Tripathy, I.N. Bhattacharya, and S.C. Das, Miner. Eng. 20, 252 https://doi.org/10.1016/j.mineng.2006.09.002 (2007).

    Article  Google Scholar 

  7. A. Meshram, and K.K. Singh, Resour. Conserv. Recycl. 130, 95108 https://doi.org/10.1016/j.resconrec.2017.11.026 (2018).

    Article  Google Scholar 

  8. Y.X. Guo, H.B. Lv, X. Yang, and F.Q. Cheng, Sep. Purif. Technol. 151, 177 https://doi.org/10.1016/j.seppur.2015.07.043 (2015).

    Article  Google Scholar 

  9. Y.X. Guo, K.Z. Yan, L. Cui, F.Q. Cheng, and H.H. Lou, Int. J. Miner. Process. 131, 51 https://doi.org/10.1016/j.minpro.2014.07.001 (2014).

    Article  Google Scholar 

  10. Y.X. Guo, K.Z. Yan, L. Cui, and F.Q. Cheng, Powder Technol. 302, 33 https://doi.org/10.1016/j.powtec.2016.08.034 (2016).

    Article  Google Scholar 

  11. Y.X. Guo, Q. Zhao, K.Z. Yan, F.Q. Cheng, and H.H. Lou, Ind. Eng. Chem. Res. 53, 4518 https://doi.org/10.1021/ie500295t (2014).

    Article  Google Scholar 

  12. X.J. Ren, J.P. Xia, and Z.S. Zhang, NonMet. Mines 35, 12 (2012).

    Google Scholar 

  13. X.L. Wang, and Y. Zhang, Sci. Adv. Mater. 11, 277 https://doi.org/10.1166/sam.2019.3468 (2019).

    Article  Google Scholar 

  14. J. Xiao, F.C. Li, Q.F. Zhong, H.G. Bao, B.J. Wang, J.D. Huang, and Y.B. Zhang, Hydrometallurgy 155, 118 https://doi.org/10.1016/j.hydromet.2015.04.018 (2015).

    Article  Google Scholar 

  15. J.M. Zhu, H.W. Cai, and N.N. Dang, Adv. Mat. Res. 997, 614 https://doi.org/10.4028/www.scientific.net/AMR.997.614 (2014).

    Article  Google Scholar 

  16. Y.Y. Teng, Y.F. Zhang, J. Bai, J.M. Shun, and L.X. Yang, Chem. Ind. Eng. Prog. 30, 456 https://doi.org/10.16085/j.issn.1000-6613.2011.02.003 (2011).

    Article  Google Scholar 

  17. Q.L. Ge, M. Moeen, Q. Tian, J.J. Xu, and K.Q. Feng, Sci. Pollut. Res. 27, 7398 https://doi.org/10.1007/s11356-019-07412-z (2020).

    Article  Google Scholar 

  18. F.Q. Liu, M.Z. Xie, G.Q. Yu, C.Y. Ke, and H.L. Zhao, ACS Sustain. Chem. Eng. 9, 10318 https://doi.org/10.1021/ACSSUSCHEMENG.1C03276 (2021).

    Article  Google Scholar 

  19. M.Z. Xie, F.Q. Liu, H.L. Zhao, C.Y. Ke, and Z.Q. Xu, J. Mater. Res. Technol. 14, 2281 https://doi.org/10.1016/J.JMRT.2021.07.129 (2021).

    Article  Google Scholar 

  20. M.Z. Xie, R.B. Li, H.L. Zhao, W. Liu, T.T. Lu, and F.Q. Liu, J. Clean. Prod. 249, 119370 https://doi.org/10.1016/j.jclepro.2019.119370 (2020).

    Article  Google Scholar 

  21. N. Li, L. Gao, K. Chattopadhyay. Migration behavior of fluorides in spent potlining during vacuum distillation method. Light Met. 2019, Part of the The Minerals, Metals & Materials Series book series (MMMS), Pittsburgh, pp 867–872.

  22. G. Hollywell, and R. Breault, JOM 65, 1441 https://doi.org/10.1007/s11837-013-0769-y (2013).

    Article  Google Scholar 

  23. X.D. Zhao, G.M. Xiang, C.Y. Ma, and C.H. Chen, Chem. Eng. 34, 59 https://doi.org/10.1016/S1872-2040(06)60041-8 (2006).

    Article  Google Scholar 

  24. X. Xin, Y.J. Li, W.J. Wang, and L. Shi, Appl. Energy 135, 391 https://doi.org/10.1016/j.apenergy.2014.08.098 (2014).

    Article  Google Scholar 

  25. Y.J. Li, H.L. Liu, R.Y. Sun, S.M. Wu, and C.M. Lu, J. Therm. Anal. Calorim. 110, 685 https://doi.org/10.1007/s10973-011-1901-2 (2012).

    Article  Google Scholar 

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Acknowledgements

This study was supported by the National Key Research and Development Program of China (2022YFC2904401).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, 100083, China

    Mingzhuang Xie, Fengqin Liu & Hongliang Zhao

  2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing, 100083, China

    Mingzhuang Xie, Fengqin Liu & Hongliang Zhao

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  1. Mingzhuang Xie
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  2. Fengqin Liu
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Correspondence to Fengqin Liu or Hongliang Zhao.

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Xie, M., Liu, F. & Zhao, H. Detoxification and Extraction of Solid and Hazardous Wastes for the Preparation of Molecular Sieves. JOM 75, 4680–4688 (2023). https://doi.org/10.1007/s11837-023-06071-3

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