Skip to main content
SpringerLink
Log in

Adsorption of phosphate from aqueous solution by lanthanum modified macroporous chelating resin

  • Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

A highly effective adsorbent of lanthanum-modified D751 resin (D751 resin for macroporous styrene chelated resin, sodium form) was prepared to enhance the effect of removing phosphate from solution. FTIR, SEM were used to explore the functional groups and structural features on the surface of D751-La; XPS analyzed the action mechanism between phosphate and D751-La. The adsorption performance about D751-La toward phosphate was investigated by batch experiment. The results showed that Langmuir, Freundlich, Temkin, Koble-Corrigan as well as Redlich-Peterson models fitted well for the adsorption isotherms. The adsorption kinetics could be better fitted by Double Constant, Elovich, and Pseudo-second-order model. The effect of salinity was not significant, such as Cl− and SO42−. When the solid-liquid ratio was 15 g·L−1 with setting the reaction time as 8 h, the unit adsorption quantity of D751-La to phosphate (calculated in P) reached up to 26.3mg·g−1 under the solution pH=3 at 293 K. The process was spontaneous and exothermic from thermodynamic analysis. It shows that D751-La has potential to remove phosphate from solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. H. Li, J. L. Cui, X. D. Li and X. Y. Li, Environ. Sci. Technol., 52, 14119 (2018).

    Article  CAS  PubMed  Google Scholar 

  2. A. Othman, E. Dumitrescu, D. Andreescu and S. Andreescu, ACS Sustain. Chem. Eng., 6, 12542 (2018).

    Article  CAS  Google Scholar 

  3. Y. Zhang, X. M. Guo, Y. Yao, F. Wu, C. Z. Zhang, R. J. Chen, J. Lu and K. Amine, ACS Appl. Mater. Inter., 8, 2905 (2016).

    Article  CAS  Google Scholar 

  4. M. Kim, H. Kim and S. H. Byeon, ACS Appl. Mater. Inter., 9, 40461 (2017).

    Article  CAS  Google Scholar 

  5. C. M. Nobile, M. N. Bravin, E. Tillard, T. Becquer and J. M. Paillat, Soil Use Manage., 34, 461 (2018).

    Article  Google Scholar 

  6. Y. L. Zhang, H. Y. Ma, L. Lin, W.Z. Cao, T. Ouyang and Y. Y. Li, ACS Sustain. Chem. Eng., 6, 10989 (2018).

    Article  CAS  Google Scholar 

  7. B. C. Pan, F. C. Han, G. Z. Nie, B. Wu, K. He and L. Lu, Environ. Sci. Technol., 48, 5101 (2014).

    Article  CAS  PubMed  Google Scholar 

  8. M. Amini, Z. A. Khoei and E. Erfanifar, Biocat. Agricul. Biotechnol., 19, 101097 (2019).

    Article  Google Scholar 

  9. M. N. Afridi, W. H. Lee and J. O. Kim, Environ. Res., 171, 428 (2019).

    Article  CAS  PubMed  Google Scholar 

  10. M. Y. Han, J.H. Zhang, Y.Y. Hu and R. P. Han, J. Chem. Eng. Data, 64, 3641 (2019).

    Article  CAS  Google Scholar 

  11. J. Q. Zhu, J. Y. Li, Y. Y. Li, J. Guo, X. Yu, L. Peng, B. P. Han, Y. Zhu and Y. M. Zhang, Sep. Purif. Technol., 223, 196 (2019).

    Article  CAS  Google Scholar 

  12. A. B. Savic, D. Cokesa, M. S. Bisercic, I. Castvan-Jankovic, R. Petrovic and L. S. Zivkovic, Adv. Powder Technol., 30, 1687 (2019).

    Article  CAS  Google Scholar 

  13. J. J. Song, P. P. Huang, L. F. Chen, Z.W. Qi and J. G. Yu, Chem. Ind. Eng. Progr., 31, 370 (2012).

    Google Scholar 

  14. L. Dithme, A. S. Lipton, K. Reitzel, T. E. Warner, D. Lundberg and U. G. Nielsen, Environ. Sci. Technol., 49, 4559 (2015).

    Article  CAS  Google Scholar 

  15. G. T. Adithya, S. Rangabhashiyam and C. Sivasankari, Microchem. J., 148, 364 (2019).

    Article  CAS  Google Scholar 

  16. J. P. Hu, D. Z. Wu, R. L. Liu, R. Z. Rao and W. L. Lai, J. Safety Environ., 16, 237 (2016).

    Google Scholar 

  17. L. Chen, F. Liu, Y. Wu, L. M. Zhao, Y. Z. Li, X. Zhang and J. S. Qian, Chem. Eng. J., 347, 695 (2018).

    Article  CAS  Google Scholar 

  18. H. H. Yi, Q. F. Yu, X. L. Tang, P. Ning, L. P. Yang, Z.Q. Ye and J. H. Song, Ind. Eng. Chem. Res., 50, 3960 (2011).

    Article  CAS  Google Scholar 

  19. M. Saraf, P. Kumar, G. Kedawat, J. Dwivedi, S.A. Vithayathil, N. Jaiswal, B.A. Kaipparettu and B. K. Gupta, Inorg. Chem., 54, 2616 (2015).

    Article  CAS  PubMed  Google Scholar 

  20. X. B. Luo, X. Wu, Z. Reng, X. Y. Min, X. Xiao and J. M. Luo, Ind. Eng. Chem. Res., 56, 9419 (2017).

    Article  CAS  Google Scholar 

  21. L. P. Fang, Q.T. Shi, J. Nguyen, B. L. Wu, Z. M. Wang and I. M. C. Lo, Environ. Sci. Technol., 51, 12377 (2017).

    Article  CAS  PubMed  Google Scholar 

  22. Z. C. Yang, L. H. Liu, L. Zhao, G. Su, Z. X. Wei, A. P. Tang and J. R. Xue, J. Environ. Sci., 86, 24 (2019).

    Article  Google Scholar 

  23. D. Setyono and S. Valiyaveettil, ACS Sustain. Chem. Eng., 2, 2722 (2014).

    Article  CAS  Google Scholar 

  24. T. Liu, S. R. Zheng and L. Y. Yang, J. Colloid Interface Sci., 552, 134 (2019).

    Article  CAS  PubMed  Google Scholar 

  25. W. C. Qiao, H. Bai, T. H. Tang, J.H. Miao and Q. W. Yang, Colloids Surf. A, 577, 118 (2019).

    Article  CAS  Google Scholar 

  26. X. Q. Li, J. Cui and Y. S. Pei, J. Environ. Manage., 213, 36 (2018).

    Article  CAS  PubMed  Google Scholar 

  27. Z. Y. Jia, Z. G. Wang, P. G. Cheng, Z. L. Xiang and N. Tang, Water Treat. Technol., 40, 83 (2014).

    CAS  Google Scholar 

  28. X. T. Zhang, R. Z. Zhang, S. S. Chen, K. Wen and R. P. Han, Desalin. Water Treat., 170, 187 (2019).

    Article  Google Scholar 

  29. M. L. Chen, C. B. Huo, Y. K. Li and J. H. Wang, ACS Sustain. Chem. Eng., 4, 1296 (2016).

    Article  CAS  Google Scholar 

  30. Y. F. Gu, M. M. Yang, W. L. Wang and R. P. Han, J. Chem. Eng. Data, 64, 2849 (2019).

    Article  CAS  Google Scholar 

  31. Y. C. Rong and R. P. Han, Korean J. Chem. Eng., 36, 942 (2019).

    Article  CAS  Google Scholar 

  32. F.Z. Xie, Z. L. Dai, Y.R. Zhu, G. L. Li, H. B. Li, Z.Q. He, S.X. Geng and F. C. Wu, Colloids Surf. A, 562, 16 (2018).

    Article  CAS  Google Scholar 

  33. W. H. Zou, H. J. Bai and S. P. Gao, J. Chem. Eng. Data, 57, 2792 (2012).

    Article  CAS  Google Scholar 

  34. R. D. Zhang, J. H. Zhang, X.N. Zhang, C. C. Dou and R. P. Han, J. Taiwan Inst. Chem. E., 45, 2578 (2014).

    Article  CAS  Google Scholar 

  35. J. Chen, L. G. Yan, H. Q. Yu, S. Li, L. L. Qin, G. Q. Liu, Y. F. Li and B. Du, Chem. Eng. J., 287, 162 (2016).

    Article  CAS  Google Scholar 

  36. X. H. Liu, E. M. Zong, W. J. Hu, P. G. Song, J. F. Wang, Q. C. Liu, Z. Q. Ma and S. Y. Fu, ACS Sustain. Chem. Eng., 7, 758 (2019).

    Article  CAS  Google Scholar 

  37. B. L. Zhao, W. Xiao, Y. Shang, H. M. Zhu and R. P. Han, Arab. J. Chem., 10, s359 (2017).

  38. M. Y. Han, Q. Wang, H. Li, L.Y. Fang and R. P. Han, Desalin. Water Treat., 115, 271, (2018).

  39. Y. F. Gu, M.Y. Liu, M. M. Yang, W. L. Wang, S. S. Zhang and R. P. Han, Desalin. Water Treat., 138, 368 (2019).

    Article  CAS  Google Scholar 

  40. Y. Y. Hu and R. P. Han, J. Chem. Eng. Data, 64, 791 (2019).

    Article  CAS  Google Scholar 

  41. S. Chen, C. X. Qin, T. Wang, F. Y. Chen, X. L. Li, H. B. Hou and M. Zhou, J. Mol. Liq., 285, 62 (2019).

    Article  CAS  Google Scholar 

  42. R. Xue, J. Xu, L. Gu, L. H. Pan and Q. He, Water Air Soil Poll., 229, 1 (2018).

    Article  CAS  Google Scholar 

  43. X. Q. Li, J. Cui and Y. S. Pei, J. Environ. Manage., 213, 36 (2018).

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgement

This work was supported in part by the Key Scientific Research Project in Universities of Henan Province (19A150048).

Author information

Authors and Affiliations

  1. College of Chemistry, Zhengzhou University, No 100 of Kexue Road, Zhengzhou, 450001, P. R. China

    Xiaoting Zhang, Chenghui Ma, Kang Wen & Runping Han

Authors
  1. Xiaoting Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chenghui Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kang Wen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Runping Han
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Runping Han.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, X., Ma, C., Wen, K. et al. Adsorption of phosphate from aqueous solution by lanthanum modified macroporous chelating resin. Korean J. Chem. Eng. 37, 766–775 (2020). https://doi.org/10.1007/s11814-020-0495-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-020-0495-4

Keywords

Search

Navigation