Skip to main content
Log in

Properties of chitosan/magnetite nanoparticles composites for efficient dye adsorption and antibacterial agent

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Chitosan (CS)/iron oxide (Fe3O4) composites were prepared using a chemical precipitation method. The CS/Fe3O4 composite was characterized by Fourier-transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, and zeta-potential measurements. The composite was used to remove methyl orange (MO) dye from an aqueous solution. The factors affecting the adsorption capacity, such as adsorption time, absorbent dosage and solution pH were investigated. The results suggested that the composite was an effective adsorbent for the removal of MO dye from its aqueous solution. Kinetics studies showed that the adsorption process was consistent with a pseudo-second- order model. The adsorbent efficiency was unaltered, even after five cycles of reuse, and the adsorbent could be recollected easily using a magnet. In addition, the composite exhibited a superior antibacterial efficacy against Escherichia coli; 82% within 24 h, as measured by the colony forming units.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. Moussavi and M. Mahmoudi, J. Hazard. Mater., 168, 806 (2009).

    Article  CAS  Google Scholar 

  2. K. Vijayaraghavan and Y.-S. Yun, Biotechnol. Adv., 26, 266 (2008).

    Article  CAS  Google Scholar 

  3. F.-C. Wu and R.-L. Tseng, J. Hazard. Mater., 152, 1256 (2008).

    Article  CAS  Google Scholar 

  4. M. Zhao, Z. Tang and P. Liu, J. Hazard. Mater., 158, 43 (2008).

    Article  CAS  Google Scholar 

  5. H.S. Rai, M.S. Bhattacharyya, J. Singh, T.K. Bansal, P. Vats and U. C. Banerjee, Crit. Rev. Environ. Sci. Technol., 35, 219 (2005).

    Article  CAS  Google Scholar 

  6. M. Valix, W. H. Cheung and G. McKay, Langmuir, 22, 4574 (2006).

    Article  CAS  Google Scholar 

  7. Y. S. Ho and G. McKay, Chem. Eng. J., 70, 115 (1998).

    Article  CAS  Google Scholar 

  8. K.Y. Ho, G. McKay and K. L. Yeung. Langmuir, 19, 3019 (2003).

    Article  CAS  Google Scholar 

  9. P. Liu and L. Zhang, Sep. Purif. Technol., 58, 32 (2007).

    Article  CAS  Google Scholar 

  10. E. I. Rabea, M.E.-T. Badawy, C.V. Stevens, G. Smagghe and W. Steurbaut, Biomacromolecules, 4, 1457 (2003).

    Article  CAS  Google Scholar 

  11. C. M. Yeng, S. Husseinsyah and S. S. Ting, BioResources, 8, 2910 (2013).

    Google Scholar 

  12. Z. Liu, H. Bai and D. D. Sun, New J. Chem., 35, 137 (2011).

    Article  CAS  Google Scholar 

  13. V. Singh, A. K. Sharma and R. Sanghi, J. Hazard. Mater., 166, 327 (2009).

    Article  CAS  Google Scholar 

  14. L. Douziech-Eyrolles, H. Marchais, K. Hervé, E. Munnier, M. Soucé, C. Linassier, P. Dubois and I. Chourpa, Int. J. Nanomedicine., 2, 541 (2007).

    Google Scholar 

  15. G. Reiss and A. Hütten, Nature Mater., 4, 725 (2005).

    Article  CAS  Google Scholar 

  16. J.W.M. Bulte and D.L. Kraitchman, NMR Biomed., 17, 484 (2004).

    Article  CAS  Google Scholar 

  17. A.-H. Lu, W. Schmidt, N. Matoussevitch, H. Bönnemann, B. Spliethoff, B. Tesche, E. Bill, W. Kiefer and F. Schüth, Angew. Chem. Int. Edit., 43, 4303 (2004).

    Article  CAS  Google Scholar 

  18. C.T. Yavuz, J.T. Mayo, W.W Yu, A. Prakash, J.C. Falkner, S. Yean, L. Cong, H. J. Shipley, A. Kan, M. Tomson, D. Natelson and V. L. Colvin, Science, 314, 964 (2006).

    Article  Google Scholar 

  19. B. Li, D. Jia, Y. Zhou, Q. Hu and W. Cai, J. Magn. Magn. Mater., 306, 223 (2006).

    Article  CAS  Google Scholar 

  20. Y. Wang, B. Li, Y. Zhou and D. Jia, Polym. Adv. Technol., 19, 1256 (2008).

    Article  CAS  Google Scholar 

  21. H.-Y. Zhu, Y.-Q. Fu, R. Jiang, J. Yao, L. Xiao and G.-M. Zeng, Bioresource Technol., 105, 24 (2012).

    Article  CAS  Google Scholar 

  22. Z. Liu, H. Wang, C. Liu, Y. Jiang, G. Yu, X. Mu and X. Wang, Chem. Commun., 48, 7350 (2012).

    Article  CAS  Google Scholar 

  23. G. Dodi, D. Hritcu, G. Lisa and M. I. Popa, Chem. Eng. J., 203, 130 (2012).

    Article  CAS  Google Scholar 

  24. C.-Y. Wang, C.-H. Yang, K.-S. Huang, C.-S. Yeh, A. H.-J. Wang and C.-H. Chen, J. Mater. Chem. B, 1, 2205 (2013).

    Article  CAS  Google Scholar 

  25. G. Huang, H. Zhang, J.X. Shi, T.A.G. Langrish, X. S. Jeffrey and A. G. L. Tim, Ind. Eng. Chem. Res., 48, 2646 (2009).

    Article  CAS  Google Scholar 

  26. H. V. Tran, L. D. Tran and T. N. Nguyen, Mater. Sci. Eng. C, 30, 304 (2010).

    Article  CAS  Google Scholar 

  27. M. Omer, S. Haider and S. y. Park, Polymer, 52, 91 (2011).

    Article  CAS  Google Scholar 

  28. A. Higazy, M. Hashem, A. ElShafei, N. Shaker and M. A. Hady, Carbohydr. Polym., 79, 867 (2010).

    Article  CAS  Google Scholar 

  29. F. Tian, Y. Liu, K. Hu and B. Zhao, J. Mater. Sci., 38, 4709 (2003).

    Article  CAS  Google Scholar 

  30. C. M. Yeng, S. Husseinsyah and S. S. Ting, Polym.-Plast. Technol., 52, 1496 (2013).

    Article  CAS  Google Scholar 

  31. S. Arokiyaraj, M. Saravanan, N. K. Udaya Prakash, M. Valan Arasu, B. Vijayakumar and S. Vincent, Mater. Res. Bull., 48, 3323 (2013).

    Article  CAS  Google Scholar 

  32. Y. Haldorai and J.-J. Shim, Compos. Interfaces, 20, 365 (2013).

    Article  CAS  Google Scholar 

  33. I. A.W. Tan, A. L. Ahmad and B. H. Hameed, J. Hazard. Mater., 154, 337 (2008).

    Article  CAS  Google Scholar 

  34. R. Jain and S. Sikarwar, J. Hazard. Mater., 152, 942 (2008).

    Article  CAS  Google Scholar 

  35. Y. S. Al-Degs, M. I. El-Barghouthi, A. H. El-Sheikh and G. M. Walker, Dyes Pigm., 77, 16 (2007).

    Article  Google Scholar 

  36. S. Lagergren, Kgl. Svenska Vetenskapsakad. Handl., 24, 1 (1898).

    Google Scholar 

  37. Y. S. Ho and G. McKay, Process Biochem., 34, 451 (1999).

    Article  CAS  Google Scholar 

  38. Y. Haldorai, J.-J. Shim, Appl. Surf. Sci., 292, 447 (2014).

    Article  CAS  Google Scholar 

  39. Z. Shariatinia and Z. Nikfar, Int. J. Biol. Macromol., 60, 226 (2013).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jae-Jin Shim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Haldorai, Y., Kharismadewi, D., Tuma, D. et al. Properties of chitosan/magnetite nanoparticles composites for efficient dye adsorption and antibacterial agent. Korean J. Chem. Eng. 32, 1688–1693 (2015). https://doi.org/10.1007/s11814-014-0368-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-014-0368-9

Keywords

Navigation