Skip to main content
SpringerLink
Log in

Preparation of CO2 adsorbent with N1-(3-(trimethoxysilyl)propyl)-1,3-propanediamine and its performance

  • Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

N1-(3-(trimethoxysilyl)propyl)-1,3-propanediamine (2NS-P), a diaminosilane having a propyl spacer between the two amino groups was successfully synthesized, and a CO2 adsorbent functionalized with 2NS-P was prepared via impregnation of it into silica. The adsorption performance and stability of 2NS-P/Kona95 were examined and compared to that of N1-(3-(trimethoxysilyl)propyl)ethane-1,2-diamine (2NS)/Kona95 having an ethyl spacer. 2NS-P/Kona95 exhibited better CO2 adsorption capacity and CO2/N efficiency. The adsorbents were subjected to ten cycles of temperature swing adsorption (TSA), demonstrating that stability of 2NS-P/Kona95 was better than that of 2NS/Kona95. The spent 2NS-P/Kona95 showed the absence of cyclic urea formation in FT-IR spectrum, explaining the better stability of 2NS-P/Kona95 than 2NS/Kona95.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Oexmann and A. Kather, Int. J. Greenh. Gas Control, 4, 36 (2010).

    Article  CAS  Google Scholar 

  2. I. Kim and H. F. Svendsen, Ind. Eng. Chem. Res., 46, 5803 (2007).

    Article  CAS  Google Scholar 

  3. B. P. Spigarelli and S. K. Kawatra, J. CO2 Util., 1, 69 (2013).

    Article  CAS  Google Scholar 

  4. G. T. Rochelle, Science, 325, 1652 (2009).

    Article  CAS  Google Scholar 

  5. D. M. D’Alessandro, B. Smit and J. R. Long, Angew. Chem. Int. Ed., 49(35), 6058 (2010).

    Article  Google Scholar 

  6. I. Sreedhar, T. Nahar, A. Venugopal and B. Srinivas, Renew. Sustain. Energy Rev., 76, 1080 (2017).

    Article  CAS  Google Scholar 

  7. A. Samanta, A. Zhao, G. K. H. Shimizu, P. Sarkar and R. Gupta, Ind. Eng. Chem. Res., 51(4), 1438 (2012).

    Article  CAS  Google Scholar 

  8. R. V. Siriwardane, M. Shen, E. P. Fisher and J. A. Poston, Energy Fuels, 15(2), 279 (2001).

    Article  CAS  Google Scholar 

  9. S. Choi, J. H. Drese and C. W. Jones, ChemSusChem., 2, 796 (2009).

    Article  CAS  Google Scholar 

  10. J. Wang, L. Huang, R. Yang, Z. Zhang, J. Wu, Y. Gao, Q. Wang, D. O’Hare and Z. Zhong, Energy Environ. Sci., 7, 3478 (2014).

    Article  CAS  Google Scholar 

  11. K. Min, W. Choi, C. Kim, C. Kim and M. Choi, Nat. Commun., 9, 726 (2018).

    Article  Google Scholar 

  12. D. H. Kim, J. Celedonio and Y. S. Ko, Top. Catal., 60, 706 (2017).

    Article  CAS  Google Scholar 

  13. D. H. Kim and Y. S. Ko, Res. Chem. Intermed., 44, 3661 (2018).

    Article  CAS  Google Scholar 

  14. C. Manianglung, R. M. Pacia and Y. S. Ko, Korean J. Chem. Eng., 36(8), 1267 (2019).

    Article  CAS  Google Scholar 

  15. P. Bollini, S. A. Didas and C. W. Jones, J. Mater. Chem., 21(39), 15100 (2011).

    Article  CAS  Google Scholar 

  16. J. H. Park, J. M. Celedonio, H. Seo, Y. K. Park and Y. S. Ko, Catal. Today, 265, 68 (2016).

    Article  CAS  Google Scholar 

  17. A. Sayari, A. Heydari-Gorji and Y. Yang, J. Am. Chem. Soc., 134(33), 13834 (2012).

    Article  CAS  Google Scholar 

  18. A. Heydari-Gorji and A. Sayari, Ind. Eng. Chem. Res., 51(19), 6887 (2012).

    Article  CAS  Google Scholar 

  19. J. M. Celedonio, R. M. Pacia and Y. S. Ko, Catal. Today, 303, 55 (2018).

    Article  CAS  Google Scholar 

  20. A. F. Ciftja, A. Hartono and H. F. Svendsen, Energy Procedia, 37, 1605 (2013).

    Article  CAS  Google Scholar 

  21. M. J. O’Brien, R. L. Farnum and R. J. Perry, Energy Fuels, 27(1), 467 (2013).

    Article  Google Scholar 

  22. W. Choi, K. Min, C. Kim, Y. S. Ko, J. W. Jeon, H. Seo, Y.-K. Park and M. Choi, Nat. Commun., 7, 12640 (2016).

    Article  CAS  Google Scholar 

  23. S. H. Pang, L. C. Lee, M. A. Sakwa-Novak, R. P. Lively and C. W. Jones, J. Am. Chem. Soc., 139(10), 3627 (2017).

    Article  CAS  Google Scholar 

  24. R. M. Pacia, C. Manianglung and Y. S. Ko, Catalysts, 9(11), 910 (2019).

    Article  CAS  Google Scholar 

  25. S. Cerveny, G. A. Schwartz, J. Otegui, J. Colmenero, J. Loichen and S. Westermann, J. Phys. Chem. C, 116(45), 24340 (2012).

    Article  CAS  Google Scholar 

  26. K. Li, J. Jang, F. Yan, S. Tian and X. Chen, Appl. Energy, 136, 750 (2014).

    Article  CAS  Google Scholar 

  27. K. M. Hello, A. A. Ibrahim, J. K. Shneine and J. N. Appaturi, South African J. Chem. Eng., 25, 159 (2018).

    Article  Google Scholar 

  28. M. Borkovec and G. J. M. Koper, J. Phys. Chem., 98(23), 6038 (1994).

    Article  CAS  Google Scholar 

  29. G. J. M. Koper, M. H. P. Van Genderen, C. Elissen-Román, M. W. P. L. Baars, E. W. Meijer and M. Borkovec, J. Am. Chem. Soc., 119(28), 6512 (1997).

    Article  CAS  Google Scholar 

  30. N. Hedin and Z. Bacsik, Curr. Opin. Green Sustain. Chem., 16, 13 (2019).

    Article  Google Scholar 

  31. C. H. Chen, D. Shimon, J. J. Lee, S. A. Didas, A. K. Mehta, C. Sievers, C. W. Jones and S. E. Hayes, Environ. Sci. Technol., 51, 6553 (2017).

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by a National Research Foundation of Korea (NRF) grant funded by the government of Korea (MSIP) (2016R1D1A1B01009941). Financial grants for this endeavor were also provided by the Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) under the Ministry of Trade, Industry & Energy, Republic of Korea (No. 20194010201730).

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Kongju National University, 1223-24 Cheonan-daero, Seobuk-gu, Cheonan, 31080, Korea

    Tristan James Sim, Rose Mardie Pacia & Young Soo Ko

Authors
  1. Tristan James Sim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rose Mardie Pacia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Young Soo Ko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Young Soo Ko.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sim, T.J., Pacia, R.M. & Ko, Y.S. Preparation of CO2 adsorbent with N1-(3-(trimethoxysilyl)propyl)-1,3-propanediamine and its performance. Korean J. Chem. Eng. 37, 1515–1521 (2020). https://doi.org/10.1007/s11814-020-0565-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-020-0565-7

Keywords

Search

Navigation