Abstract
Activated carbon could be prepared from residue of rice husk using physical activation with steam as activating agent. Response surface methodology (RSM) was applied to optimize the effects of processing parameters, and regression analysis was performed on the data obtained. The optimal conditions for adsorption capacity of activated carbon from the residue of rice husk were activation temperature of 946 °C, activation time of 31 min and water (18 g) which changed to steam by heating, resulting in 970.06 mg·g−1 of iodine adsorption capacity and 31.36% of activated carbon yield. The activated carbon prepared under optimum condition was mesoporous with BET surface area of 1,004.296 m2·g−1, total pore volume of 0.9388 cm3·g−1 and average pore diameter of 2.043 nm. The surface chemical functional groups of activated carbon were identified by FT-IR, and its microstructure was examined by scanning electron microscopy (SEM). We concluded that the process of physical activation with steam could be an environmentally harmonious and effective method for preparing activated carbon from residue of desilicated rice husk.
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S.V. Mikhalovsky and V.G. Nikolaev, Interface Sci., 7, 529 (2006).
F. C. Wu, R. L. Tseng and C. C. Hu, Micropor. Mesopor. Mater., 80, 9 (2005).
A. Aworn, P. Thiravety and W. Nakbanpote, J. Anal. Appl. Pyrolysis, 82, 279 (2008).
M. J. Ahmed and S. K. Theydan, Powder Technol., 229, 237 (2012).
R. H. Hesas, W.M.A. Van Daud, J. N. Sahu and A. Arami-Niya, J. Anal. Appl. Pyrolysis, 100, 1 (2013).
S.K. Ryu, H. Jin, D. Gondy and N. Pusset, Carbon, 5, 31 (1993).
T. Wigmans, Carbon, 1, 27 (1989).
S. M. Guillermo, D. F. Geoffrey and J. S. Christopher, Carbon, 41, 1009 (2003).
C. F. Chang, C.Y. Chang and W. T. Tsai, J. Colloid Interface Sci., 232, 45 (2000).
B. H. Hameed, I.A.W. Tan and A. L. Ahmad, J. Hazard. Mater., 158, 324 (2008).
H.Y. Kang, S. S. Park and Y. S. Rim, Korean J. Chem. Eng., 23, 948 (2006).
Y.W. Zhu, J. H. Gao, Y. Li, F. Sun and Y. K. Qin, Korean J. Chem. Eng., 28, 2344 (2011).
M. F. Tennant and D.W. Mazyck, Carbon, 41, 2195 (2003).
H. Demiral, İ. Demiral, B. Karabacakoğlu and F. Tümsek, Chem. Eng. Res. Des., 89, 206 (2011).
Y. Ngernyen, C. Tangsathitkulchai and M. Tangsathitkulchai, Korean J. Chem. Eng., 23, 1046 (2006).
C.A. Toles, W.E. Marshall, L.H. Wartelle and A. McAloon, Bioresour. Technol., 75, 197 (2000).
A.V. Esin and E. P. Ayşe, J. Anal. Appl. Pyrolysis, 98, 29 (2012).
B. C. Kim, Y. H. Kim and T. Yamamoto, Korean J. Chem. Eng., 25, 5 (2008).
Z. Z. Chowdhury, S. M. Zain, R. A. Khan and Md. S. Islam, Korean J. Chem. Eng., 29, 1187 (2012).
P. Fu, S. Hu, J. Xiang, W. M. Yi, X. Y. Bai, L. S. Sun and S. Su, Bioresour. Technol., 114, 591 (2012).
C. Deiana, D. Granados, R. Venturini, A. Amaya, M. Sergio and N. Tancredi, Ind. Eng. Chem. Res., 47, 4754 (2008).
Y. Lin, Y. P. Guo, W. Gao, Z. Wang, Y. J. Ma and Z. C. Wang, J. Clean Prod., 32, 204 (2012).
A. A.M. Daifullah, B. S. Girgis, H. M. H. Gad, Mater. Lett., 57, 1723 (2003).
S. Román, J. F. González, C. M. González-García and F. Zarmora, Fuel Process. Technol., 89, 715 (2008).
J. Lee, L. Ye, W. O. Landen and R. R. Eitenmiller, J. Food Compos. Anal., 13, 45 (2000).
J. M. Valente Nabais, P. Nunes, P. J. M. Carrott, M. M. L. Ribeiro Carrott, A. Macías García and M. A. Díaz-Díez, Fuel Process. Technol., 89, 262 (2008).
M. A. Ahmad and R. Alrozi, Chem. Eng. J., 165, 883 (2010).
X. H. Duan, C. Srinivasakannan, W.W. Qu and X. Wang, Chem. Eng. Process., 53, 53 (2012).
A. A. Ahmad, B. H. Hameed and A. L. Ahmad, J. Hazard. Mater., 170, 612 (2009).
A. Arami-Niya, W. M. A. Wan Daud, F. S. Mjalli and F. Abnisa, Chem. Eng. Res. Des., 90, 776 (2012).
L.X. Huang, M.X. Wang, Y. P. Wu, L.R. Li and F.M. Zhou, J. Nanjing Inst. Forestry, 1, 31 (1986).
A. Aranda, R. Murillo, T. García and A. M. Mastral, Chem. Eng. J., 187, 123 (2012).
Y. Sudaryanto, S. B. Hartono, W. Irawaty, H. Hindarso and S. Ismadji, Bioresour. Technol., 97, 734 (2006).
B.G.P. Kumar, K. Shivakamy, L.R. Miranda and M. Velan, J. Hazard. Mater., B136, 922 (2006).
Ç. Şentorun-Shalaby, M.G. Ucak-Astarloğlu, L. Artok, Ç. Sarici, Micropor. Mesopor. Mater., 88, 126 (2006).
L. S. Balistrieri and J.W. Murray, Am. J. Sci., 281, 788 (1981).
P. Luo, B. Zhang, Y. Zhao, J. Wang, H. Zhang and J. Liu, Korean J. Chem. Eng., 28, 800 (2011).
K. S. Kumar Reddy, A. Al Shoaibi and C. Srinivasakannan, New Carbon Mater., 27, 344 (2012).
Y. B. Tang, Q. Liu and F.Y. Chen, Chem. Eng. J., 203, 19 (2013).
S. K. Theydan and M. J. Ahmed, J. Anal. Appl. Pyrolysis, 97, 16 (2012).
B. Bestani, N. Benderdouche, B. Benstaali, M. Belhakem and A. Addou, Bioresour. Technol., 99, 8441 (2008).
W. H. Li, Q. Y. Yue, B. Y. Gao, X. J. Wang, Y. F. Qi, Y. Q. Zhao and Y. J. Li, Desalination, 278, 179 (2011).
M. J. Ahmed and S. K. Theydan, J. Anal. Appl. Pyrolysis, 105, 199 (2014).
K. F. Fu, Q.Y. Yue, B.Y. Gao, Y.Y. Sun and L. J. Zhu, Chem. Eng. J., 228, 1074 (2013).
H. Deng, L. Yang, G. H. Tao and J. L. Dai, J. Hazard. Mater., 166, 1514 (2009).
O.P.A.L. Cazetta, I. P. A. F. Souza, K. C. Bedin, A. C. Matins, T. L. Silva and V. C. Almeida, J. Ind. Eng. Chem., JIEC-1895, No. pages 7 (2014).
N. Passe-Coutrin, S. Altenor, D. Cossement, C. Jean-Marius and S. Gaspared, Micropor. Mesopor. Mater., 111, 517 (2008).
Y. Chen, Y. C. Zhu, Z. C. Wang, Y. Li, L. L. Wang, L. L. Ding, X.Y. Gao, Y. J. Ma and Y. P. Guo, Adv. Colloid Interface Sci., 163, 39 (2011).
V. C. Srivastava, I. D. Mall and I.M. Mishra, J. Hazard. Mater., B134, 257 (2006).
U. R. Lakshmi, V. C. Srivastava, I. D. Mall and D. H. Lataye, J. Environ. Manage., 90, 710 (2009).
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Han, X., He, Y., Zhao, H. et al. Optimization of preparation conditions of activated carbon from the residue of desilicated rice husk using response surface methodology. Korean J. Chem. Eng. 31, 1810–1817 (2014). https://doi.org/10.1007/s11814-014-0103-6
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DOI: https://doi.org/10.1007/s11814-014-0103-6