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In situ soft templated synthesis of polyfluorene-molybdenum oxide (PF-MoO3) nanocomposite: A nanostructure glucose sensor

  • Materials (Organic, Inorganic, Electronic, Thin Films)
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Abstract

A polyfluorene-molybdenum oxide nanocomposite (PF-MoO3) was successfully prepared in swollen liquid crystalline (SLC) lamellar phase. The morphology, shape, and structure of the nanocomposite are characterized by field emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The obtained PF-MoO3 material was loaded over a glassy carbon electrode (GCE). The PF-MoO3/GCE was employed as a working electrode for the detection of glucose by differential pulse voltammetry (DPV) and cyclic voltammetry (CV) techniques. The determined limits of detection (LOD) and the limits of quantification (LOQ) from CV were 7.90×10−5M and 2.63×10−5M, respectively. The calculated sensitivity of the PF-MoO3 electrode material for glucose was estimated to be 4.29×104 µA L mol−1 cm−2. The values of LOD and LOQ obtained from DPV data were 7.05×10−5 M and 2.35×10−5 M, respectively. The results were in agreement with CV observations. Similarly, the glucose sensitivity for the PF-MoO3/GCE by DPV technique was 5.18×103 µA L mol−1 cm−2. In this research, we have developed a highly sensitive glucose sensor by modification of the GCE electrode surface with PF-MoO3 nanocomposite.

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References

  1. Y. Zhang, Y. Ma, Y. Li, W. Zhu, Z. Wei, J. Sun, T. Li and J. Wang, Appl. Surf. Sci., 505, 144636 (2020).

    Article  CAS  Google Scholar 

  2. M. Christwardana, J. Ji, Y. Chung and Y. Kwon, Korean J. Chem. Eng., 34, 2916 (2017).

    Article  CAS  Google Scholar 

  3. G. Wang, X. He, L. Wang, A. Gu, Y. Huang, B. Fang, B. Geng and X. Zhang, Microchim. Acta, 180, 161 (2013).

    Article  CAS  Google Scholar 

  4. M. Li, L. Liu, Y. Xiong, X. Liu, A. Nsabimana, X. Bo and L. Guo, Sens. Actuators B, 207, 614 (2015).

    Article  CAS  Google Scholar 

  5. K. E. Toghill and R. G. Compton, Int. J. Electrochem. Sci., 5, 1246 (2010).

    CAS  Google Scholar 

  6. Z. G. Zhu, L. Garcia-Gancedo, A. J. Flewitt, H. Q. Xie, F. Moussy and W. I. Milne, Sensors, 12, 5996 (2012).

    Article  PubMed  PubMed Central  Google Scholar 

  7. M. Pumera and A. Loo, TrAC Trends in Anal. Chem., 61, 49 (2014).

    Article  CAS  Google Scholar 

  8. S. Balendhran, S. Walia, H. Nili, J. Ou, S. Zhuiykov, R. B. Kaner, S. Sriram, M. Bhaskaran and K. Kalantar-zadeh, Adv. Funct. Mater., 23, 3952 (2013).

    Article  CAS  Google Scholar 

  9. V. M. Reddy, B. Sravani, T. Luczak, K. Mallikarjunad and G. Madhavi, Colloids Surf. A: Physicochem. Eng. Aspects, 608, 125533 (2021).

    Article  CAS  Google Scholar 

  10. L. Zhang, H. Li, Y. Ni, J. Li, K. Liao and G. Zhao, Electrochem. Commun., 11, 812 (2009).

    Article  CAS  Google Scholar 

  11. Y. Xue, B. Tian, M. Wang, T. Zhai, R. Li and L. Tan, Colloids Surf. A: Physicochem. Eng. Aspects, 591, 124549 (2020).

    Article  CAS  Google Scholar 

  12. F. Meng, W. Shi, Y. Sun, X. Zhu, G. Wua, C. Ruan, X. Liu and D. Ge, Biosens. Bioelectron., 42, 141 (2013).

    Article  CAS  PubMed  Google Scholar 

  13. A. M. Azharudeen, R. Karthiga, M. Rajarajan and A. Suganthi, Microchem. J., 157, 105006 (2020).

    Article  CAS  Google Scholar 

  14. I. Shakir and M. Sarfraz, Electrochim. Acta, 147, 380 (2014).

    Article  CAS  Google Scholar 

  15. Y. Wang, Y. Zhu, Z. Xing and Y. Qian, Int. J. Electrochem. Sci., 8, 9851 (2013).

    CAS  Google Scholar 

  16. D. Murugesan, K. Moulaee, G. Neri, N. Ponpandian and C. Viswanathan, Nanotechnology, 30, 265501 (2019).

    Article  CAS  PubMed  Google Scholar 

  17. W. Lei, W. Si, Y. Xu, Z. Gu and Q. Hao, Microchim. Acta, 181, 707 (2014).

    Article  CAS  Google Scholar 

  18. L. Li, H. Qiu, Y. Wang, J. Jiang and F. Xu, J. Rare Earths, 26, 558 (2008).

    Article  Google Scholar 

  19. J. Mort, Science, 208, 819 (1980).

    Article  CAS  PubMed  Google Scholar 

  20. L. Zhang, S. Yuan and X. Lu, Microchim. Acta, 181, 365 (2014).

    Article  CAS  Google Scholar 

  21. J. Xie, X. Yang, S. Zhou and D. Wang, ACS Nano., 5, 9225 (2011).

    Article  CAS  PubMed  Google Scholar 

  22. A. Mehdinia, H. Khani and S. Mozaffari, Microchim. Acta, 181, 89 (2014).

    Article  CAS  Google Scholar 

  23. A. Mostafaei and F. Nasirpouri, Prog. Org. Coat., 77, 146 (2014).

    Article  CAS  Google Scholar 

  24. F. Jiang, W. Li, R. Zou, Q. Liu, K. Xu, L. An and J. Hu, Nano Energy, 7, 72 (2014).

    Article  CAS  Google Scholar 

  25. S. Li, D. Wu, C. Cheng, J. Wang, F. Zhang, Y. Su and X. Feng, Chem. Int. Ed., 52, 12105 (2013).

    Article  CAS  Google Scholar 

  26. D. Neher, Macromol. Electroluminescence Rap. Commun., 22, 1365 (2001).

    Article  CAS  Google Scholar 

  27. U. Scherf and E. J. W. List, Adv. Mater., 14, 477 (2002).

    Article  CAS  Google Scholar 

  28. G. Surendran, M. Tokumoto, E. Pena dos Santos, H. Remita, L. Ramos, P. Kooyman and J. Prouzet, Chem. Mater., 17, 1505 (2005).

    Article  CAS  Google Scholar 

  29. A. Tawade, D. Mohan kumar, P. Talele, K. K. Sharma and S. Tayade, J. Electronic Mater., 48, 7747 (2019).

    Article  CAS  Google Scholar 

  30. A. Chithambararaj and A. Bose, J. Nanotechnol., 2, 585 (2011).

    CAS  Google Scholar 

  31. A. Aljabali, J. Barclay, J. George, B. Lomonossoffa and P. Evans, Dalton Trans., 39, 7569 (2010).

    Article  CAS  PubMed  Google Scholar 

  32. G. S. Zakharova, C. Schmidt, A. Ottmann, E. Mijowska and R. Klingeler, J. Solid State Electrochem., 22, 3651 (2018).

    Article  CAS  Google Scholar 

  33. G. Farial, T. Plivelic, R. Cossiello and A. Multitechnique, J. Phys. Chem. B, 113, 11403 (2009).

    Article  CAS  Google Scholar 

  34. M. Jumali, B. Al-Asbahi, C. Yap, M. Salleh and M. Alsalhi, Thin Solid Films, 524, 257 (2012).

    Article  CAS  Google Scholar 

  35. T. Mika, G. Frank and S. Ullrich, Macromolecules, 48, 5244 (2015).

    Article  CAS  Google Scholar 

  36. M. Sims, D. D. C Bradely, M. Ariu, M. Koeberg, A. Asimakis, M. Grell and D. G. Lidzey, Adv. Funct. Mater., 14, 765 (2004).

    Article  CAS  Google Scholar 

  37. K. Li, J. Pan, S. Feng, A. Wenqing, K. Pu, Y. Liu and B. Liu, Adv. Funct. Mater., 19, 3535 (2009).

    Article  CAS  Google Scholar 

  38. S. E. Dhanavel, A. K. Nivethaa, K. Dhanapal, V.K. Gupta, V. Narayanan and A. Stephena, RSC Adv., 6, 28871 (2016).

    Article  CAS  Google Scholar 

  39. B. A. Rozenberg and R. Tenne, Prog. Polym. Sci., 33, 40 (2008).

    Article  CAS  Google Scholar 

  40. A. Chithambararaj and A. Bose, J. Alloys Compd., 509, 8105 (2011).

    Article  CAS  Google Scholar 

  41. W. Zhao, T. Cao and J. M. White, Adv. Funct. Mater., 14, 783 (2004).

    Article  CAS  Google Scholar 

  42. T. Marimuthu, S. Mohamad and Y. Alias, Synthetic Metals, 207, 35 (2015).

    Article  CAS  Google Scholar 

  43. B. Kamble, M. Naikwade, K. Garadkar, R. Mane, K. Sharma B. Ajalkar and S. Tayade, J. Mater. Sci.: Mater. Electron., 30, 13984 (2019).

    CAS  Google Scholar 

  44. X. Li and X. Du, Sens. Actuators B: Chem., 239, 536 (2017).

    Article  CAS  Google Scholar 

  45. K. Anderson, B. Poulter, J. Dudgeon, S.-E. Li and X. Ma, Sensors, 17, 1807 (2017).

    Article  PubMed Central  CAS  Google Scholar 

  46. A. M. Azharudeen, R. Karthiga, M. Rajarajan and A. Suganthi, Microchem. J., 157, 105006 (2020).

    Article  CAS  Google Scholar 

  47. M. Sharma, A. Gangan, B. Chakraborty and C. S. Rout, J. Phys. D: Appl. Phys., 50, 475401 (2017).

    Article  CAS  Google Scholar 

  48. Y. J. Zhai, J. H. Li, X. Y. Chu, M. Z. Xu, F. J. Jin, X. Li, X. Fang, Z. P. Wei and X. H Wang, J. Alloys Compd., 672, 600 (2016).

    Article  CAS  Google Scholar 

  49. P. Kannan, F. Chen, H. Jiang, H. Wang, R. Wang, P. Subramanian and S. Ji, Analyst, 144, 4925 (2019).

    Article  CAS  PubMed  Google Scholar 

  50. H. Ren, L. Yan, M. Liu, Y. Wang, X. Liu, C. Liu, K. Liu, L. Zeng and A. Liu, Sens. Actuators B: Chem., 296, 126517 (2019).

    Article  CAS  Google Scholar 

  51. L. Fang, F. Wang, Z. Chen, Y. Qiu, T. Zhai, M. Hu, C. Zhang and K. Huang, Talanta, 167, 593 (2017).

    Article  CAS  PubMed  Google Scholar 

  52. Z. Zhang, D. Vieira, J. E. Barralet and G. Merle, 2D Mater., 7, 025044 (2020).

    Article  CAS  Google Scholar 

  53. Z. Shahnavaz, F. Lorestani, Y. Alias and P. M. Woi, Appl. Surf. Sci., 317, 622 (2014).

    Article  CAS  Google Scholar 

  54. M. Lyons and G. P. Keeley, Chem. Commun., 22, 2529 (2008).

    Article  CAS  Google Scholar 

  55. N. Hui, S. Wang, H. Xie, S. Xu, S. Niu and X. Luo, Sens. Actuators B, 221, 606 (2015).

    Article  CAS  Google Scholar 

  56. A. S. Kumar, P. Y. Chen, S. H. Chien and J. M. Zen, Electroanalysis, 3, 17 (2005).

    Google Scholar 

  57. S. Park, H. Boo and T. Dong, Anal. Chim. Acta, 556, 46 (2006).

    Article  CAS  PubMed  Google Scholar 

  58. F. Largeaud, K. B. Kokoh, B. Beden and C. J. Lamy, Electroanal. Chem., 397, 261 (1995).

    Article  Google Scholar 

  59. S. Ernst, J. Heitbaum, C. H. Hamann and B. Bunsenges, Phys. Chem., 84, 50 (1980).

    CAS  Google Scholar 

  60. N. Hareesha and J. G. Manjunatha, J. Iran Chem. Soc., 17, 1507 (2020).

    Article  CAS  Google Scholar 

  61. A. Bard and L. Faulkner, Electrochemical methods: fundamentals and applications, 2nd Edition, John Wiley, New York (2001).

    Google Scholar 

  62. B. B. Kamble, A. K. Tawade, P. Kamble, M. N. Padavi, K. K. Sharma, B. D. Ajalkar and S. N. Tayade, Russian J. Electrochem., 56, 766 (2020).

    Article  Google Scholar 

  63. A. Raziq, M. Tariq, R. Hussian, M. Mehmood, M. S. Khan and A. Hassan, Chem. Select., 2, 9711 (2017).

    CAS  Google Scholar 

  64. B. B. Kamble, B. D. Ajalkar, A. K. Tawade, K. K. Sharma, S. S. Mali, C. K. Hong, C. Bathula, A. N. Kadam and S. N. Tayade, J. Mol. Liq., 324, 115119 (2021).

    Article  CAS  Google Scholar 

  65. P. Mukherjee, P. S. Roy and S. K. Bhattacharya, Int. J. Hydrogen Energy, 40, 13357 (2015).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Shivaji University, Kolhapur, 416004, Maharashtra, India

    Bhagyashri Bajirao Kamble & Shivaji Nemchand Tayade

  2. Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, India

    Paurnima Talele

  3. School of Nanoscience and Technology, Shivaji University, Kolhapur, 416004, Maharashtra, India

    Anita Kundlik Tawade & Kirankumar Kakchingtabam Sharma

  4. Polymer Energy Materials Laboratory, School of Advance Chemical Engineering, Chonnam National University, Gwangju, 61186, Korea

    Sawanta Subhash Mali & Chang Kook Hong

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  1. Bhagyashri Bajirao Kamble
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11814_2021_1010_MOESM1_ESM.pdf

In situ soft templated synthesis of polyfluorene-molybdenum oxide (PF-MoO3) nanocomposite: A nanostructure glucose sensor

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Kamble, B.B., Talele, P., Tawade, A.K. et al. In situ soft templated synthesis of polyfluorene-molybdenum oxide (PF-MoO3) nanocomposite: A nanostructure glucose sensor. Korean J. Chem. Eng. 39, 1604–1613 (2022). https://doi.org/10.1007/s11814-021-1010-2

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