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Potential organic magnetic nanoparticles from peel extract of Archidendron pauciflorum for the effective removal of cationic and anionic dyes

  • Materials (Organic, Inorganic, Electronic, Thin Films)
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Abstract

The adsorption of cationic (methylene blue, MB) and anionic (Congo red, CR) dyes using magnetic from Archidendron pauciflorum peel extract obtained via sonochemical synthesis (Fe3O4-AP) has been carried out. This study also compared the ability of Fe3O4-AP as an adsorbent for MB and CR through isotherm and kinetics studies. Fe3O4-AP was synthesized by the sonochemical method at a frequency of 800 kHz and characterized using FTIR, XRD, PSA, VSM and SEM-EDX The XRD diffractogram showed Fe3O4-AP with high crystallinity with a crystal size of 17.05 nm, and the particle size distributed in three groups, 2.56, 862.23, and 4855.78 nm, respectively. Meanwhile, the Ms of Fe3O4-AP was 27.71 emu/g. The SEM-EDX showed disordered morphology with Fe, O and C elemental composition. The kinetics and isotherm of MB and CR dye adsorption on Fe3O4-AP followed Ho’s kinetics model and Freundlich isotherm. The Freundlich isotherm model with adsorption capacities MB and CR on Fe3O4-AP was 16.02 and 10.24 mg/g, respectively.

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Acknowledgements

The authors would like to thank the Institute for Research and Community Service UIN Sunan Kalijaga Yogyakarta for the 2022 research grant for a research cluster of higher education collaborations. The authors also thank Mr. Wijayanto as laboratory assistant from the UIN Sunan Kalijaga Integrated Laboratory who has accompanied the research team in completing this research. In addition, the authors also thank Dr. Khurul Wardati as dean of the Faculty of Science and Technology, UIN Sunan Kalijaga for administrative support.

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Authors and Affiliations

  1. Chemistry Department, Science and Technology Faculty, UIN Sunan Kalijaga Yogyakarta, Yogyakarta, 55281, Indonesia

    Maya Rahmayanti,  Karmanto & Endaruji Sedyadi

  2. Chemical Engineering Department, Faculty of Engineering Lambung Mangkurat University, Banjarbaru, 70714, Indonesia

    Meilana Dharma Putra

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  1. Maya Rahmayanti
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  2. Meilana Dharma Putra
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  3. Karmanto
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Correspondence to Maya Rahmayanti.

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Rahmayanti, M., Putra, M.D., Karmanto et al. Potential organic magnetic nanoparticles from peel extract of Archidendron pauciflorum for the effective removal of cationic and anionic dyes. Korean J. Chem. Eng. 40, 2759–2770 (2023). https://doi.org/10.1007/s11814-023-1499-7

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