Skip to main content
Log in

Phase diagrams of advanced magnesium alloys containing Al, Ca, Sn, Sr, and Mn

  • Magnesium: Phase Diagrams and Thermodynamics/Overview
  • Published:
JOM Aims and scope Submit manuscript

Abstract

In this paper an overview of the most relevant phase diagrams is given comprising the unconventional alloying elements Sn, Ca, and Sr, in reasonable combinations with Al and Mn in Mg alloys as a basis for advanced applications. The focus is on magnesium-rich partial projections of the liquidus surface of five ternary systems, relevant to technological applications for lightweight materials. All phase diagrams are calculated from a coherent thermodynamic multicomponent database for magnesium alloys. These calculations are validated by key samples in the pertinent subsystems, including extensive ternary assessments and also quaternary work. Isothermal sections of magnesium-rich phase diagrams of alloys with constant aluminum and manganese content at 500°C and 550°C are given for the two five-component systems: Mg-Al-Mn-Ca-Sr and Mg-Al-Mn-Ca-Sn.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H.L. Lukas, S.G. Fries, and B. Sundman, Computational Thermodynamics: The Calphad Method (Cambridge, U.K.: Cambridge University Press, 2007).

    MATH  Google Scholar 

  2. R. Schmid-Fetzer and J. Gröbner, Adv. Eng. Mat., 3 (2001), pp. 947–961.

    Article  CAS  Google Scholar 

  3. R. Schmid-Fetzer et al., Magnesium Technology 2007, ed. R. Beals, M. Pekguleryuz, and N. Neelameggham (Warrendale, PA: TMS, 2007), pp. 339–344.

    Google Scholar 

  4. R. Schmid-Fetzer et al., Adv. Eng. Mat., 7 (2005), pp. 1142–1149.

    Article  CAS  Google Scholar 

  5. B.L. Mordike and T. Ebert, Mater. Sci. Eng., A 302 (2001), pp. 37–45.

    CAS  Google Scholar 

  6. H. Dieringa et al., Magnesium Technology 2007, ed. R. Beals, M. Pekguleryuz, and N. Neelameggham (Warrendale, PA: TMS, 2007), pp. 3–8.

    Google Scholar 

  7. K.U. Kainer, editor, Magnesium: Proc. 7th Internat. Conference on Magnesium Alloys and their Applications (Weinheim, Germany: Wiley-VCH Verlag, 2007).

    Google Scholar 

  8. A.A. Luo, International Materials Reviews, 49 (2004), pp. 13–30.

    Article  CAS  Google Scholar 

  9. M.O. Pekguleryuz and E. Baril, Mat. Trans., 42(7) (2001), pp. 1258–1267.

    Article  CAS  Google Scholar 

  10. E. Baril, P. Labelle, and M.O. Pekguleryuz, JOM, 55 (11) (2003), pp. 34–39.

    Article  CAS  Google Scholar 

  11. E.F. Emley, Principles of Magnesium Technology (Oxford: Pergamon Press, 1966).

    Google Scholar 

  12. H. Liu et al., Mat. Sci. Eng. A, 464(1–2) (2007), pp. 124–128.

    Article  Google Scholar 

  13. M. Ohno, D. Mirkovic, and R. Schmid-Fetzer, Acta Mater., 54 (2006), pp. 3883–3891.

    Article  CAS  Google Scholar 

  14. A. Prince, MSIT Workplace, ed. G. Effenberg (Stuttgart, Germany: MSI, Materials Science International Services GmbH, 1992), Document ID: 10.19950.1.20.

    Google Scholar 

  15. A. Prince, MSIT Workplace, ed. G. Effenberg (Stuttgart, Germany: MSI, Materials Science International Services GmbH, 1992), Document ID: 10.21613.1.20.

    Google Scholar 

  16. A. Prince, MSIT Workplace, ed. G. Effenberg (Stuttgart, Germany: MSI, Materials Science International Services GmbH, 1990), Document ID: 10.14589.1.20.

    Google Scholar 

  17. A. Prince, MSIT Workplace, ed. G. Effenberg (Stuttgart, Germany: MSI, Materials Science International Services GmbH, 1990), Document ID: 10.33760.1.20.

    Google Scholar 

  18. Q. Ran, MSIT Workplace, ed. G. Effenberg (Stuttgart, Germany: MSI, Materials Science International Services GmbH, 1992), Document ID: 10.28826.1.20.

    Google Scholar 

  19. A. Janz, “Thermodynamics and Constitution of Quaternary Mg-Al-Ca-Sr Alloys and the Extension to the Quinary Mg-Al-Ca-Sr-Mn System“ (Ph.D. thesis, Clausthal University of Technology, Germany, 28 March 2008).

    Google Scholar 

  20. S.-L. Chen et al., Calphad, 26 (2002), pp. 175–188.

    Article  CAS  Google Scholar 

  21. M. Ohno and R. Schmid-Fetzer, Z. Metallkunde, 96 (2005), pp. 857–869.

    CAS  Google Scholar 

  22. Yong Du et al., Int. J. Materials Research (Z. Metallkunde), 98 (2007), pp. 855–871.

    Article  CAS  Google Scholar 

  23. A. Janz et al., “Thermodynamic Modeling of the Mg-Al-Ca System”, Acta Materialia (2008) submitted.

  24. A. Janz et al., Intermetallics, 15 (2007), pp. 506–519.

    Article  CAS  Google Scholar 

  25. E. Doernberg, A. Kozlov, and R. Schmid-Fetzer, J. Phase Equilibria & Diffusion, 28 (2007), pp. 523–535.

    Article  CAS  Google Scholar 

  26. M. Ohno et al., Acta Mater., 54 (2006), pp. 4939–4951.

    Article  CAS  Google Scholar 

  27. A. Kozlov et al., Intermetallics, 16 (2008), pp. 299–315.

    Article  CAS  Google Scholar 

  28. A. Kozlov et al., Intermetallics, 16 (2008), pp. 316–321.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rainer Schmid-Fetzer.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gröbner, J., Janz, A., Kozlov, A. et al. Phase diagrams of advanced magnesium alloys containing Al, Ca, Sn, Sr, and Mn. JOM 60, 32–38 (2008). https://doi.org/10.1007/s11837-008-0163-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-008-0163-3

Keywords

Navigation