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Electrodeposition-fabricated catalysts for polymer electrolyte water electrolysis

  • Invited Review Paper
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Abstract

Water electrolysis using renewable energy sources such as solar and wind power has the advantage of producing hydrogen with high efficiency and zero emissions. Solid polymer electrolyte water electrolysis (SPEWE) is divided into anion exchange membrane electrolysis (AEMWE) carried out in an alkaline environment and proton exchange membrane electrolysis (PEMWE) carried out in an acidic environment. Research on the electrocatalysts used in these electrolysis procedures has focused on the development of transition metal-based catalysts with catalytic activity, high stability, and low cost that can replace the currently used noble-metal based electrocatalysts. Among the various electrocatalyst fabrication methods, electrodeposition can be used to fabricate catalysts in a simple manner at low cost and high purity. In addition, catalysts can be directly electrodeposited onto a substrate such as a gas diffusion layer, simplifying the electrode fabrication process and readily enabling the advantageous control of the physical, chemical, structural, and compositional properties of the catalyst. In this paper, we summarize the characteristics and structures of the water electrolysis catalysts prepared by the electrodeposition method based on recent research studies that suggest their applicability to practical water electrolysis systems in the future.

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Acknowledgements

This work was supported by the Hydrogen Energy Innovation Technology Development Program of the National Research Foundation (NRF) of Korea funded by Korean government (Ministry of Science and ICT (MSIT)) (grant number 2019M3E6A1063676). This work is also supported by the Chung-Ang University Research Scholarship Grants in 2020.

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Authors and Affiliations

  1. School of Integrative Engineering, Chung-Ang University, 84 Heukseok-ro, Dongjak-gu, Seoul, 06974, Korea

    Hoyoung Kim, Hyanjoo Park, Hotae Bang & Soo-Kil Kim

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  1. Hoyoung Kim
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  2. Hyanjoo Park
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  3. Hotae Bang
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Correspondence to Soo-Kil Kim.

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Soo-Kil Kim received his BS (1999), MS (2001), and Ph D (2004) degrees from School of Chemical and Biological Engineering, Seoul National University, Korea. From 2005 to 2006, he worked as a guest researcher at National Institute of Standards and Technology, Gaithersburg, USA. After that he joined Fuel Cell Research Center, Korea Institute of Science and Technology as a senior research scientist. In 2011, he joined School of Integrative Engineering, Chung-Ang University as a faculty member. He has published more than 130 papers and 58 international and domestic patents on electrocatalysts for fuel cell, CO2 conversion, and water electrolysis as well as on metal interconnection for semiconductor devices. He has served in various positions at The Korean Institute of Chemical Engineers, The Korean Electrochemical Society, and The Electrochemical Society (USA).

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Kim, H., Park, H., Bang, H. et al. Electrodeposition-fabricated catalysts for polymer electrolyte water electrolysis. Korean J. Chem. Eng. 37, 1275–1294 (2020). https://doi.org/10.1007/s11814-020-0626-y

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