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Effects of Process Gas Pressure and Type on Oxygen Content in Sintered Titanium Produced using Jet-Milled Titanium Hydride Powders

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Abstract

Titanium hydride powders are increasingly being used to produce titanium components via powder metallurgy processes due to their improvements in densification over titanium metal powders. Since the oxygen content plays a significant role in the mechanical properties of titanium alloys, understanding how powder preparation techniques, such as milling, affect the final oxygen content is key. In this work, titanium hydride powders were milled through jet milling using air, nitrogen, and argon gas at various processing pressures. The oxygen content in the sintered powders is shown to be mostly dependent on the specific surface area, which is mainly affected by the grinding pressure. The type of gas used was also found to have an effect on the oxygen content, but the dependence was small.

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References

  1. O.M. Ivasishin, D.G. Savvakin, M.M. Gumenyak, and O.B. Bondarchuk, Key Eng. Mater. 520, 121 (2012).

    Article  Google Scholar 

  2. Y. Zhang, Z.Z. Fang, L. Xu, P. Sun, B. Van Devener, S. Zheng, Y. Xia, P. Li, and Y. Zhang, J. Phys. Chem. C 122, 20691 (2018).

    Article  Google Scholar 

  3. X.L. Han, Q. Wang, D.L. Sun, and H.X. Zhang, Scr. Mater. 56, 77 (2007).

    Article  Google Scholar 

  4. O.M. Ivasishin, D.G. Savvakin, I.S. Bielov, V.S. Moxson, V.A. Duz, R. Davies, and C. Lavender, Mater. Sci. Technol. 151 (2005).

  5. J. Greenspan, F.J. Rizzitano, and E. Scala, in Proceedings of the Second International Conference on Titanium Science Technology (1973), pp. 365–379.

  6. J. Greenspan, F.J. Rizzitano, and E. Scala, Metal matrix composites by decomposition sintering of titanium hydride. Army Materials and Mechanics Research Center Technical Report 70-33 (1970).

  7. O.M. Ivasishin, D. Eylon, V.I. Bondarchuk, and D.G. Savvakin, Defect Diffus. Forum 277, 177 (2008).

    Article  Google Scholar 

  8. P. Sun, Z.Z. Fang, and M. Koopman, Adv. Eng. Mater. 15, 1007 (2013).

    Google Scholar 

  9. P. Sun, Z.Z. Fang, M. Koopman, Y. Xia, J. Paramore, K.S.R. Chandran, Y. Ren, and J. Lu, Metall. Mater. Trans. A 46, 5546 (2015).

    Article  Google Scholar 

  10. P. Sun, Z.Z. Fang, M. Koopman, J. Paramore, and K.S.R. Chandran, Acta Mater. 84, 29 (2015).

    Article  Google Scholar 

  11. J.D. Paramore, Z.Z. Fang, P. Sun, M. Koopman, K.S.R. Chandran, and M. Dunstan, Scr. Mater. 107, 103 (2015).

    Article  Google Scholar 

  12. J.D. Paramore, Z.Z. Fang, M. Dunstan, P. Sun, and B.G. Butler, Sci. Rep. 7, 41444 (2017).

    Article  Google Scholar 

  13. G. Lutjering and J.C. Williams, Titanium, 2nd ed. (Berlin: Springer, 2007).

    Google Scholar 

  14. E. Baril, L.P. Lefebvre, and Y. Thomas, Powder Metall. 54, 183 (2011).

    Article  Google Scholar 

  15. C.G. McCracken, C. Motchenbacher, and D.P. Barbis, Int. J. Powder Metall. 46, 19 (2010).

    Google Scholar 

  16. C.G. McCracken, D.P. Barbis, and R.C. Deeter, Powder Metall. 54, 180 (2011).

    Article  Google Scholar 

  17. I.I. Ivanova, N.A. Krylova, O.M. Demydyk, V.A. Barabash, and M.V. Karpets, Powder Metall. Met. Ceram. 58, 13 (2019).

    Article  Google Scholar 

  18. S.L.G. Petroni, V.A.R. Henriques, M.S.M. Paula, and C.A.A. Cairo, Mater. Sci. Forum 727–728, 374 (2012).

    Article  Google Scholar 

  19. S.L.G. Petroni, M.S.M. Paula, and V.A.R. Henriques, Powder Metall. 56, 202 (2013).

    Article  Google Scholar 

  20. T.M. Motsai, S. Chikosha, C. Machio, and M.E. Makhatha, in IOP Conference Series: Materials Science and Engineering, vol 430 (2018).

  21. L.R. de Andrade, E.T. Galvani, V.A.R. Henriques, and S.L.G. Petroni, in SAE Technical Paper 2012-36-02 (2012).

  22. D. Eskin, S. Voropayev, and O. Vasilkov, Powder Technol. 105, 257 (1999).

    Article  Google Scholar 

  23. H.-G. Zander, H. Bornfeld, and B.-M. Holle, US Patent 4,917,309 (1990).

  24. ASTM E1409-13, Standard Test Method for Determination of Oxygen and Nitrogen in Titanium and Titanium Alloys by Inert Gas Fusion (West Conshohocken, PA: ASTM International, 2013). https://doi.org/10.1520/E1409-13.

  25. X. Suo, S. Yin, M.P. Planche, T. Liu, and H. Liao, Surf. Coat. Technol. 268, 90 (2015).

    Article  Google Scholar 

  26. E.W. Lemmon, M.O. McLinden, and D.G. Friend, in NIST Chemistry WebBook, NIST Standard Reference Database Number 69, ed. by P.J. Linstrom, W.G. Mallard (National Institute of Standards and Technology, Gaithersburg MD, 2016).

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Acknowledgement

The authors acknowledge Funding support by the US Department of Energy (US DOE), Innovative Manufacturing Initiative (DEEE0005761), through the Advanced Manufacturing Office and the Office of Energy Efficiency and Renewable Energy.

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Correspondence to Z. Zak Fang.

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Dr. Pei Sun, Dr. Mark Koopman, and Dr. Z. Zak Fang are listed as inventors on the HSPT process patent (US patent no. 9816157B2).

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Dunstan, M.K., Simpson, B., Sun, P. et al. Effects of Process Gas Pressure and Type on Oxygen Content in Sintered Titanium Produced using Jet-Milled Titanium Hydride Powders. JOM 72, 1286–1291 (2020). https://doi.org/10.1007/s11837-020-04010-0

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  • DOI: https://doi.org/10.1007/s11837-020-04010-0

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