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Fischer-Tropsch synthesis on Co-Al2O3-(promoter)/ZSM5 hybrid catalysts for the production of gasoline range hydrocarbons

  • Catalysis, Reaction Engineering
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Abstract

The Fischer-Tropsch synthesis (FTS) reaction was investigated for the direct production of gasoline range hydrocarbons (C5-C9) from syngas on Ru-, Pt- and La-promoted Co-Al2O3/ZSM-5 (Si/Al=25) hybrid catalysts prepared by co-precipitation method in a slurry. The hybrid catalysts were characterized by BET surface area, XRD, H2-TPR and NH3-TPD analyses. Their physicochemical properties were correlated with the activity and selectivity of the catalysts. The promoted Co-Al2O3-(promoter)/ZSM-5 hybrid catalysts were superior to the unpromoted Co-Al2O3/ ZSM-5 catalyst in terms of better C5-C9 yield. In particular, the Co-Al2O3-Pt/ ZSM-5 hybrid catalyst exhibited the highest catalytic activity with a low C1 and olefin selectivity and a high C5-C9 selectivity. It could be due to not only a higher value for the reduction degree by H2-TPR, but also assigned to weak acidic sites of a low temperature desorption peak by NH3-TPD.

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Authors and Affiliations

  1. Plant Engineering Center, Institute for Advances Engineering (IAE), Suwon, 443-749, Korea

    Jae-Hong Ryu, Suk-Hwan Kang & Jin-Ho Kim

  2. Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), Sinseong-ro 19, Yuseong, Daejeon, P. O. Box 107, 305-600, Korea

    Yun-Jo Lee & Ki-Won Jun

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  1. Jae-Hong Ryu
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  2. Suk-Hwan Kang
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  3. Jin-Ho Kim
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  4. Yun-Jo Lee
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  5. Ki-Won Jun
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Correspondence to Jae-Hong Ryu.

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Ryu, JH., Kang, SH., Kim, JH. et al. Fischer-Tropsch synthesis on Co-Al2O3-(promoter)/ZSM5 hybrid catalysts for the production of gasoline range hydrocarbons. Korean J. Chem. Eng. 32, 1993–1998 (2015). https://doi.org/10.1007/s11814-015-0046-6

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  • DOI: https://doi.org/10.1007/s11814-015-0046-6

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